An energy diagram for the molecular orbitals of period 2 diatomic molecules should be drawn and the difference in ordering for B 2 , C 2 and N 2 should be compared to O 2 , F 2 and Ne 2 . Concept introduction: MOT is more accurate theory than VBT . VBT fails to explain the magnetic behavior and bonding in electron-deficient compound. According to this theory, atomic orbitals combine to form molecular orbitals. The number of the molecular orbital is equal to atomic orbital according to this theory. ( i ) The molecular orbitals are formed by the linear combination of atomic orbitals. There are two type of combination ( a ) constructive ( b ) destructive interference ( ii )Molecular orbitals formed by constructive interference is known as bonding molecular orbital, and its energy is less than atomic orbital ( iii ) Molecular orbital formed by destructive interference is known as anti bonding molecular orbital and its energy is greater than atomic orbital. ( iv ) Electrons in molecular orbitals are filled according to Aufbau’s rule, Pauli’s Exclusion Principle, and Hund’s rule.
An energy diagram for the molecular orbitals of period 2 diatomic molecules should be drawn and the difference in ordering for B 2 , C 2 and N 2 should be compared to O 2 , F 2 and Ne 2 . Concept introduction: MOT is more accurate theory than VBT . VBT fails to explain the magnetic behavior and bonding in electron-deficient compound. According to this theory, atomic orbitals combine to form molecular orbitals. The number of the molecular orbital is equal to atomic orbital according to this theory. ( i ) The molecular orbitals are formed by the linear combination of atomic orbitals. There are two type of combination ( a ) constructive ( b ) destructive interference ( ii )Molecular orbitals formed by constructive interference is known as bonding molecular orbital, and its energy is less than atomic orbital ( iii ) Molecular orbital formed by destructive interference is known as anti bonding molecular orbital and its energy is greater than atomic orbital. ( iv ) Electrons in molecular orbitals are filled according to Aufbau’s rule, Pauli’s Exclusion Principle, and Hund’s rule.
Solution Summary: The author explains that MOT is more accurate than VBT, which fails to explain the magnetic behavior and bonding in electron-deficient compound.
Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.
Chapter 6, Problem 19E
Interpretation Introduction
Interpretation:
An energy diagram for the molecular orbitals of period 2 diatomic molecules should be drawn and the difference in ordering for B2, C2 and N2 should be compared to O2, F2 and Ne2.
Concept introduction:
MOT is more accurate theory than VBT. VBT fails to explain the magnetic behavior and bonding in electron-deficient compound. According to this theory, atomic orbitals combine to form molecular orbitals. The number of the molecular orbital is equal to atomic orbital according to this theory.
(i) The molecular orbitals are formed by the linear combination of atomic orbitals. There are two type of combination (a) constructive (b) destructive interference
(ii)Molecular orbitals formed by constructive interference is known as bonding molecular orbital, and its energy is less than atomic orbital
(iii) Molecular orbital formed by destructive interference is known as anti bonding molecular orbital and its energy is greater than atomic orbital.
(iv) Electrons in molecular orbitals are filled according to Aufbau’s rule, Pauli’s Exclusion Principle, and Hund’s rule.
Use the Henderson-Hasselbalch equation to calculate pH of a buffer containing 0.050M benzoic acidand 0.150M sodium benzoate. The Ka of benzoic acid is 6.5 x 10-5
A. Draw the structure of each of the following alcohols. Then draw and name the product you would expect to produce by the oxidation of each. a. 4-Methyl-2-heptanol
b. 3,4-Dimethyl-1-pentanol
c. 4-Ethyl-2-heptanol
d. 5,7-Dichloro-3-heptanol
What is the pH of a 1.0 L buffer made with 0.300 mol of HF (Ka = 6.8 × 10⁻⁴) and 0.200 mol of NaF to which 0.160 mol of NaOH were added?
Chapter 6 Solutions
Study Guide for Chemistry: Structure and Properties
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