Chemistry In Context
Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 6, Problem 17Q

(a)

Interpretation Introduction

Interpretation:

For the given plutonium-239 and iodine-131 decays, nuclear equation has to be given.

(b)

Interpretation Introduction

Interpretation:

In particulate form inhalation of plutonium is most dangerous, reason for this fact has to be given.

(c)

Interpretation Introduction

Interpretation:

If Iodine is ingested to body, accumulation part of iodine isotopes in the body has to be given.

(d)

Interpretation Introduction

Interpretation:

For the given mass of sample, after three half-lives the remaining amount of sample and the substance having longest decay constant has to identified.

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C. I, II, III Consider the reaction sequence below to answer the following questions: 0 0 1. NaOEt, EtOH ΕΙΟ OEt 2 Compound X CO₂Et NaOEt, EtOH CO₂Et Br Compound Y A Compound Z A. Compound X, diethyl propanedioate, is more commonly known as a. ethyl acetoacetate acetoacetic ester b. C. oxalic ester d. malonic ester B. Write the complete stepwise mechanism for the conversion of Compound X into Compound Y. Show all electron flow with arrows and draw all intermediate structures.
Diethyl malonate can be prepared by the following reaction sequence. Draw the structures of each of the missing intermediates in the boxes provided EtO 0 H3C 11 C 1. Br₂ PBr OH 2 H₂O 010 0 CH3CH₂OH C CH2 OEt Ha CH3CH2OH на NaCN H₂SO4 NC H₂O, heat CH2 OCH2CH3

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