MAST F/ CHEM: THE CENTRAL SCI CODE ALON
14th Edition
ISBN: 9781323654378
Author: Brown
Publisher: PEARSON
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Chapter 6, Problem 100AE
[6.100] The Chemistry and Life box in Section 6.7 described the techniques called NMR and MRI.
Instruments for obtaining MRI data are typically labeled with a frequency, such as 600 MHz. In what region of the
- What is the value of ΔE in Figure 6.27 that would correspond to the absorption of a photon of radiation with frequency 450 MHz?
- When the 450-MHz photon is absorbed, does it change the spin of the electron or the proton on a hydrogen atom?
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6.
Gallium arsenide (GaAs) is used in the red lasers of bar-code readers.
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6.22
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Chapter 6 Solutions
MAST F/ CHEM: THE CENTRAL SCI CODE ALON
Ch. 6.1 - A source of electromagnetic radiation produces...Ch. 6.1 - Which type of visible light has a longer...Ch. 6.1 - Consider the following three statements: For any...Ch. 6.1 - A laser used in orthopedic spine surgery produces...Ch. 6.2 - Prob. 6.3.1PECh. 6.2 -
A laser emits light that has a frequency of 4.69...Ch. 6.3 - Prob. 6.4.1PECh. 6.3 -
For each of the following transitions, give the...Ch. 6.4 - Consider the following three moving objects: a...Ch. 6.4 - Calculate the velocity of a neutron whose de...
Ch. 6.5 - An orbital has n = 4 and ml = 0, 1, 2, 3 -3, - 2,...Ch. 6.5 -
What is the designation for the subshell with = 5...Ch. 6.8 - How many of the elements in the second row of the...Ch. 6.8 - Write the electron configuration for silicon,...Ch. 6.9 - A certain atom has an ns2np2electron configuration...Ch. 6.9 -
Which group of elements is characterized by an...Ch. 6.9 -
A certain atom has a [noble gas]5s24d105p4...Ch. 6.9 - Prob. 6.9.2PECh. 6 - In this chapter, we have learned about the...Ch. 6 - The speed of sound in dry air at 20°C is 343 m/s...Ch. 6 -
6.2 A popular kitchen appliance produces...Ch. 6 - 6.3 The following diagrams represent two...Ch. 6 -
6.4 Stars do not all have the same temperature....Ch. 6 - 6 5 The familiar phenomenon of a rainbow results...Ch. 6 -
6.7 A certain quantum mechanical system has the...Ch. 6 - Consider the three electronic transitions in a...Ch. 6 - Prob. 8ECh. 6 -
6.9 The contour representation of one of the...Ch. 6 -
6.10 The accompanying drawing shows a contour...Ch. 6 -
8.11 Four possible electron configurations for a...Ch. 6 -
6.12 State where in the periodic table these...Ch. 6 - Prob. 13ECh. 6 -
6.14
a What is the relationship between the...Ch. 6 - Label each of the following statements as true or...Ch. 6 - Determine which of the following statements are...Ch. 6 - Arrange the following kinds of electromagnetic...Ch. 6 - List the following types of electromagnetic...Ch. 6 - What is the frequency of radiation that has a...Ch. 6 - What is the frequency of radiation whose...Ch. 6 - A laser pointer used in a lecture hall emits light...Ch. 6 - It is possible to convert radiant energy into...Ch. 6 - If human height were quantized in 1-foot...Ch. 6 - Einstein's 1905 paper on the photoelectric effect...Ch. 6 - Calculate the energy of a photon of...Ch. 6 - Prob. 26ECh. 6 - Prob. 27ECh. 6 - An AM radio station broadcasts at 1010 kHz, and...Ch. 6 - One type of sunburn occurs on exposure to UV light...Ch. 6 - Prob. 30ECh. 6 - Prob. 31ECh. 6 - A stellar object is emitting radiation at 3.55 mm....Ch. 6 - Molybdenum metal must absorb radiation with a...Ch. 6 - Titanium metal requires a photon with a minimum...Ch. 6 - Prob. 35ECh. 6 - Classify each of the following statements as...Ch. 6 - Prob. 37ECh. 6 -
6 38 Indicate whether energy is emitted or...Ch. 6 - Using Equation 6.5. calculate the energy of an...Ch. 6 - Prob. 40ECh. 6 - The visible emission lines observed by Balmer all...Ch. 6 - Prob. 42ECh. 6 - Prob. 43ECh. 6 - The hydrogen atom can absorb light of wavelength...Ch. 6 - Prob. 45ECh. 6 - Prob. 46ECh. 6 - Use the de Brogue relationship to determine the...Ch. 6 - Prob. 48ECh. 6 - Neutron diffraction is an important technique for...Ch. 6 - The electron microscope has been widely used to...Ch. 6 - Using Heisenberg's uncertainty principle,...Ch. 6 - Prob. 52ECh. 6 - Classify the following statements as either true...Ch. 6 - 0 1 2 3 4 5 6 7 8 9 10 Distance from the nucleus,...Ch. 6 - Prob. 55ECh. 6 - Prob. 56ECh. 6 - Prob. 57ECh. 6 - Give the values for n, I,and mlfor each orbital in...Ch. 6 - Prob. 59ECh. 6 - Prob. 60ECh. 6 - Which of the following represent impossible...Ch. 6 - For the table that follows, write which orbital...Ch. 6 - Sketch the shape and orientation of the following...Ch. 6 - Prob. 64ECh. 6 - Prob. 65ECh. 6 - Prob. 66ECh. 6 - Prob. 67ECh. 6 - Prob. 68ECh. 6 - Two possible electron configurations for an Li...Ch. 6 -
6.70 An experiment called the Stern—Gerlach...Ch. 6 - Prob. 71ECh. 6 - Prob. 72ECh. 6 - What are "valence electrons"? What are "core...Ch. 6 - For each element, indicate the number of valence...Ch. 6 - Write the condensed electron configurations for...Ch. 6 - Write the condensed electron configurations for...Ch. 6 - Identify the specific element that corresponds to...Ch. 6 - Identify the group of elements that corresponds to...Ch. 6 - The following do not represent valid ground-state...Ch. 6 - Prob. 80ECh. 6 - Prob. 81AECh. 6 - Prob. 82AECh. 6 - Prob. 83AECh. 6 - Prob. 84AECh. 6 - Prob. 85AECh. 6 - Prob. 86AECh. 6 - Prob. 87AECh. 6 - In an experiment to study the photoelectric...Ch. 6 - Prob. 89AECh. 6 - Prob. 90AECh. 6 - Prob. 91AECh. 6 - Prob. 92AECh. 6 - Prob. 93AECh. 6 - Prob. 94AECh. 6 - Prob. 95AECh. 6 - Prob. 96AECh. 6 - Prob. 97AECh. 6 - Prob. 98AECh. 6 - Prob. 99AECh. 6 - [6.100] The Chemistry and Life box in Section 6.7...Ch. 6 - Prob. 101AECh. 6 - Using the periodic table as a guide, write the...Ch. 6 - Prob. 103AECh. 6 - [6.104] In the experiment shown schematically...Ch. 6 - Microwave ovens use microwave radiation to heat...Ch. 6 - Prob. 106IECh. 6 - The discovery of hafnium, element number 72,...Ch. 6 - Account for formation of the following series of...Ch. 6 - Prob. 109IECh. 6 - The two most common isotopes of uranium are 235U...
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- 6.103 Atomic absorption spectroscopy is based on the atomic spectra of the elements being studied. It can be used to determine the impurities in a metal sample. If an element is present, light at the appropriate wavelength is absorbed. You are working with a metal stamping company and the rolled steel you use to form panels for automobile doors is failing at an alarming rate. There is some chance that the problem is unacceptably high levels of manganese in the steel. Given that the atomic spectrum of manganese has three lines near 403 nm, how could you use a spectrometer to determine the amount of manganese in the steel?arrow_forward5. (a) Use the hydrogen-like model z2 (in eV) En --13.6 to calculate the total energy of the three electrons of lithium (Li), which has the electron configuration: 1s? 2s'. The three ionization energies for Li(g) are: IE, = 5.392 ev; IE2 = 75.64 eV; IE = 122.5 ev. With the help of Koopman's theorem, what is the total energy of ropulsion between lithium's three electrons (in kJ mol')?arrow_forwardGg.231.arrow_forward
- 6.113 When an electron makes a transition between energylevels of a hydrogen atom, there are no restrictions onthe initial and final values of the principal quantumnumber n. However, there is a quantum mechanicalrule that restricts the initial and final values of theorbital angular momentum l. This is the selectionrule, which states that Δl = ±1; that is, in atransition, the value of l can only increase or decreaseby 1. According to this rule, which of the followingtransitions are allowed:arrow_forwardFor each of the statements below, indicate whether it is true or false and explain your reasoning. (1 sentence ) 1/ It takes more energy to ionize an electron from the 2s orbital than an electron from the 2p orbital in the Li2+ ion. 2/ The electron affinity of the Ne atom is larger than the electron affinity of the F atom. 3/ K* has a larger radius than Ar. 4/ For a diatomic molecule, in which the internuclear axis is the z-axis, the 3dz? orbital cannot mix with the 2px orbital. 5/ The internuclear distance of O2 increases as it takes an additional electron to become O2".arrow_forward6.21arrow_forward
- Assume that the filling of orbitals must be sequential, -1 →0→1(corresponding to px → Py→ p2) What element (use the symbol only) have the four quantum number set for the last electron added? 1. (3,1,0,-1/2) 2. (4,3,-2,+1/2) : 3. (2,1,0,-1/2) What is the four quantum number set for the last electron added to the following elements: 4. Sn = ( 5. Cf = ( How many electrons have the following quantum number sets? 6. (3,?,?,-1/2) = 7. (?,0,0,?) = %3D 8. (2,1,?,?) = 9. (?,?,1,-1/2) = 10. (7,?,-1,-1/2) =arrow_forwardQ4: Find the wave length of the electromagnetic radiation, which emitted from an atom, when two electrons jump from ( 5th to 2nd ) orbit and the other from ( 3rd to 1º) orbit? Note that the ground energy equal to (-13.6eV). (Ans. 435 nm, 102 nm).arrow_forwardHelium is in group 18 (VIIIB) of the periodic table with a ground state electron configuration of 1s? How many valence electrons does it have? 8. 2.arrow_forward
- (4.10a, continued). Each electron in an atom may be characterized by a set of four quantum numbers (n, l, mỵ, mg). For each of the following, tell how many different sets of quantum numbers are possible, such that each set contains all the values listed. If it is not possible to write a set of 4 quantum numbers, write N/A (not allowed). a) n = 2, l = 2 b) n = 2, l = 0 c) n = 4, l = 2, mį = +3 d) n = 4, l =3, m¡ = -2 e) n = 3, l = 1, mį = 0 f) n = 3, l = 1 Write each set of four quantum numbers in parentheses, and follow the sequence without a comma: (n I mị mg). For example, a set for 1s subshell can be written as (1 0 0 +½) or (1 0 0 -½) where n =1, l = 0, m¡ = 0, mɛ = +½ or -/½. Only 2 sets are possible. Answer: no. of sets possible per given No. of orbitals (n I m¡ mg) subshell d) n = 4, l =3, mį = -2 e) n = 3, l = 1, mį = 0 For this part, please f) n = 3, l = 1 answer on the next pagearrow_forward7.5 B What must the distance be between charges of +2.25 and −1.86 for the attractive force between them to be the same as that between charges of +4.06 and −2.11 separated by a distance of 2.16 pm?arrow_forwardIV. There is one more policy that helps the hotel run smoothly and keep customers happy. Hund's Rule states that if electrons are being placed in the same section of a floor (rooms that cost the same) then each one gets their own room and has the same spin until the floor is half-filled. If any more electrons want to stay in that same section, then they must pair up with another electron and assume the opposite spin. This does not necessarily apply to electrons that have purchased more expensive rooms. In the diagrams below identify the areas in which Hund's Rule was broken. Describe how the rule is being broken in each case. D1111 |1|1||1| 1 1 1 1 1 November 26, 1995 February 12, 1997 July 10, 1983 A В V. OBSERVATIONS: A. How many "rooms" are there in an "s" suite of a floor? B. How many "rooms" are there in a "p" suite of a floor? C. How many "rooms" are there in a "d" suite of a floor? D. How many electrons can stay on the first floor? second floor? third floor? E. Describe how the…arrow_forward
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