
Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
Chapter 5.8, Problem 2.1ACP
Interpretation Introduction
Interpretation:
The enthalpy change of the combustion of ethanol and octane has to be calculated and compared
Concept Introduction:
Standard enthalpy of the reaction,
Enthalpy change for the reaction
Enthalpy of the reaction,
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Question 11 of 18 (1 point) Question Attempt: 3 of
How many signals do you expect in the 'H NMR spectrum for this molecule?
Br
Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
1
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box…
Organic Chemistry
Esterification reactions
1. Write the steps to prepare ester.
2. Write complete reaction of ethanol and acetic acid to make ester.
3. What does ester smell like? What are the uses of ester.
4. What the role of sulfuric acid in the esterification reaction
11. Complete the following esterification reaction with names of all the reactants and products under.
Hint: Remove the water and end up with ester
R-C-OH + ROH
R-C-OR + H₂O
A carboxylic acid
An alcohol
An ester
Water
BYJU'S
H-C-C
O-H
Нин
C-C-C-H
HAAA
H O-C-C-C-H
AAA
Ethanoic acid
Propanol
Water Propyl ethanoate
By com
CH3COOH + CH3CH2CH2CH₂CH₂OH →
Practice for alcohols aldehydes and ketones:
12. Draw the structures from the following names mixed of alcohol/aldehyde and ketone:
a. 4-methyl cyclohexanone
b. 3-methyl-2-pentenal
c. 2,3-dimethylcyclohexanone
d. 1,3propanediol or Propane 1,3 diol
13. Write systematic names for the following compounds identify
functional group:
a.
b. (CH3)2CH-C
OH
c) CH(CH₂)--
OH
-,-,
Chapter 5 Solutions
Chemistry & Chemical Reactivity
Ch. 5.2 - You did an experiment in which you found that 59.8...Ch. 5.2 - A 15.5-g piece of chromium, heated to 100.0 C, is...Ch. 5.3 - Calculate the amount of energy necessary to raise...Ch. 5.3 - To make a glass of iced tea, you pour 250 mL of...Ch. 5.4 - Nitrogen gas (2.75 L) is confined in a cylinder...Ch. 5.5 - The combustion of ethane, C2H6, has an enthalpy...Ch. 5.6 - Assume 200. mL of 0.400 M HCl is mixed with 200....Ch. 5.6 - A 1.00-g sample of ordinary table sugar (sucrose,...Ch. 5.7 - Use Hesss law to calculate the enthalpy change for...Ch. 5.7 - Calculate the standard enthalpy of combustion for...
Ch. 5.8 - The standard enthalpies of formation of KNO3(s)...Ch. 5.8 - Prob. 1.2ACPCh. 5.8 - The decomposition of nitroglycerin (C3H5N3O9)...Ch. 5.8 - Prob. 2.1ACPCh. 5.8 - Prob. 2.2ACPCh. 5.8 - Prob. 2.3ACPCh. 5.8 - Prob. 2.4ACPCh. 5.8 - Prob. 2.5ACPCh. 5 - Define the terms system and surroundings. What...Ch. 5 - What determines the directionality of energy...Ch. 5 - Identify whether the following processes are...Ch. 5 - Identify whether the following processes are...Ch. 5 - The molar heat capacity of mercury is 28.1 J/mol ...Ch. 5 - The specific heat capacity of benzene (C6H6) is...Ch. 5 - The specific heat capacity of copper metal is...Ch. 5 - How much energy as heat is required to raise the...Ch. 5 - The initial temperature of a 344-g sample of iron...Ch. 5 - After absorbing 1.850 kJ of energy as heat, the...Ch. 5 - A 45.5-g sample of copper at 99.8 C is dropped...Ch. 5 - One beaker contains 156 g of water at 22 C, and a...Ch. 5 - A 182-g sample of gold at some temperature was...Ch. 5 - When 108 g of water at a temperature of 22.5 C is...Ch. 5 - A 13.8-g piece of zinc is heated to 98.8 C in...Ch. 5 - A 237-g piece of molybdenum, initially at 100.0 C,...Ch. 5 - How much energy is evolved as heat when 1.0 L of...Ch. 5 - The energy required to melt 1.00 g of ice at 0 C...Ch. 5 - How much energy is required to vaporize 125 g of...Ch. 5 - Chloromethane, CH3CI, arises from microbial...Ch. 5 - The freezing point of mercury is 38.8 C. What...Ch. 5 - What quantity of energy, in joules, is required to...Ch. 5 - Ethanol, C2HsOH, boils at 78.29 C. How much...Ch. 5 - A 25.0-mL sample of benzene at 19.9 C was cooled...Ch. 5 - As a gas cools, it is compressed from 2.50 L to...Ch. 5 - A balloon expands from 0.75 L to 1.20 L as it is...Ch. 5 - A balloon does 324 J of work on the surroundings...Ch. 5 - As the gas trapped in a cylinder with a movable...Ch. 5 - When 745 J of energy in the form of heat is...Ch. 5 - The internal energy of a gas decreases by 1.65 kJ...Ch. 5 - A volume of 1.50 L of argon gas is confined in a...Ch. 5 - Nitrogen gas is confined in a cylinder with a...Ch. 5 - Nitrogen monoxide, a gas recently found to be...Ch. 5 - Calcium carbide, CaC2, is manufactured by the...Ch. 5 - Isooctane (2,2,4-trimethylpentane), one of the...Ch. 5 - Acetic acid. CH3CO2H, is made industrially by the...Ch. 5 - You mix 125 mL of 0.250 M CsOH with 50.0 mL of...Ch. 5 - You mix 125 mL of 0.250 M CsOH with 50.0 mL of...Ch. 5 - A piece of titanium metal with a mass of 20.8 g is...Ch. 5 - A piece of chromium metal with a mass of 24.26 g...Ch. 5 - Adding 5.44 g of NH4NO3(s) to 150.0 g of water in...Ch. 5 - You should use care when dissolving H2SO4 in water...Ch. 5 - Sulfur (2.56 g) was burned in a constant-volume...Ch. 5 - Suppose you burned 0.300 g of C(s) in an excess of...Ch. 5 - Suppose you burned 1.500 g of benzoic acid,...Ch. 5 - A 0.692-g sample of glucose, C6H12O6, was burned...Ch. 5 - An ice calorimeter can be used to determine the...Ch. 5 - A 9.36-g piece of platinum was heated to 98.6 C in...Ch. 5 - The enthalpy changes for the following reactions...Ch. 5 - The enthalpy changes of the following reactions...Ch. 5 - Enthalpy changes for the following reactions can...Ch. 5 - You wish to know the enthalpy change for the...Ch. 5 - Write a balanced chemical equation for the...Ch. 5 - Write a balanced chemical equation for the...Ch. 5 - (a) Write a balanced chemical equation for the...Ch. 5 - (a) Write a balanced chemical equation for the...Ch. 5 - Use standard enthalpies of formation in Appendix L...Ch. 5 - Use standard enthalpies of formation in Appendix L...Ch. 5 - The first step in the production of nitric acid...Ch. 5 - The Romans used calcium oxide, CaO, to produce a...Ch. 5 - The standard enthalpy of formation of solid barium...Ch. 5 - An important step in the production of sulfuric...Ch. 5 - The enthalpy change for the oxidation of...Ch. 5 - The enthalpy change for the oxidation of styrene....Ch. 5 - Prob. 65GQCh. 5 - Prob. 66GQCh. 5 - For each of the following, define a system and its...Ch. 5 - Prob. 68GQCh. 5 - Use Appendix L to find the standard enthalpies of...Ch. 5 - You have a large balloon containing 1.0 mol of...Ch. 5 - Determine whether energy as heat is evolved or...Ch. 5 - Determine whether energy as heat is evolved or...Ch. 5 - Use standard enthalpies of formation to calculate...Ch. 5 - Which evolves more energy on cooling from 50 C to...Ch. 5 - You determine that 187 J of energy as heat is...Ch. 5 - Calculate the quantity of energy required to...Ch. 5 - You add 100.0 g of water at 60.0 C to 100.0 g of...Ch. 5 - Three 45-g ice cubes at 0 C are dropped into 5.00 ...Ch. 5 - Suppose that only two 45-g ice cubes had been...Ch. 5 - You take a diet cola from the refrigerator and...Ch. 5 - The standard molar enthalpy of formation of...Ch. 5 - Chloromethane, CH3Cl, a compound found throughout...Ch. 5 - Prob. 83GQCh. 5 - Camping stoves are fueled by propane (C3H8),...Ch. 5 - Prob. 85GQCh. 5 - Prob. 86GQCh. 5 - (a) Calculate the enthalpy change, rH, for the...Ch. 5 - You drink 350 mL of diet soda that is at a...Ch. 5 - Chloroform, CHCl3, is formed from methane and...Ch. 5 - Water gas, a mixture of carbon monoxide and...Ch. 5 - Using standard enthalpies of formation, verify...Ch. 5 - A piece of lead with a mass of 27.3 g was heated...Ch. 5 - A 192-g piece of copper is heated to 100.0 C in a...Ch. 5 - Insoluble AgCl(s) precipitates when solutions of...Ch. 5 - Insoluble PbBr2(s) precipitates when solutions of...Ch. 5 - The value of U for the decomposition of 7.647 g of...Ch. 5 - A bomb calorimetric experiment was run to...Ch. 5 - The meals-ready-to-eat (MREs) in the military can...Ch. 5 - On a cold day, you can warm your hands with a heat...Ch. 5 - Without doing calculations, decide whether each of...Ch. 5 - Prob. 102SCQCh. 5 - You want to determine the value for the enthalpy...Ch. 5 - Prepare a graph of specific heat capacities for...Ch. 5 - Prob. 105SCQCh. 5 - You are attending summer school and living in a...Ch. 5 - Prob. 107SCQCh. 5 - Prob. 108SCQCh. 5 - Prob. 109SCQCh. 5 - Peanuts and peanut oil are organic materials and...Ch. 5 - Isomers are molecules with the same elemental...Ch. 5 - Prob. 112SCQCh. 5 - Prob. 113SCQCh. 5 - A piece of gold (10.0 g, CAu = 0.129 J/g K) is...Ch. 5 - Methane, CH4, can be converted to methanol, which,...Ch. 5 - Calculate rH for the reaction 2 C(s) + 3 H2(g) + ...Ch. 5 - You have the six pieces of metal listed below,...Ch. 5 - Sublimation of 1.0 g of dry ice. CO2(s), forms...Ch. 5 - In the reaction of two moles of gaseous hydrogen...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- may you please show all steps! i am having a hard time understanding and applying in this format, thank you!arrow_forward10. Complete the substitution reaction of 2 pentanol with these reagents. Reagents & Reaction Conditions use practice sheet. Please write only major products, minor product like water, other gases are not required. Hint: In substitution of alcohol, we generally substitute OH group with Halogens like cl, Br, F using some reagent containing halogens. Ensure to add halogens to the same carbon number where you are removing OH from Examples Alcohols can be converted to Alkyl Halides with HX acids HBr H₂O HCI + H₂O HI + H₂O CH,CH₂OH + SOCI₂ CH,CH₂OH + PCI₁₂ A BBYJU'S CH CHCI + SO₂+ HCI CH₂CH CIP(OH), + HCI CH,CH₂OH + PCI CHCHCI + POCI + HCI CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr 1. Reaction with HBr with 2 Pentanol 2.Reaction with HI with 2 pentanol © Byjus.com 3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role) 4.Reaction with SOCI,, with 2 Pentanol 5.Reaction with PBr; or PCl, with 2 pentanolarrow_forward3. Is 2-methyl-2-propanol a primary, secondary, or tertiary alcohol? Write out the structures of 2-methyl-2-propanol and also any oxidation products of 2- methyl-2- propanol. If there is more than one oxidation product, give the structure of each of the products. 4. 2-Propanol is the IUPAC systematic name of this alcohol. It has a common name by which it is much better known (You'll see it in the grocery store or pharmacy). Give that common name 5. Aldehydes can be synthesized by the oxidation of. Please choose from below choices A. Primary alcohols B. Secondary alcohols C. Organic acids D. Inorganic acids 6. Tertiary alcohol Can undergo oxidation. yes or no. ? If yes then answer the product.arrow_forward
- Finish the reactions hand written pleasearrow_forwardPart A Identify each alcohol as primary, secondary, or tertiary Drag the appropriate items to their respective bins. CH₂ H₂C- -C-OH HO CH₂ Primary Он OH CH₂ OH CCH₂OH CH₂ сн Secondary Tertiary Reset Help CH,CH₂ (CH)CHCH,OH CH,CH,CH,CCH, CHOH CH₂ Different types of alcohol groups Alcohol and its reaction: 8. Combing two alcohol molecules below and completing the reaction with Product .( Hint Reaction called etherification as ether is formed and name the ether once you complete the reaction. Hint.: R-O-H+H-O-RR-O-R Do the reaction: CH₂OH + CH₂OH---→ + H-O-H 9. Write the reaction of formation of alcohol from alkene by adding water: Addition reaction also called hydration reaction as we are adding water which occur always in presence of acid Hint: Break the double bond and add H and OH if symmetrical then add anywhere if unsymmetrical then follow Markovnikov rule H should go to that double bone carbon which has more hydrogen CH2=CH2 + H₂O-→arrow_forwardComplete the reaction hand written pleasearrow_forward
- Predict the major products of this organic reaction: HBr (1 equiv) cold ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. dm Re Explanation Check ©2025 McGraw Hill LLC. All Rights Reserved. Termarrow_forwardb) Use curved arrows to show the reaction of the radical with hydrogen bromide. Br: Br H .. Answer Bankarrow_forwardIndicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning

Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning

Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning

Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning

General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY