(a) Interpretation: Two stereogenic centers in the given compound are to be labeled and all possible stereoisomers are to be drawn. Concept introduction: A compound exhibits large number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2 n . A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

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Answer 1

Question

Chapter 5.7, Problem 20P

Interpretation Introduction

(a)

Interpretation: Two stereogenic centers in the given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits large number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

Interpretation Introduction

(b)

Interpretation: Two stereogenic centers of given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Answer 2

Question

Chapter 5.7, Problem 20P

Interpretation Introduction

(a)

Interpretation: Two stereogenic centers in the given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits large number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

Interpretation Introduction

(b)

Interpretation: Two stereogenic centers of given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

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Answer 3

Question

Chapter 5.7, Problem 20P

Interpretation Introduction

(a)

Interpretation: Two stereogenic centers in the given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits large number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

Interpretation Introduction

(b)

Interpretation: Two stereogenic centers of given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

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Answer 4

Question

Chapter 5.7, Problem 20P

Interpretation Introduction

(a)

Interpretation: Two stereogenic centers in the given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits large number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

Interpretation Introduction

(b)

Interpretation: Two stereogenic centers of given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

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Answer 5

Chapter 5.7, Problem 20P

Interpretation Introduction

(a)

Interpretation: Two stereogenic centers in the given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits large number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

Interpretation Introduction

(b)

Interpretation: Two stereogenic centers of given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

Answer 6

Chapter 5.7, Problem 20P

Interpretation Introduction

(a)

Interpretation: Two stereogenic centers in the given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits large number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

Answer 7

Chapter 5.7, Problem 20P

Interpretation Introduction

(a)

Interpretation: Two stereogenic centers in the given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits large number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

Answer 8

Interpretation Introduction

(b)

Interpretation: Two stereogenic centers of given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

Answer 9

Interpretation Introduction

(b)

Interpretation: Two stereogenic centers of given compound are to be labeled and all possible stereoisomers are to be drawn.

Concept introduction: A compound exhibits number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with n number of stereogenic centers can show is 2n. A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center.

Answer 10

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Answer 11

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Answer 13

Ch. 5.1 - Prob. 1P Ch. 5.2 - Prob. 2P Ch. 5.3 - Draw the mirror image of each compound. Label each...Ch. 5.3 - Prob. 4P Ch. 5.3 - A molecule is achiral if it has a plane of...Ch. 5.6 - Prob. 17P Ch. 5.6 - Prob. 18P Ch. 5.7 - Prob. 19P Ch. 5.7 - Prob. 20P Ch. 5.7 - Problem 5.18 Compounds E and F are two isomers of...

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