Pearson eText Organic Chemistry -- Instant Access (Pearson+)

8th Edition

ISBN: 9780135213711

Author: Paula Bruice

Publisher: PEARSON+

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Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atom…

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Textbook Question

Chapter 5.6, Problem 18P

a. Which of the monosubstituted cyclohexanes in Table 3.9 on p. 128 has a negative·∆G°, for the conversion of an axial-substituted chair conformer to an equatorial-substituted chair conformer?

b. Which monosubstituted cyclohexane has the most negative ∆G° for this conversion?

c. Which monosubstituted cyclohexane has the greatest preference for an equatorial position?

d. Calculate ∆G° for the conversion of “axial methylcyclohexane to “equatorial” methylcyclohexane at 25°C.

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Chapter 5.5, Problem 17P

Chapter 5.6, Problem 20P

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Chapter 5 Solutions

Pearson eText Organic Chemistry -- Instant Access (Pearson+)

Ch. 5.1 - What is the molecular formula for each of the...Ch. 5.1 - Prob. 4P Ch. 5.1 - Determine the degree of unsaturation and then draw...Ch. 5.1 - Prob. 6P Ch. 5.2 - What is each compounds systematic name?Ch. 5.2 - Prob. 8P Ch. 5.2 - Draw the structure for each of the following: a....Ch. 5.3 - How many carbons are in the planar double-bond...Ch. 5.3 - Prob. 12P Ch. 5.5 - Prob. 13P

Ch. 5.5 - Prob. 14P Ch. 5.5 - Prob. 16P Ch. 5.5 - Prob. 17P Ch. 5.6 - a. Which of the monosubstituted cyclohexanes in...Ch. 5.6 - a. Calculate the percentage of isopropylcylohexane...Ch. 5.6 - a. for which reaction in each set will S be more...Ch. 5.6 - a. For a reaction with H = 12 kcal/ mol and S =...Ch. 5.8 - Prob. 23P Ch. 5.9 - Prob. 24P Ch. 5.9 - How many different alkenes can be hydrogenated to...Ch. 5.9 - The same alkane is obtained from the catalytic...Ch. 5.9 - Prob. 27P Ch. 5.9 - Rank the following compounds from most stable to...Ch. 5.10 - Prob. 29P Ch. 5.10 - Prob. 30P Ch. 5.11 - The rate constant for a reaction can be increased...Ch. 5.11 - Prob. 33P Ch. 5.11 - a. Which reaction has a greater equilibrium...Ch. 5.12 - Draw a reaction coordinate diagram for a two-step...Ch. 5.12 - a. Which step in the reaction coordinate diagram...Ch. 5.12 - Draw a reaction coordinate diagram for the...Ch. 5.13 - Prob. 38P Ch. 5 - What is each compounds systematic name?Ch. 5 - Prob. 40P Ch. 5 - Draw the structure of a hydrocarbon that has six...Ch. 5 - Draw the condensed structure for each of the...Ch. 5 - Prob. 43P Ch. 5 - Prob. 44P Ch. 5 - Prob. 45P Ch. 5 - Name the following:Ch. 5 - Prob. 47P Ch. 5 - Prob. 48P Ch. 5 - Prob. 49P Ch. 5 - In a reaction in which reactant A is in...Ch. 5 - Which bond is stronger? Briefly explain why.Ch. 5 - Prob. 52P Ch. 5 - Prob. 53P Ch. 5 - By following the curved red arrows, draw the...Ch. 5 - Prob. 55P Ch. 5 - Prob. 56P Ch. 5 - Draw structures for the following: a....Ch. 5 - Prob. 58P Ch. 5 - a. Which of the following reactions has the larger...Ch. 5 - Prob. 60P Ch. 5 - a. What is the equilibrium constant for a reaction...Ch. 5 - Prob. 62P Ch. 5 - Prob. 63P Ch. 5 - Given that the free energy of the twist-boat...Ch. 5 - Prob. 65P Ch. 5 - Prob. 1P Ch. 5 - Prob. 2P Ch. 5 - Prob. 3P Ch. 5 - Prob. 4P Ch. 5 - Prob. 5P Ch. 5 - Prob. 6P Ch. 5 - Draw curved arrows to show the movement of the...Ch. 5 - Prob. 8P Ch. 5 - Prob. 9P Ch. 5 - Prob. 10P

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Solution Summary: The author analyzes the equilibrium constant of monosubstituted cyclohexane at 25 0 C.

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