The electrophile reactant and nucleophile reactant in the given reaction has to be indicated. Concept introduction: Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge. Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

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Answer 1

Question

Chapter 5.5, Problem 16P

(a)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(b)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(c)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(d)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Answer 2

Question

Chapter 5.5, Problem 16P

(a)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(b)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(c)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(d)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

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Answer 3

Question

Chapter 5.5, Problem 16P

(a)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(b)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(c)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(d)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

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Answer 4

Question

Chapter 5.5, Problem 16P

(a)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(b)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(c)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(d)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

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Answer 5

Chapter 5.5, Problem 16P

(a)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(b)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(c)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

(d)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

Answer 6

Chapter 5.5, Problem 16P

(a)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

Answer 7

Chapter 5.5, Problem 16P

(a)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The electrophile reactant and nucleophile reactant in the given reaction has to be indicated.

Concept introduction:

Nucleophiles are the electron rich species and it can share at least a pair of electron. Nucleophiles have negative charge.

Electrophiles are electron deficient species; they look for a pair of electrons. An electrophile has a positive charge, a partial positive charge or an incomplete octet that can accept electron.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 5.1 - What is the molecular formula for each of the...Ch. 5.1 - Prob. 4P Ch. 5.1 - Determine the degree of unsaturation and then draw...Ch. 5.1 - Prob. 6P Ch. 5.2 - What is each compounds systematic name?Ch. 5.2 - Prob. 8P Ch. 5.2 - Draw the structure for each of the following: a....Ch. 5.3 - How many carbons are in the planar double-bond...Ch. 5.3 - Prob. 12P Ch. 5.5 - Prob. 13P

Solution Summary: The author explains that nucleophiles are electron rich species and can share at least a pair of electrons.

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