Chemistry
14th Edition
ISBN: 9781264243709
Author: Chang, Raymond
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Textbook Question
Chapter 5.2, Problem 2RCF
Rank the following pressures from lowest to highest: (a) 736 mmHg, (b) 0.928 atm, (c) 728 torr, (d) 1.12 × 105 Pa.
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Naming and drawing secondary
Write the systematic (IUPAC) name for each of the following organic molecules:
CH3
Z
structure
CH3
CH2
CH2
N-CH3
CH3-CH2-CH2-CH-CH3
NH
CH3-CH-CH2-CH2-CH2-CH2-CH2-CH3
Explanation
Check
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name
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This question shows how molecular orbital (MO) theory can be used to understand the chemical
properties of elemental oxygen O₂ and its anionic derivative superoxide Oz.
a)
Draw the MO energy diagram for both O2 and O2. Clearly label your diagram with atomic orbital names
and molecular orbital symmetry labels and include electrons.
Draw the Lewis structure of O2. How does the MO description of O2 differ from the Lewis structure, and
how does this difference relate to the high reactivity and magnetic properties of oxygen?
) Use the MO diagram in (a) to explain the difference in bond length and bond energy between superoxide
ion (Oz, 135 pm, 360 kJ/mol) and oxygen (O2, 120.8 pm, 494 kJ/mol).
Please draw
Chapter 5 Solutions
Chemistry
Ch. 5.2 - Prob. 1PECh. 5.2 - Prob. 2PECh. 5.2 - Express 1184 torr in units of mmHg, atm, and kPa.Ch. 5.2 - Rank the following pressures from lowest to...Ch. 5.2 - Prob. 3RCFCh. 5.3 - A gas occupies a volume of 2.50 L at 375 mmHg....Ch. 5.3 - Prob. 2RCFCh. 5.3 - What volume of ClF3 will be produced when 75.0 mL...Ch. 5.4 - Calculate the volume (in liters) occupied by 2.12...Ch. 5.4 - Prob. 4PE
Ch. 5.4 - A sample of chlorine gas occupies a volume of 946...Ch. 5.4 - Prob. 6PECh. 5.4 - A gas initially at 4.0 L, 1.2 atm, and 66C...Ch. 5.4 - What is the density (in g/L) of uranium...Ch. 5.4 - Prob. 9PECh. 5.4 - Prob. 10PECh. 5.4 - Prob. 1RCFCh. 5.4 - Prob. 2RCFCh. 5.4 - Prob. 3RCFCh. 5.5 - Prob. 11PECh. 5.5 - The equation for the metabolic breakdown of...Ch. 5.5 - Prob. 13PECh. 5.5 - Zinc metal reacts with hydrochloric acid according...Ch. 5.5 - Prob. 2RCFCh. 5.6 - Prob. 14PECh. 5.6 - Prob. 15PECh. 5.6 - Prob. 1RCFCh. 5.6 - Prob. 2RCFCh. 5.6 - Prob. 3RCFCh. 5.7 - Prob. 16PECh. 5.7 - Prob. 17PECh. 5.7 - Prob. 1RCFCh. 5.7 - Prob. 2RCFCh. 5.8 - Using the data shown in Table 5.4, calculate the...Ch. 5.8 - Prob. 1RCFCh. 5.8 - Prob. 2RCFCh. 5 - Prob. 5.1QPCh. 5 - Prob. 5.2QPCh. 5 - Prob. 5.3QPCh. 5 - Prob. 5.4QPCh. 5 - Prob. 5.5QPCh. 5 - Prob. 5.6QPCh. 5 - Prob. 5.7QPCh. 5 - Prob. 5.8QPCh. 5 - Prob. 5.9QPCh. 5 - Prob. 5.10QPCh. 5 - Prob. 5.11QPCh. 5 - Prob. 5.12QPCh. 5 - Convert 562 mmHg to atm.Ch. 5 - Prob. 5.14QPCh. 5 - Prob. 5.15QPCh. 5 - A gaseous sample of a substance is cooled at...Ch. 5 - Consider the following gaseous sample in a...Ch. 5 - Prob. 5.19QPCh. 5 - Prob. 5.20QPCh. 5 - Prob. 5.21QPCh. 5 - A sample of air occupies 3.8 L when the pressure...Ch. 5 - Prob. 5.23QPCh. 5 - Under constant-pressure conditions a sample of...Ch. 5 - Ammonia burns in oxygen gas to form nitric oxide...Ch. 5 - Molecular chlorine and molecular fluorine combine...Ch. 5 - Prob. 5.27QPCh. 5 - Prob. 5.28QPCh. 5 - Prob. 5.29QPCh. 5 - Prob. 5.30QPCh. 5 - Prob. 5.31QPCh. 5 - Given that 6.9 moles of carbon monoxide gas are...Ch. 5 - What volume will 5.6 moles of sulfur hexafluoride...Ch. 5 - Prob. 5.34QPCh. 5 - Prob. 5.35QPCh. 5 - Prob. 5.36QPCh. 5 - Prob. 5.37QPCh. 5 - Prob. 5.38QPCh. 5 - An ideal gas originally at 0.85 atm and 66C was...Ch. 5 - Prob. 5.40QPCh. 5 - Prob. 5.41QPCh. 5 - Dry ice is solid carbon dioxide. A 0.050-g sample...Ch. 5 - Prob. 5.43QPCh. 5 - At 741 torr and 44C, 7.10 g of a gas occupy a...Ch. 5 - Ozone molecules in the stratosphere absorb much of...Ch. 5 - Prob. 5.46QPCh. 5 - A 2.10-L vessel contains 4.65 g of a gas at 1.00...Ch. 5 - Calculate the density of hydrogen bromide (HBr)...Ch. 5 - A certain anesthetic contains 64.9 percent C, 13.5...Ch. 5 - A compound has the empirical formula SF4. At 20C,...Ch. 5 - Prob. 5.51QPCh. 5 - The density of a mixture of fluorine and chlorine...Ch. 5 - Consider the formation of nitrogen dioxide from...Ch. 5 - Methane, the principal component of natural gas,...Ch. 5 - When coal is burned, the sulfur present in coal is...Ch. 5 - In alcohol fermentation, yeast converts glucose to...Ch. 5 - Prob. 5.57QPCh. 5 - A quantity of 0.225 g of a metal M (molar mass =...Ch. 5 - What is the mass of the solid NH4Cl formed when...Ch. 5 - Prob. 5.60QPCh. 5 - Prob. 5.61QPCh. 5 - Ethanol (C2H5OH) burns in air:...Ch. 5 - (a) What volumes (in liters) of ammonia and oxygen...Ch. 5 - Prob. 5.64QPCh. 5 - Prob. 5.65QPCh. 5 - A sample of air contains only nitrogen and oxygen...Ch. 5 - A mixture of gases contains 0.31 mol CH4, 0.25 mol...Ch. 5 - A 2.5-L flask at 15C contains a mixture of N2, He,...Ch. 5 - Dry air near sea level has the following...Ch. 5 - Prob. 5.70QPCh. 5 - Prob. 5.71QPCh. 5 - A sample of zinc metal reacts completely with an...Ch. 5 - Prob. 5.73QPCh. 5 - A sample of ammonia (NH3) gas is completely...Ch. 5 - Prob. 5.75QPCh. 5 - The volume of the box on the right is twice that...Ch. 5 - Prob. 5.78QPCh. 5 - Prob. 5.79QPCh. 5 - Prob. 5.80QPCh. 5 - Compare the root-mean-square speeds of O2 and UF6...Ch. 5 - Prob. 5.82QPCh. 5 - The average distance traveled by a molecule...Ch. 5 - At a certain temperature the speeds of six gaseous...Ch. 5 - Prob. 5.85QPCh. 5 - The 235U isotope undergoes fission when bombarded...Ch. 5 - Prob. 5.87QPCh. 5 - Prob. 5.88QPCh. 5 - Prob. 5.90QPCh. 5 - (a) A real gas is introduced into a flask of...Ch. 5 - Using the data shown in Table 5.4, calculate the...Ch. 5 - Prob. 5.94QPCh. 5 - Prob. 5.95QPCh. 5 - Prob. 5.96QPCh. 5 - Prob. 5.97QPCh. 5 - Prob. 5.98QPCh. 5 - When ammonium nitrite (NH4NO2) is heated, it...Ch. 5 - The percent by mass of bicarbonate (HCO3) in a...Ch. 5 - Prob. 5.101QPCh. 5 - Prob. 5.102QPCh. 5 - Prob. 5.103QPCh. 5 - A healthy adult exhales about 5.0 102 mL of a...Ch. 5 - Prob. 5.105QPCh. 5 - Prob. 5.106QPCh. 5 - Some commercial drain cleaners contain a mixture...Ch. 5 - The volume of a sample of pure HCl gas was 189 mL...Ch. 5 - Prob. 5.109QPCh. 5 - Prob. 5.110QPCh. 5 - Prob. 5.111QPCh. 5 - Prob. 5.112QPCh. 5 - Prob. 5.113QPCh. 5 - Prob. 5.114QPCh. 5 - Prob. 5.115QPCh. 5 - Prob. 5.116QPCh. 5 - Prob. 5.117QPCh. 5 - Commercially, compressed oxygen is sold in metal...Ch. 5 - Prob. 5.119QPCh. 5 - Prob. 5.120QPCh. 5 - Prob. 5.121QPCh. 5 - Prob. 5.122QPCh. 5 - Prob. 5.123QPCh. 5 - Prob. 5.124QPCh. 5 - Prob. 5.125QPCh. 5 - Prob. 5.126QPCh. 5 - Prob. 5.127QPCh. 5 - Prob. 5.128QPCh. 5 - Acidic oxides such as carbon dioxide react with...Ch. 5 - Prob. 5.130QPCh. 5 - Prob. 5.131QPCh. 5 - Prob. 5.132QPCh. 5 - Atop Mt. Everest, the atmospheric pressure is 210...Ch. 5 - Prob. 5.134QPCh. 5 - Prob. 5.135QPCh. 5 - Prob. 5.136QPCh. 5 - Prob. 5.137QPCh. 5 - Prob. 5.138QPCh. 5 - Prob. 5.139QPCh. 5 - Prob. 5.140QPCh. 5 - Prob. 5.141QPCh. 5 - Prob. 5.142QPCh. 5 - Prob. 5.143QPCh. 5 - Prob. 5.144QPCh. 5 - Prob. 5.145QPCh. 5 - At what temperature will He atoms have the same...Ch. 5 - Prob. 5.148QPCh. 5 - Prob. 5.149QPCh. 5 - Prob. 5.150QPCh. 5 - Prob. 5.151QPCh. 5 - Prob. 5.152QPCh. 5 - Prob. 5.153QPCh. 5 - A 6.11-g sample of a Cu-Zn alloy reacts with HCl...Ch. 5 - Prob. 5.155QPCh. 5 - Prob. 5.156QPCh. 5 - Prob. 5.157QPCh. 5 - A mixture of methane (CH4) and ethane (C2H6) is...Ch. 5 - Prob. 5.159QPCh. 5 - One way to gain a physical understanding of b in...Ch. 5 - Use the van der Waals constants in Table 5.4. to...Ch. 5 - Prob. 5.162QPCh. 5 - Prob. 5.163QPCh. 5 - Prob. 5.164QPCh. 5 - Referring to Figure 5.17, we see that the maximum...Ch. 5 - Prob. 5.166QPCh. 5 - A gaseous hydrocarbon (containing C and H atoms)...Ch. 5 - Three flasks (a)(c) contain gases A (red) and B...Ch. 5 - Prob. 5.169QPCh. 5 - Prob. 5.170QPCh. 5 - In 2012, Felix Baumgartner jumped from a balloon...Ch. 5 - Prob. 5.172QPCh. 5 - A flask with a volume of 14.5 L contains 1.25...Ch. 5 - Prob. 5.174QPCh. 5 - Prob. 5.175QPCh. 5 - Prob. 5.176QPCh. 5 - Prob. 5.177QP
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