ORGANIC CHEMISTRY (LOOSELEAF)
6th Edition
ISBN: 9781260475630
Author: SMITH
Publisher: MCG
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Question
Chapter 5.10, Problem 29P
Interpretation Introduction
(a)
Interpretation: All possible stereoisomers for the given compound are to be drawn and pairs of enantiomers and diastereomers are to be labeled.
Concept introduction: A disubstituted cycloalkane has two stereogenic centers. One should follow the given steps, while drawing all possible stereoisomers of a disubstituted cycloalkane. In first step, the cis and trans isomers of disubstituted cycloalkane is drawn. These isomers are diastereomers (stereoisomers that are not mirror images of each other). In second step, the mirror images of cis and trans isomers are to be drawn.
Interpretation Introduction
(b)
Interpretation: The all possible stereoisomers for given compound is to be drawn and pairs of enantiomers and diastereomers are to be labeled.
Concept introduction: A disubstituted cycloalkane has two stereogenic centers. One should follow the given steps, while drawing all possible stereoisomers of a disubstituted cycloalkane. In first step, the cis and trans isomers of disubstituted cycloalkane is drawn. These isomers are diastereomers (stereoisomers that are not mirror images of each other). In second step, the mirror images of cis and trans isomers are to be drawn.
Interpretation Introduction
(c)
Interpretation: The all possible stereoisomers for given compound is to be drawn and pairs of enantiomers and diastereomers are to be labeled.
Concept introduction: A disubstituted cycloalkane has two stereogenic centers. One should follow the given steps, while drawing all possible stereoisomers of a disubstituted cycloalkane. In first step, the cis and trans isomers of disubstituted cycloalkane is drawn. These isomers are diastereomers (stereoisomers that are not mirror images of each other). In second step, the mirror images of cis and trans isomers are to be drawn.
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Draw the most stable chair conformation of 1-ethyl-1-methylcyclohexane, clearly showing the axial and equatorial substituents. [4]
Draw structures corresponding to the following IUPAC name for each of the following compounds; [5]
i) 4-Isopropyl-2,4,5-trimethylheptane
ii) trans-1-tert-butyl-4-ethylcyclohexane
iii) Cyclobutylcycloheptane
iv) cis-1,4-di-isopropylcyclohexane (chair conformation)
v) 3-Ethyl-5-isobutylnonane
Draw and name molecules that meet the following descriptions; [4]
a) An organic molecule containing 2 sp2 hybridised carbon and 1 sp-hybridised carbon atom.
b) A cycloalkene, C7H12, with a tetrasubstituted double bond.
Also answer question 2 from the image
H
14. Draw the line angle form of the following molecule make sure you use the proper
notation to indicate spatial positioning of atoms.
F
F
H
15. Convert the following condensed form to line angle form:
(CH3)3CCH2COCH2CON(CH2CH3)2
Chapter 5 Solutions
ORGANIC CHEMISTRY (LOOSELEAF)
Ch. 5.1 - Prob. 1PCh. 5.2 - Prob. 2PCh. 5.3 - Draw the mirror image of each compound. Label each...Ch. 5.3 - Prob. 4PCh. 5.3 - A molecule is achiral if it has a plane of...Ch. 5.6 - Prob. 17PCh. 5.6 - Prob. 18PCh. 5.7 - Prob. 19PCh. 5.7 - Prob. 20PCh. 5.7 - Problem 5.18 Compounds E and F are two isomers of...
Ch. 5.8 - Prob. 22PCh. 5.8 - Prob. 23PCh. 5.8 - Prob. 24PCh. 5.9 - Prob. 25PCh. 5.9 - Prob. 26PCh. 5.9 - Prob. 27PCh. 5.10 - Which of the following cyclic molecules are meso...Ch. 5.10 - Prob. 29PCh. 5.11 - Prob. 30PCh. 5.12 - Problem 5.28 The amino acid has the physical...Ch. 5.12 - Prob. 32PCh. 5.12 - Prob. 33PCh. 5.12 - Prob. 34PCh. 5.12 - Prob. 35PCh. 5 - Prob. 39PCh. 5 - Prob. 40PCh. 5 - Prob. 41PCh. 5 - Prob. 42PCh. 5 - 5.40 Determine if each compound is identical to or...Ch. 5 - Prob. 44PCh. 5 - Prob. 45PCh. 5 - Prob. 46PCh. 5 - Prob. 47PCh. 5 - Prob. 48PCh. 5 - Prob. 52PCh. 5 - Prob. 56PCh. 5 - Prob. 61PCh. 5 - Prob. 67PCh. 5 - Prob. 68PCh. 5 - Prob. 69PCh. 5 -
5.67 Artemisinin and mefloquine are widely used...Ch. 5 - 5.68 Saquinavir (trade name Invirase) is a...Ch. 5 - Prob. 72P
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