GENERAL, ORGANIC, BIOCHEM (LL W/ ACCESS)
10th Edition
ISBN: 9781260885958
Author: Denniston
Publisher: MCG
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Chapter 5.1, Problem 5.7PP
Interpretation Introduction
Interpretation:
Moles of the nitrogen gas that will occupy
Concept Introduction:
Where,
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32. Consider a two-state system in which the low energy level is 300 J mol 1 and the higher energy
level is 800 J mol 1, and the temperature is 300 K. Find the population of each level. Hint: Pay attention
to your units.
A. What is the partition function for this system?
B. What are the populations of each level?
Now instead, consider a system with energy levels of 0 J mol
C. Now what is the partition function?
D. And what are the populations of the two levels?
E. Finally, repeat the second calculation at 500 K.
and 500 J mol 1 at 300 K.
F. What do you notice about the populations as you increase the temperature? At what temperature
would you expect the states to have equal populations?
30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in
class, but the partition function that describes the translational and rotational motion of a homonuclear
diatomic molecule is given by
Itrans (V,T) =
=
2πmkBT
h²
V
grot (T)
4π²IKBT
h²
Where h is Planck's constant and I is molecular moment of inertia.
The overall partition function is qmolec Qtrans qrot.
Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational
modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a
volume of 1 m³. Here is some useful data:
Moment of inertia:
I2 I 7.46 x 10-
45
kg m²
2
O2 I 1.91 x 101
-46
kg m²
K
for each reaction step.
Be sure to account for all bond-breaking and bond-making
steps.
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Chapter 5 Solutions
GENERAL, ORGANIC, BIOCHEM (LL W/ ACCESS)
Ch. 5.1 - Prob. 5.1QCh. 5.1 - Prob. 5.2QCh. 5.1 - Prob. 5.1PPCh. 5.1 - Prob. 5.2PPCh. 5.1 - Prob. 5.3PPCh. 5.1 - Prob. 5.4PPCh. 5.1 - Prob. 5.5PPCh. 5.1 - Prob. 5.6PPCh. 5.1 - Prob. 5.7PPCh. 5.1 - Prob. 5.8PP
Ch. 5.1 - Prob. 5.3QCh. 5.1 - Prob. 5.4QCh. 5.1 - Prob. 5.5QCh. 5.1 - Prob. 5.6QCh. 5.2 - Prob. 5.7QCh. 5.2 - Prob. 5.8QCh. 5.2 - Prob. 5.9QCh. 5.2 - Prob. 5.10QCh. 5.2 - Prob. 5.11QCh. 5.2 - Prob. 5.12QCh. 5.3 - Prob. 5.13QCh. 5.3 - Prob. 5.14QCh. 5 - Prob. 5.15QPCh. 5 - Prob. 5.16QPCh. 5 - Prob. 5.17QPCh. 5 - Prob. 5.18QPCh. 5 - Prob. 5.19QPCh. 5 - Prob. 5.20QPCh. 5 - Prob. 5.21QPCh. 5 - Prob. 5.22QPCh. 5 - Prob. 5.23QPCh. 5 - Prob. 5.24QPCh. 5 - Prob. 5.25QPCh. 5 - Prob. 5.26QPCh. 5 - Prob. 5.27QPCh. 5 - Prob. 5.28QPCh. 5 - Prob. 5.29QPCh. 5 - Prob. 5.30QPCh. 5 - Prob. 5.31QPCh. 5 - Prob. 5.32QPCh. 5 - Prob. 5.33QPCh. 5 - Prob. 5.34QPCh. 5 - Prob. 5.35QPCh. 5 - Prob. 5.36QPCh. 5 - Prob. 5.37QPCh. 5 - Prob. 5.38QPCh. 5 - Calculate the pressure, in atm, required to...Ch. 5 - A balloon filled with helium gas at 1.00 atm...Ch. 5 - Prob. 5.41QPCh. 5 - Prob. 5.42QPCh. 5 - Prob. 5.43QPCh. 5 - The temperature on a summer day may be 90°F....Ch. 5 - Prob. 5.45QPCh. 5 - Prob. 5.46QPCh. 5 - Prob. 5.47QPCh. 5 - Prob. 5.48QPCh. 5 - A balloon containing a sample of helium gas is...Ch. 5 - The balloon described in Question 5.49 was then...Ch. 5 - Prob. 5.51QPCh. 5 - A balloon, filled with an ideal gas, has a volume...Ch. 5 - Prob. 5.53QPCh. 5 - Prob. 5.54QPCh. 5 - Prob. 5.55QPCh. 5 - Prob. 5.56QPCh. 5 - Prob. 5.57QPCh. 5 - A sealed balloon filled with helium gas occupies...Ch. 5 - A 5.00-L balloon exerts a pressure of 2.00 atm at...Ch. 5 - If we double the pressure and temperature of the...Ch. 5 - State Avogadro’s law in words.
Ch. 5 - Prob. 5.62QPCh. 5 - Prob. 5.63QPCh. 5 - Prob. 5.64QPCh. 5 - Prob. 5.65QPCh. 5 - Prob. 5.66QPCh. 5 - Prob. 5.67QPCh. 5 - Prob. 5.68QPCh. 5 - Prob. 5.69QPCh. 5 - Prob. 5.70QPCh. 5 - Prob. 5.71QPCh. 5 - Prob. 5.72QPCh. 5 - Prob. 5.73QPCh. 5 - Prob. 5.74QPCh. 5 - Prob. 5.75QPCh. 5 - Calculate the pressure (atm) exerted by 1.00 mol...Ch. 5 - A sample of argon (Ar) gas occupies 65.0 mL at...Ch. 5 - A sample of O2 gas occupies 257 mL at 20°C and...Ch. 5 - Prob. 5.79QPCh. 5 - Prob. 5.80QPCh. 5 - Prob. 5.81QPCh. 5 - Calculate the volume of 6.00 mol O2 gas at 30 cm...Ch. 5 - State Dalton’s law in words.
Ch. 5 - Prob. 5.84QPCh. 5 - Prob. 5.85QPCh. 5 - Prob. 5.86QPCh. 5 - Prob. 5.87QPCh. 5 - Prob. 5.88QPCh. 5 - Prob. 5.89QPCh. 5 - Prob. 5.90QPCh. 5 - Prob. 5.91QPCh. 5 - Prob. 5.92QPCh. 5 - Prob. 5.93QPCh. 5 - Prob. 5.94QPCh. 5 - Prob. 5.95QPCh. 5 - Prob. 5.96QPCh. 5 - Prob. 5.97QPCh. 5 - Prob. 5.98QPCh. 5 - Prob. 5.99QPCh. 5 - Prob. 5.100QPCh. 5 - Prob. 5.101QPCh. 5 - Prob. 5.102QPCh. 5 - Prob. 5.103QPCh. 5 - Prob. 5.104QPCh. 5 - Prob. 5.105QPCh. 5 - Prob. 5.106QPCh. 5 - Prob. 5.107QPCh. 5 - Prob. 5.108QPCh. 5 - Prob. 5.109QPCh. 5 - Prob. 5.110QPCh. 5 - Prob. 5.111QPCh. 5 - Prob. 5.112QPCh. 5 - Prob. 2MCPCh. 5 - Prob. 5MCPCh. 5 - Prob. 6MCPCh. 5 - Prob. 8MCPCh. 5 - Prob. 9MCPCh. 5 - Prob. 10MCP
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