ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.)
4th Edition
ISBN: 9781119761068
Author: Klein
Publisher: WILEY
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Chapter 5.1, Problem 5.4P
Interpretation Introduction
Interpretation:
Given compound can whether work as a suitable electrophile in a nucleophilic
Concept introduction:
Criteria for nucleophilic aromatic substitution:
- An electron withdrawing group must be present on the ring.
- A leaving group should be present on the ring.
- The orientation of leaving group should be ortho or para to the electron-withdrawing group.
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Given the reaction R+ Q → P, indicate
(A). the rate law with respect to P:
(B). the rate law with respect to R:
(C). the rate law with respect to Q:
d[P]
dt
d[R]
dt
d[Q]
dt
The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)?
b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Chapter 5 Solutions
ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.)
Ch. 5.1 - Prob. 5.2PCh. 5.1 - Prob. 5.3PCh. 5.1 - Prob. 5.4PCh. 5.1 - Prob. 5.5PCh. 5.1 - Prob. 5.6PCh. 5.1 - Prob. 5.7PCh. 5.2 - Propose a mechanism for each of the following...Ch. 5.2 - Propose a mechanism for each of the following...Ch. 5.2 - Propose a mechanism for each of the following...Ch. 5.3 - Prob. 5.13P
Ch. 5.3 - Prob. 5.14PCh. 5.3 - Prob. 5.15PCh. 5.3 - Prob. 5.16PCh. 5.3 - Prob. 5.17PCh. 5.3 - Prob. 5.18PCh. 5.4 - Propose a mechanism for each of the following...Ch. 5.4 - Propose a mechanism for each of the following...Ch. 5.4 - Propose a mechanism for each of the following...Ch. 5.4 - Propose a mechanism for each of the following...
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