The given table is to be completed by determining the formula, type (ionic, molecular or acid) and name of the given compound. Concept Introduction: Ionic compounds are formed between the metals and non-metals. The naming of ionic compounds which contains a metal forming only one type of ion is as follows: name of the cation (metal) + base name of anion(nonmetal) + − ide The compounds which are composed of non-metals are known as molecular compounds. The molecular compounds are named by writing the name of first element with the prefix. This is followed by the prefix of second element and suffix ‘-ide’ is placed on the end of the name of second element. The prefixes are written to indicate the number of atoms present in the compound. Oxyacids are the combination of one or more hydrogen ions with an oxyanion. The naming of these acids depends on the ending of the oxyanion. The naming of oxyacids ending with –ate is as follows: First base name of oxyanion is written followed by the suffix –ic to it and then, the word acid follows it.

Question

bre The reaction sequence shown in Scheme 5 demonstrates the synthesis of a substituted benzene derivative Q. wolsd works 2 NH2 NaNO2, HCI (apexe) 13× (1 HNO3, H2SO4 C6H5CIN2 0°C HOTE CHINO₂ N O *O₂H ( PO Q Я Scheme 5 2 bag abouoqmics to sounde odi WEIC (i) Draw the structure of intermediate O. [2 marks] to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa (ii) Draw the mechanism for the transformation of aniline N to intermediate O. Spoilage (b) [6 marks] (iii) Identify the reagent X used to convert compound O to the iodinated compound [tom E P. vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx (iv) Identify the possible structures of compound Q. [2 marks] [2 marks] [shom 2] (v) bus noires goiribbeolovo xnivollot adj to subora sidab Draw the mechanism for the transformation of intermediate P to compound Q. [5 marks] vi (vi) Account for the regiochemical outcome observed in the reaction forming compound Q. [3 marks]

Answer 1

Question

Chapter 5, Problem 93E

Interpretation Introduction

Interpretation:

The given table is to be completed by determining the formula, type (ionic, molecular or acid) and name of the given compound.

Concept Introduction:

Ionic compounds are formed between the metals and non-metals.

The naming of ionic compounds which contains a metal forming only one type of ion is as follows:

name of the cation (metal)+base name of anion(nonmetal)+−ide

The compounds which are composed of non-metals are known as molecular compounds. The molecular compounds are named by writing the name of first element with the prefix. This is followed by the prefix of second element and suffix ‘-ide’ is placed on the end of the name of second element. The prefixes are written to indicate the number of atoms present in the compound.

Oxyacids are the combination of one or more hydrogen ions with an oxyanion. The naming of these acids depends on the ending of the oxyanion. The naming of oxyacids ending with –ate is as follows:

First base name of oxyanion is written followed by the suffix –ic to it and then, the word acid follows it.

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bre The reaction sequence shown in Scheme 5 demonstrates the synthesis of a substituted benzene derivative Q. wolsd works 2 NH2 NaNO2, HCI (apexe) 13× (1 HNO3, H2SO4 C6H5CIN2 0°C HOTE CHINO₂ N O *O₂H ( PO Q Я Scheme 5 2 bag abouoqmics to sounde odi WEIC (i) Draw the structure of intermediate O. [2 marks] to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa (ii) Draw the mechanism for the transformation of aniline N to intermediate O. Spoilage (b) [6 marks] (iii) Identify the reagent X used to convert compound O to the iodinated compound [tom E P. vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx (iv) Identify the possible structures of compound Q. [2 marks] [2 marks] [shom 2] (v) bus noires goiribbeolovo xnivollot adj to subora sidab Draw the mechanism for the transformation of intermediate P to compound Q. [5 marks] vi (vi) Account for the regiochemical outcome observed in the reaction forming compound Q. [3 marks]

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