Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Relative Transmittance
0.995
0.99
0.985
0.98
Please draw the structure that is consistent with all the spectral data below in the box and
alphabetically label the equivalent protons in the structure (Ha, Hb, Hc ....) in order to assign all the
proton NMR peaks. Label the absorption bands in the IR spectrum indicated by the arrows.
INFRARED SPECTRUM
1
0.975
3000
2000
Wavenumber (cm-1)
1000
Structure with assigned H peaks
1
3
180 160 140 120
100
f1 (ppm)
80 60
40
20
0
C-13 NMR
note that there are 4
peaks between 120-140ppm
Integral values equal
the number of
equivalent protons
10.0
9.0
8.0
7.0
6.0
5.0
4.0
3.0
2.0
1.0
0.0
fl (ppm)
Calculate the pH of 0.0025 M phenol.
In the following reaction, the OH- acts as which of these?
NO2-(aq) + H2O(l) ⇌ OH-(aq) + HNO2(aq)
Chapter 5 Solutions
Chemistry: An Atoms-Focused Approach
Ch. 5 - Prob. 5.1VPCh. 5 - Prob. 5.2VPCh. 5 - Prob. 5.3VPCh. 5 - Prob. 5.4VPCh. 5 - Prob. 5.5VPCh. 5 - Prob. 5.6VPCh. 5 - Prob. 5.7VPCh. 5 - Prob. 5.8VPCh. 5 - Prob. 5.9VPCh. 5 - Prob. 5.10VP
Ch. 5 - Prob. 5.11QACh. 5 - Prob. 5.12QACh. 5 - Prob. 5.13QACh. 5 - Prob. 5.14QACh. 5 - Prob. 5.15QACh. 5 - Prob. 5.16QACh. 5 - Prob. 5.17QACh. 5 - Prob. 5.18QACh. 5 - Prob. 5.19QACh. 5 - Prob. 5.20QACh. 5 - Prob. 5.21QACh. 5 - Prob. 5.22QACh. 5 - Prob. 5.23QACh. 5 - Prob. 5.24QACh. 5 - Prob. 5.25QACh. 5 - Prob. 5.26QACh. 5 - Prob. 5.27QACh. 5 - Prob. 5.28QACh. 5 - Prob. 5.29QACh. 5 - Prob. 5.30QACh. 5 - Prob. 5.31QACh. 5 - Prob. 5.32QACh. 5 - Prob. 5.33QACh. 5 - Prob. 5.34QACh. 5 - Prob. 5.35QACh. 5 - Prob. 5.36QACh. 5 - Prob. 5.37QACh. 5 - Prob. 5.38QACh. 5 - Prob. 5.39QACh. 5 - Prob. 5.40QACh. 5 - Prob. 5.41QACh. 5 - Prob. 5.42QACh. 5 - Prob. 5.43QACh. 5 - Prob. 5.44QACh. 5 - Prob. 5.45QACh. 5 - Prob. 5.46QACh. 5 - Prob. 5.47QACh. 5 - Prob. 5.48QACh. 5 - Prob. 5.49QACh. 5 - Prob. 5.50QACh. 5 - Prob. 5.51QACh. 5 - Prob. 5.52QACh. 5 - Prob. 5.54QACh. 5 - Prob. 5.55QACh. 5 - Prob. 5.56QACh. 5 - Prob. 5.57QACh. 5 - Prob. 5.58QACh. 5 - Prob. 5.59QACh. 5 - Prob. 5.60QACh. 5 - Prob. 5.61QACh. 5 - Prob. 5.62QACh. 5 - Prob. 5.63QACh. 5 - Prob. 5.64QACh. 5 - Prob. 5.65QACh. 5 - Prob. 5.66QACh. 5 - Prob. 5.67QACh. 5 - Prob. 5.68QACh. 5 - Prob. 5.69QACh. 5 - Prob. 5.70QACh. 5 - Prob. 5.71QACh. 5 - Prob. 5.72QACh. 5 - Prob. 5.73QACh. 5 - Prob. 5.74QACh. 5 - Prob. 5.75QACh. 5 - Prob. 5.76QACh. 5 - Prob. 5.77QACh. 5 - Prob. 5.78QACh. 5 - Prob. 5.79QACh. 5 - Prob. 5.80QACh. 5 - Prob. 5.81QACh. 5 - Prob. 5.82QACh. 5 - Prob. 5.83QACh. 5 - Prob. 5.84QACh. 5 - Prob. 5.85QACh. 5 - Prob. 5.86QACh. 5 - Prob. 5.87QACh. 5 - Prob. 5.88QACh. 5 - Prob. 5.89QACh. 5 - Prob. 5.90QACh. 5 - Prob. 5.91QACh. 5 - Prob. 5.92QACh. 5 - Prob. 5.93QACh. 5 - Prob. 5.94QACh. 5 - Prob. 5.95QACh. 5 - Prob. 5.96QACh. 5 - Prob. 5.97QACh. 5 - Prob. 5.98QACh. 5 - Prob. 5.99QACh. 5 - Prob. 5.100QACh. 5 - Prob. 5.101QACh. 5 - Prob. 5.102QACh. 5 - Prob. 5.103QACh. 5 - Prob. 5.104QACh. 5 - Prob. 5.105QACh. 5 - Prob. 5.106QACh. 5 - Prob. 5.107QACh. 5 - Prob. 5.108QACh. 5 - Prob. 5.109QACh. 5 - Prob. 5.110QACh. 5 - Prob. 5.111QACh. 5 - Prob. 5.112QACh. 5 - Prob. 5.113QACh. 5 - Prob. 5.114QACh. 5 - Prob. 5.115QACh. 5 - Prob. 5.116QACh. 5 - Prob. 5.117QACh. 5 - Prob. 5.118QACh. 5 - Prob. 5.119QACh. 5 - Prob. 5.120QACh. 5 - Prob. 5.121QACh. 5 - Prob. 5.122QACh. 5 - Prob. 5.123QACh. 5 - Prob. 5.124QACh. 5 - Prob. 5.125QACh. 5 - Prob. 5.126QACh. 5 - Prob. 5.127QACh. 5 - Prob. 5.128QACh. 5 - Prob. 5.129QACh. 5 - Prob. 5.130QACh. 5 - Prob. 5.131QACh. 5 - Prob. 5.132QA
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- Using spectra attached, can the unknown be predicted? Draw the predicition. Please explain and provide steps. Molecular focrmula:C16H13ClOarrow_forwardCalculate the percent ionization for 0.0025 M phenol. Use the assumption to find [H3O+] first. K = 1.0 x 10-10arrow_forwardThe Ka for sodium dihydrogen phosphate is 6.32 x 10-8. Find the pH of a buffer made from 0.15 M H2PO4- and 0.25 M HPO42- .arrow_forward
- The Ka for lactic acid is 1.4 x 10-4. Find the pH of a buffer made from 0.066 M lactic acid and 0.088 M sodium lactate.arrow_forwardZaitsev's Rule 3) (a) Rank the following alkenes in order of decreasing stability. most stable A B C D > > > (b) Rank the following carbocations in order of decreasing stability least stable B C Darrow_forwardCalculate the pH of 0.25 M acetic acid.arrow_forward
- For each of the following reactions: Fill in the missing reactant, reagent, or product (s), indicating stereochemistry where appropriate using dashed and wedged bonds. If the reaction forms a racemic mixture, draw both structures in the box and write the word “racemic”.arrow_forward5) Using the carbon-containing starting material(s), propose a synthesis based on the following retrosynthetic analysis. Provide structures for all intermediates. The carbon atoms in the product must originate from the starting material(s), but you may use as many equivalents of each starting material as you would like, and any reagent/reaction you know (note: no mechanisms are required). H H =arrow_forwardCalculate the percent ionization for 0.0025 M phenol. Use the assumption to find [H3O+] first. K = 1.0 x 10-10arrow_forward
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