Chemistry (7th Edition)
7th Edition
ISBN: 9780321943170
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 5, Problem 5.2A
Interpretation Introduction
To determine:
- The highest frequency wave.
- A wave which represents more intense beam of light
- A wave which represents blue light and red light.
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
Check
Br
(Choose one)
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
O
HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
OA
B
OC
ch
B
C
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 5 Solutions
Chemistry (7th Edition)
Ch. 5 - Prob. 5.1PCh. 5 - Conceptual APPLY 5.2 Two electromagnetic waves are...Ch. 5 - PRACTICE 5.3 The biological effects of a given...Ch. 5 - Prob. 5.4ACh. 5 - Prob. 5.5PCh. 5 - Conceptual APPLY 5.6 Compare the two elements Rb...Ch. 5 - PRACTICE 5.7 The Balmer equation can be extended...Ch. 5 - APPLY 5.8 (a) What is the longest-wavelength line...Ch. 5 - Prob. 5.9PCh. 5 - Prob. 5.10A
Ch. 5 - Prob. 5.11PCh. 5 - APPLY 5.10 Extend Table 5.2 to show allowed...Ch. 5 - Conceptual PRACTICE 5.13 Give a possible...Ch. 5 - Conceptual APPLY 5.14 How many nodal planes...Ch. 5 - Prob. 5.15PCh. 5 - Conceptual APPLY 5.16 Identify the atoms with the...Ch. 5 - Prob. 5.17PCh. 5 - APPLY 5.18 Predict which bond length will be the...Ch. 5 - PROBLEM 5.19 Mercury vapor is contained inside the...Ch. 5 - PROBLEM 5.20 When electricity is used to add...Ch. 5 - Prob. 5.21PCh. 5 - PROBLEM 5.22 Three different wavelengths in the...Ch. 5 - Prob. 5.23PCh. 5 - Two electromagnetic waves are represented below....Ch. 5 - The following diagram shows the energy levels of...Ch. 5 - Identify each of the following orbitals, and give...Ch. 5 - Where on the blank outline of the periodic table...Ch. 5 - One of the elements shown on the following...Ch. 5 - What atom has the following orbital-filling...Ch. 5 - The following orbital-filling diagram represents...Ch. 5 - Prob. 5.31CPCh. 5 - Which has the higher frequency, red light or...Ch. 5 - Prob. 5.33SPCh. 5 - The Hubble Space Telescope detects electromagnetic...Ch. 5 - Prob. 5.35SPCh. 5 - Prob. 5.36SPCh. 5 - Prob. 5.37SPCh. 5 - Prob. 5.38SPCh. 5 - Prob. 5.39SPCh. 5 - Prob. 5.40SPCh. 5 - Prob. 5.41SPCh. 5 - Prob. 5.42SPCh. 5 - Prob. 5.43SPCh. 5 - Prob. 5.44SPCh. 5 - Prob. 5.45SPCh. 5 - Prob. 5.46SPCh. 5 - Prob. 5.47SPCh. 5 - Prob. 5.48SPCh. 5 - Prob. 5.49SPCh. 5 - Prob. 5.50SPCh. 5 - Prob. 5.51SPCh. 5 - Prob. 5.52SPCh. 5 - Prob. 5.53SPCh. 5 - Prob. 5.54SPCh. 5 - Prob. 5.55SPCh. 5 - Spectroscopy is a technique that uses the...Ch. 5 - Prob. 5.57SPCh. 5 - Prob. 5.58SPCh. 5 - Prob. 5.59SPCh. 5 - Prob. 5.60SPCh. 5 - Prob. 5.61SPCh. 5 - Prob. 5.62SPCh. 5 - What velocity would an electron ( mass=9.111031...Ch. 5 - Prob. 5.64SPCh. 5 - Prob. 5.65SPCh. 5 - Prob. 5.66SPCh. 5 - Prob. 5.67SPCh. 5 - Prob. 5.68SPCh. 5 - Prob. 5.69SPCh. 5 - Prob. 5.70SPCh. 5 - Prob. 5.71SPCh. 5 - Prob. 5.72SPCh. 5 - Prob. 5.73SPCh. 5 - Prob. 5.74SPCh. 5 - Prob. 5.75SPCh. 5 - Prob. 5.76SPCh. 5 - Prob. 5.77SPCh. 5 - Prob. 5.78SPCh. 5 - Prob. 5.79SPCh. 5 - Prob. 5.80SPCh. 5 - Prob. 5.81SPCh. 5 - Prob. 5.82SPCh. 5 - Prob. 5.83SPCh. 5 - Prob. 5.84SPCh. 5 - Prob. 5.85SPCh. 5 - Prob. 5.86SPCh. 5 - Prob. 5.87SPCh. 5 - Prob. 5.88SPCh. 5 - Prob. 5.89SPCh. 5 - Prob. 5.90SPCh. 5 - Prob. 5.91SPCh. 5 - Prob. 5.92SPCh. 5 - Prob. 5.93SPCh. 5 - Prob. 5.94SPCh. 5 - Prob. 5.95SPCh. 5 - Prob. 5.96SPCh. 5 - Draw orbital-filling diagrams for atoms with the...Ch. 5 - Prob. 5.98SPCh. 5 - Prob. 5.99SPCh. 5 - Prob. 5.100SPCh. 5 - Prob. 5.101SPCh. 5 - Prob. 5.102SPCh. 5 - Prob. 5.103SPCh. 5 - Prob. 5.104SPCh. 5 - Prob. 5.105SPCh. 5 - Prob. 5.106SPCh. 5 - Prob. 5.107SPCh. 5 - Prob. 5.108SPCh. 5 - Prob. 5.109SPCh. 5 - What is the expected ground-state electron...Ch. 5 - What is the atomic number and expected...Ch. 5 - Prob. 5.112CPCh. 5 - Prob. 5.113CPCh. 5 - Prob. 5.114CPCh. 5 - 5.115 Lines in a certain series of the hydrogen...Ch. 5 - Prob. 5.116CPCh. 5 - Prob. 5.117CPCh. 5 - Prob. 5.118CPCh. 5 - Prob. 5.119CPCh. 5 - Prob. 5.120CPCh. 5 - Prob. 5.121CPCh. 5 - Prob. 5.122CPCh. 5 - Prob. 5.123CPCh. 5 - Prob. 5.124CPCh. 5 - Prob. 5.125CPCh. 5 - Prob. 5.126CPCh. 5 - Prob. 5.127CPCh. 5 - Prob. 5.128CPCh. 5 - Prob. 5.129CPCh. 5 - Prob. 5.130CPCh. 5 - Prob. 5.131CPCh. 5 - Prob. 5.132CPCh. 5 - Prob. 5.133CPCh. 5 - Prob. 5.134CPCh. 5 - Prob. 5.135CPCh. 5 - Prob. 5.136CPCh. 5 - Prob. 5.137CPCh. 5 - Prob. 5.138CPCh. 5 - Prob. 5.139MPCh. 5 - Prob. 5.140MPCh. 5 - Prob. 5.141MP
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