The reason for the energy of activation for diffusion through the interstitial mechanism to be lower than that for another mechanism needs to be explained. Concept introduction: The institutional mechanism is the mechanism in which an atom is smaller and requires less energy to pass the surrounding atom.

Question

One thousand kg/h of a (50-50 wt%) acetone-in-water solution is to be extracted at 25C in a continuous, countercurrent system with pure 1,1,2-trichloroethane to obtain a raffinate containing 10 wt% acetone. Using the following equilibrium data, determine with an equilateral-triangle diagram: a- the minimum flow rate of solvent; b- the number of stages required for a solvent rate equal to 1.5 times minimum, and composition of each streamleaving each stage. c- Repeat the calculation of (a) and (b) if the solvent used has purity 93wt% (4wr% acetone, 3wt% water impurities) acetone water 1,1,2-trichloroethane Raffinate. Weight Extract. Weight 0.6 0.13 0.27 Fraction Acetone Fraction Acetone 0.5 0.04 0.46 0.44 0.56 0.4 0.03 0.57 0.29 0.40 0.3 0.02 0.68 0.12 0.18 0.2 0.015 0.785 0.0 0.0 0.1 0.01 0.89 0.55 0.35 0.1 0.5 0.43 0.07 0.4 0.57 0.03 0.3 0.68 0.02 0.2 0.79 0.01 0.1 0.895 0.005

Answer 1

Question

Chapter 5, Problem 5.16P

Interpretation Introduction

Interpretation:

The reason for the energy of activation for diffusion through the interstitial mechanism to be lower than that for another mechanism needs to be explained.

Concept introduction:

The institutional mechanism is the mechanism in which an atom is smaller and requires less energy to pass the surrounding atom.

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One thousand kg/h of a (50-50 wt%) acetone-in-water solution is to be extracted at 25C in a continuous, countercurrent system with pure 1,1,2-trichloroethane to obtain a raffinate containing 10 wt% acetone. Using the following equilibrium data, determine with an equilateral-triangle diagram: a- the minimum flow rate of solvent; b- the number of stages required for a solvent rate equal to 1.5 times minimum, and composition of each streamleaving each stage. c- Repeat the calculation of (a) and (b) if the solvent used has purity 93wt% (4wr% acetone, 3wt% water impurities) acetone water 1,1,2-trichloroethane Raffinate. Weight Extract. Weight 0.6 0.13 0.27 Fraction Acetone Fraction Acetone 0.5 0.04 0.46 0.44 0.56 0.4 0.03 0.57 0.29 0.40 0.3 0.02 0.68 0.12 0.18 0.2 0.015 0.785 0.0 0.0 0.1 0.01 0.89 0.55 0.35 0.1 0.5 0.43 0.07 0.4 0.57 0.03 0.3 0.68 0.02 0.2 0.79 0.01 0.1 0.895 0.005

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