Chemistry
13th Edition
ISBN: 9781259911156
Author: Raymond Chang Dr., Jason Overby Professor
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 5, Problem 5.160QP
One way to gain a physical understanding of b in the van der Waals equation is to calculate the “excluded volume.” Assume that the distance of closest approach between two similar atoms is the sum of their radii (2r). (a) Calculate the volume around each atom into which the center of another atom cannot penetrate. (b) From your result in (a), calculate the excluded volume for 1 mole of the atoms, which is the constant b. How does this volume compare with the sum of the volumes of 1 mole of the atoms?
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Chapter 5 Solutions
Chemistry
Ch. 5.2 - Prob. 1PECh. 5.2 - Prob. 2PECh. 5.2 - Express 1184 torr in units of mmHg, atm, and kPa.Ch. 5.2 - Rank the following pressures from lowest to...Ch. 5.2 - Prob. 3RCFCh. 5.3 - A gas occupies a volume of 2.50 L at 375 mmHg....Ch. 5.3 - Prob. 2RCFCh. 5.3 - What volume of ClF3 will be produced when 75.0 mL...Ch. 5.4 - Calculate the volume (in liters) occupied by 2.12...Ch. 5.4 - Prob. 4PE
Ch. 5.4 - A sample of chlorine gas occupies a volume of 946...Ch. 5.4 - Prob. 6PECh. 5.4 - A gas initially at 4.0 L, 1.2 atm, and 66C...Ch. 5.4 - What is the density (in g/L) of uranium...Ch. 5.4 - Prob. 9PECh. 5.4 - Prob. 10PECh. 5.4 - Prob. 1RCFCh. 5.4 - Prob. 2RCFCh. 5.4 - Prob. 3RCFCh. 5.5 - Prob. 11PECh. 5.5 - The equation for the metabolic breakdown of...Ch. 5.5 - Prob. 13PECh. 5.5 - Zinc metal reacts with hydrochloric acid according...Ch. 5.5 - Prob. 2RCFCh. 5.6 - Prob. 14PECh. 5.6 - Prob. 15PECh. 5.6 - Prob. 1RCFCh. 5.6 - Prob. 2RCFCh. 5.6 - Prob. 3RCFCh. 5.7 - Prob. 16PECh. 5.7 - Prob. 17PECh. 5.7 - Prob. 1RCFCh. 5.7 - Prob. 2RCFCh. 5.8 - Using the data shown in Table 5.4, calculate the...Ch. 5.8 - Prob. 1RCFCh. 5.8 - Prob. 2RCFCh. 5 - Prob. 5.1QPCh. 5 - Prob. 5.2QPCh. 5 - Prob. 5.3QPCh. 5 - Prob. 5.4QPCh. 5 - Prob. 5.5QPCh. 5 - Prob. 5.6QPCh. 5 - Prob. 5.7QPCh. 5 - Prob. 5.8QPCh. 5 - Prob. 5.9QPCh. 5 - Prob. 5.10QPCh. 5 - Prob. 5.11QPCh. 5 - Prob. 5.12QPCh. 5 - Convert 562 mmHg to atm.Ch. 5 - Prob. 5.14QPCh. 5 - Prob. 5.15QPCh. 5 - A gaseous sample of a substance is cooled at...Ch. 5 - Consider the following gaseous sample in a...Ch. 5 - Prob. 5.19QPCh. 5 - Prob. 5.20QPCh. 5 - Prob. 5.21QPCh. 5 - A sample of air occupies 3.8 L when the pressure...Ch. 5 - Prob. 5.23QPCh. 5 - Under constant-pressure conditions a sample of...Ch. 5 - Ammonia burns in oxygen gas to form nitric oxide...Ch. 5 - Molecular chlorine and molecular fluorine combine...Ch. 5 - Prob. 5.27QPCh. 5 - Prob. 5.28QPCh. 5 - Prob. 5.29QPCh. 5 - Prob. 5.30QPCh. 5 - Prob. 5.31QPCh. 5 - Given that 6.9 moles of carbon monoxide gas are...Ch. 5 - What volume will 5.6 moles of sulfur hexafluoride...Ch. 5 - Prob. 5.34QPCh. 5 - Prob. 5.35QPCh. 5 - Prob. 5.36QPCh. 5 - Prob. 5.37QPCh. 5 - Prob. 5.38QPCh. 5 - An ideal gas originally at 0.85 atm and 66C was...Ch. 5 - Prob. 5.40QPCh. 5 - Prob. 5.41QPCh. 5 - Dry ice is solid carbon dioxide. 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At 20C,...Ch. 5 - Prob. 5.51QPCh. 5 - The density of a mixture of fluorine and chlorine...Ch. 5 - Consider the formation of nitrogen dioxide from...Ch. 5 - Methane, the principal component of natural gas,...Ch. 5 - When coal is burned, the sulfur present in coal is...Ch. 5 - In alcohol fermentation, yeast converts glucose to...Ch. 5 - Prob. 5.57QPCh. 5 - A quantity of 0.225 g of a metal M (molar mass =...Ch. 5 - What is the mass of the solid NH4Cl formed when...Ch. 5 - Prob. 5.60QPCh. 5 - Prob. 5.61QPCh. 5 - Ethanol (C2H5OH) burns in air:...Ch. 5 - (a) What volumes (in liters) of ammonia and oxygen...Ch. 5 - Prob. 5.64QPCh. 5 - Prob. 5.65QPCh. 5 - A sample of air contains only nitrogen and oxygen...Ch. 5 - A mixture of gases contains 0.31 mol CH4, 0.25 mol...Ch. 5 - A 2.5-L flask at 15C contains a mixture of N2, He,...Ch. 5 - Dry air near sea level has the following...Ch. 5 - Prob. 5.70QPCh. 5 - Prob. 5.71QPCh. 5 - A sample of zinc metal reacts completely with an...Ch. 5 - Prob. 5.73QPCh. 5 - A sample of ammonia (NH3) gas is completely...Ch. 5 - Prob. 5.75QPCh. 5 - The volume of the box on the right is twice that...Ch. 5 - Prob. 5.78QPCh. 5 - Prob. 5.79QPCh. 5 - Prob. 5.80QPCh. 5 - Compare the root-mean-square speeds of O2 and UF6...Ch. 5 - Prob. 5.82QPCh. 5 - The average distance traveled by a molecule...Ch. 5 - At a certain temperature the speeds of six gaseous...Ch. 5 - Prob. 5.85QPCh. 5 - The 235U isotope undergoes fission when bombarded...Ch. 5 - Prob. 5.87QPCh. 5 - Prob. 5.88QPCh. 5 - Prob. 5.90QPCh. 5 - (a) A real gas is introduced into a flask of...Ch. 5 - Using the data shown in Table 5.4, calculate the...Ch. 5 - Prob. 5.94QPCh. 5 - Prob. 5.95QPCh. 5 - Prob. 5.96QPCh. 5 - Prob. 5.97QPCh. 5 - Prob. 5.98QPCh. 5 - When ammonium nitrite (NH4NO2) is heated, it...Ch. 5 - The percent by mass of bicarbonate (HCO3) in a...Ch. 5 - Prob. 5.101QPCh. 5 - Prob. 5.102QPCh. 5 - Prob. 5.103QPCh. 5 - A healthy adult exhales about 5.0 102 mL of a...Ch. 5 - Prob. 5.105QPCh. 5 - Prob. 5.106QPCh. 5 - Some commercial drain cleaners contain a mixture...Ch. 5 - The volume of a sample of pure HCl gas was 189 mL...Ch. 5 - Prob. 5.109QPCh. 5 - Prob. 5.110QPCh. 5 - Prob. 5.111QPCh. 5 - Prob. 5.112QPCh. 5 - Prob. 5.113QPCh. 5 - Prob. 5.114QPCh. 5 - Prob. 5.115QPCh. 5 - Prob. 5.116QPCh. 5 - Prob. 5.117QPCh. 5 - Commercially, compressed oxygen is sold in metal...Ch. 5 - Prob. 5.119QPCh. 5 - Prob. 5.120QPCh. 5 - Prob. 5.121QPCh. 5 - Prob. 5.122QPCh. 5 - Prob. 5.123QPCh. 5 - Prob. 5.124QPCh. 5 - Prob. 5.125QPCh. 5 - Prob. 5.126QPCh. 5 - Prob. 5.127QPCh. 5 - Prob. 5.128QPCh. 5 - Acidic oxides such as carbon dioxide react with...Ch. 5 - Prob. 5.130QPCh. 5 - Prob. 5.131QPCh. 5 - Prob. 5.132QPCh. 5 - Atop Mt. Everest, the atmospheric pressure is 210...Ch. 5 - Prob. 5.134QPCh. 5 - Prob. 5.135QPCh. 5 - Prob. 5.136QPCh. 5 - Prob. 5.137QPCh. 5 - Prob. 5.138QPCh. 5 - Prob. 5.139QPCh. 5 - Prob. 5.140QPCh. 5 - Prob. 5.141QPCh. 5 - Prob. 5.142QPCh. 5 - Prob. 5.143QPCh. 5 - Prob. 5.144QPCh. 5 - Prob. 5.145QPCh. 5 - At what temperature will He atoms have the same...Ch. 5 - Prob. 5.148QPCh. 5 - Prob. 5.149QPCh. 5 - Prob. 5.150QPCh. 5 - Prob. 5.151QPCh. 5 - Prob. 5.152QPCh. 5 - Prob. 5.153QPCh. 5 - A 6.11-g sample of a Cu-Zn alloy reacts with HCl...Ch. 5 - Prob. 5.155QPCh. 5 - Prob. 5.156QPCh. 5 - Prob. 5.157QPCh. 5 - A mixture of methane (CH4) and ethane (C2H6) is...Ch. 5 - Prob. 5.159QPCh. 5 - One way to gain a physical understanding of b in...Ch. 5 - Use the van der Waals constants in Table 5.4. to...Ch. 5 - Prob. 5.162QPCh. 5 - Prob. 5.163QPCh. 5 - Prob. 5.164QPCh. 5 - Referring to Figure 5.17, we see that the maximum...Ch. 5 - Prob. 5.166QPCh. 5 - A gaseous hydrocarbon (containing C and H atoms)...Ch. 5 - Three flasks (a)(c) contain gases A (red) and B...Ch. 5 - Prob. 5.169QPCh. 5 - Prob. 5.170QPCh. 5 - In 2012, Felix Baumgartner jumped from a balloon...Ch. 5 - Prob. 5.172QPCh. 5 - A flask with a volume of 14.5 L contains 1.25...Ch. 5 - Prob. 5.174QPCh. 5 - Prob. 5.175QPCh. 5 - Prob. 5.176QPCh. 5 - Prob. 5.177QP
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