Increasing order of priority of the given groups has to be given. Given groups are − C H 3 , − H , − B r , − C H 2 C H 3 Concept Introduction: The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

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11 1 Which one of the following compounds would show a proton NMR signal at the highest chemical shift? (7pts) cl @amitabh CI CI d) Cl CICI

Answer 1

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Chapter 5, Problem 5.15P

(a)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3, −H, −Br, −CH2CH3

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −OCH3,−CH(CH3)2,−B(CH2CH3), −H

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3,−CH2OH,−CH2NH2, −CH2Br

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

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11 1 Which one of the following compounds would show a proton NMR signal at the highest chemical shift? (7pts) cl @amitabh CI CI d) Cl CICI

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H2SO4 (cat.), H₂O 100 °C NH₂

Answer 2

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Chapter 5, Problem 5.15P

(a)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3, −H, −Br, −CH2CH3

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −OCH3,−CH(CH3)2,−B(CH2CH3), −H

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3,−CH2OH,−CH2NH2, −CH2Br

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

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Answer 3

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Chapter 5, Problem 5.15P

(a)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3, −H, −Br, −CH2CH3

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −OCH3,−CH(CH3)2,−B(CH2CH3), −H

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3,−CH2OH,−CH2NH2, −CH2Br

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

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Answer 4

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Chapter 5, Problem 5.15P

(a)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3, −H, −Br, −CH2CH3

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −OCH3,−CH(CH3)2,−B(CH2CH3), −H

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3,−CH2OH,−CH2NH2, −CH2Br

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

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Answer 5

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Answer 6

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Answer 7

Chapter 5, Problem 5.15P

(a)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3, −H, −Br, −CH2CH3

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −OCH3,−CH(CH3)2,−B(CH2CH3), −H

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3,−CH2OH,−CH2NH2, −CH2Br

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 8

Chapter 5, Problem 5.15P

(a)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3, −H, −Br, −CH2CH3

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 9

Chapter 5, Problem 5.15P

(a)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3, −H, −Br, −CH2CH3

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 10

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −OCH3,−CH(CH3)2,−B(CH2CH3), −H

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 11

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −OCH3,−CH(CH3)2,−B(CH2CH3), −H

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 12

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3,−CH2OH,−CH2NH2, −CH2Br

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 13

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are −CH3,−CH2OH,−CH2NH2, −CH2Br

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 14

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Answer 25

Ch. 5.1 - Calculate the index of hydrogen deficiency for...Ch. 5.1 - Prob. 5.2P Ch. 5.2 - Write the IUPAC name of each alkene. (a) (b)Ch. 5.2 - Prob. 5.4P Ch. 5.2 - Prob. 5.5P Ch. 5.2 - Prob. 5.6P Ch. 5.2 - Prob. 5.7P Ch. 5.2 - Prob. 5.8P Ch. 5 - Predict all approximate bond angles about each...Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that the group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to it.

Chapter 5 Solutions