EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
6th Edition
ISBN: 9780100547506
Author: CRACOLICE
Publisher: YUZU
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Textbook Question
Chapter 5, Problem 4E
How does Dalton’s atomic theory account for the Law of Conservation of Mass?
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
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Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
4th total
• 6H total
래
• 4H total
21 total
ZH
2H
Statistical
H < 3° C-H weakest
-
product
abstraction here
bund
leads to thermo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Product
6
Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
Waterfox
10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation →
depicted below
Use proper curved arrow notation that explicitly illustrates all bonds being broken, and
all bonds formed in the transformation.
Also, be sure to include all lone pairs and formal charges on all atoms involved in the
flow of electrons.
CH3O
II
HA
H
CH3O-H
H
①
Chapter 5 Solutions
EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
Ch. 5 - Prob. 1ECh. 5 - List the major points in Daltons atomic theory.Ch. 5 - Show that the Daltons atomic theory explains the...Ch. 5 - How does Daltons atomic theory account for the Law...Ch. 5 - The chemical name for limestone, a compound of...Ch. 5 - The brilliance with which magnesium burns makes it...Ch. 5 - Sulfur and fluorine form at least two compounds...Ch. 5 - Prob. 8ECh. 5 - Advances in technology and science often progress...Ch. 5 - When J. J. Thomson measured the deflection of a...
Ch. 5 - Prob. 11ECh. 5 - What is meant by stating that the charge of an...Ch. 5 - How can we account for the fact that, in the...Ch. 5 - How can we account for the fact that most of the...Ch. 5 - What do we call the central part of an atom?Ch. 5 - What major conclusions were drawn from the...Ch. 5 - Describe the activity of electrons according to...Ch. 5 - The Rutherford experiment was performed and its...Ch. 5 - Compare the three major parts of an atom in charge...Ch. 5 - Prob. 20ECh. 5 - Can two different elements have the same atomic...Ch. 5 - Compare the number of protons and electrons in an...Ch. 5 - Explain why isotopes of different elements can...Ch. 5 - How many protons, neutrons and electrons are there...Ch. 5 - Prob. 25ECh. 5 - What advantage does the atomic mass unit have over...Ch. 5 - What is an atomic mass unit?Ch. 5 - The mass of an average atom of a certain element...Ch. 5 - The average mass of boron atoms is 10.81u. How...Ch. 5 - The atomic masses of the natural isotopes of neon...Ch. 5 - A certain element consists of two stable isotopes....Ch. 5 - The mass of 60.4 of the atoms of an element is...Ch. 5 - Isotopic data for boron allow the calculation of...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Prob. 40ECh. 5 - How many elements are in Period 5 of the periodic...Ch. 5 - Write the symbol of the element in each given...Ch. 5 - Prob. 43ECh. 5 - List the symbols of the elements of each of the...Ch. 5 - Using only a periodic table for reference, list...Ch. 5 - Prob. 46ECh. 5 - Write the atomic masses of helium and aluminum.Ch. 5 - Prob. 48ECh. 5 - Prob. 49ECh. 5 - Prob. 50ECh. 5 - Prob. 51ECh. 5 - Determine whether each statement that follows is...Ch. 5 - Prob. 53ECh. 5 - Sodium oxide and sodium peroxide are two compounds...Ch. 5 - Prob. 55ECh. 5 - The CRC Handbook, a large reference book of...Ch. 5 - The element lanthanum has two stable isotopes,...Ch. 5 - The atomic mass of lithium on a periodic table is...Ch. 5 - Prob. 59ECh. 5 - Prob. 60ECh. 5 - Prob. 61ECh. 5 - Prob. 62ECh. 5 - Prob. 5.1TCCh. 5 - Prob. 5.2TCCh. 5 - Prob. 5.3TCCh. 5 - Prob. 5.4TCCh. 5 - Prob. 5.5TCCh. 5 - Write a brief description of the relationships...Ch. 5 - Prob. 2CLECh. 5 - Prob. 3CLECh. 5 - Prob. 4CLECh. 5 - Prob. 5CLECh. 5 - Prob. 6CLECh. 5 - Prob. 7CLECh. 5 - What is the number of each type of subatomic...Ch. 5 - Naturally occurring lithium is composed of two...Ch. 5 - Prob. 3PECh. 5 - Prob. 4PECh. 5 - Prob. 5PE
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