EBK CHEMISTRY
9th Edition
ISBN: 8220100453809
Author: ZUMDAHL
Publisher: Cengage Learning US
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Chapter 5, Problem 4ALQ
Interpretation Introduction
Interpretation:
The change in temperature and volume at a constant pressure in a container with a piston has to be explained.
Concept Introduction:
Charles’s law: At constant pressure (P), for a given mass of gas, the volume (V) is directly proportional to the absolute temperature (T). The expression for Charles’s law is given by,
Where
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Understanding how substituents activate
Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
HN
NH2
Check
X
(Choose one)
(Choose one)
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects on benzene
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Inductive Effects
Resonance Effects
Overall Electron-Density
Molecule
CF3
O donating
O donating
O withdrawing
O withdrawing
O no inductive effects
O no resonance effects
electron-rich
electron-deficient
O similar to benzene
CH3
O donating
O withdrawing
O no inductive effects
O donating
O withdrawing
Ono resonance effects
O electron-rich
O electron-deficient
O similar to benzene
Explanation
Check
Х
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* Hint: Think back to Chem 1 solubility rules.
Follow Up Questions for Part B
12. What impact do the following disturbances to a system at equilibrium have on k, the rate constant
for the forward reaction? Explain. (4 pts)
a) Changing the concentration of a reactant or product. (2 pts)
b) Changing the temperature of an exothermic reaction. (2 pts)
of
Chapter 5 Solutions
EBK CHEMISTRY
Ch. 5 - Prob. 1RQCh. 5 - Prob. 2RQCh. 5 - Prob. 3RQCh. 5 - Prob. 4RQCh. 5 - Prob. 5RQCh. 5 - Prob. 6RQCh. 5 - Prob. 7RQCh. 5 - Prob. 8RQCh. 5 - Prob. 9RQCh. 5 - Why do real gases not always behave ideally? Under...
Ch. 5 - Prob. 3ALQCh. 5 - Prob. 4ALQCh. 5 - Prob. 6ALQCh. 5 - Prob. 8ALQCh. 5 - Prob. 11ALQCh. 5 - Prob. 12ALQCh. 5 - Prob. 15ALQCh. 5 - Prob. 16ALQCh. 5 - Draw molecular-level views that show the...Ch. 5 - Prob. 20QCh. 5 - Prob. 21QCh. 5 - Prob. 22QCh. 5 - Prob. 23QCh. 5 - As weather balloons rise from the earths surface,...Ch. 5 - Prob. 25QCh. 5 - Consider two different containers, each filled...Ch. 5 - Prob. 27QCh. 5 - Prob. 28QCh. 5 - Prob. 29QCh. 5 - Prob. 30QCh. 5 - Prob. 31QCh. 5 - Prob. 32QCh. 5 - Prob. 33QCh. 5 - Without looking at a table of values, which of the...Ch. 5 - Prob. 35QCh. 5 - Prob. 36QCh. 5 - Prob. 37ECh. 5 - Prob. 38ECh. 5 - A sealed-tube manometer (as shown below) can be...Ch. 5 - Prob. 40ECh. 5 - A diagram for an open-tube manometer is shown...Ch. 5 - Prob. 42ECh. 5 - Prob. 43ECh. 5 - Prob. 44ECh. 5 - Prob. 45ECh. 5 - Prob. 46ECh. 5 - Prob. 47ECh. 5 - Prob. 48ECh. 5 - Prob. 49ECh. 5 - Prob. 50ECh. 5 - The Steel reaction vessel of a bomb calorimeter,...Ch. 5 - A 5.0-L flask contains 0.60 g O2 at a temperature...Ch. 5 - Prob. 53ECh. 5 - A person accidentally swallows a drop of liquid...Ch. 5 - A gas sample containing 1.50 moles at 25C exerts a...Ch. 5 - Prob. 56ECh. 5 - Prob. 57ECh. 5 - What will be the effect on the volume of an ideal...Ch. 5 - Prob. 59ECh. 5 - Prob. 60ECh. 5 - An ideal gas is contained in a cylinder with a...Ch. 5 - Prob. 62ECh. 5 - A sealed balloon is filled with 1.00 L helium at...Ch. 5 - Prob. 64ECh. 5 - Consider the following reaction:...Ch. 5 - A student adds 4.00 g of dry ice (solid CO2) to an...Ch. 5 - Air bags are activated when a severe impact causes...Ch. 5 - Concentrated hydrogen peroxide solutions are...Ch. 5 - In 1897 the Swedish explorer Andre tried to reach...Ch. 5 - Sulfur trioxide, SO3, is produced in enormous...Ch. 5 - A 15.0-L rigid container was charged with 0.500...Ch. 5 - An important process for the production of...Ch. 5 - Consider the reaction between 50.0 mL liquid...Ch. 5 - Urea (H2NCONH2) is used extensively as a nitrogen...Ch. 5 - Prob. 75ECh. 5 - Prob. 76ECh. 5 - Prob. 77ECh. 5 - A compound has the empirical formula CHCl. A...Ch. 5 - Prob. 79ECh. 5 - Given that a sample of air is made up of nitrogen,...Ch. 5 - Prob. 81ECh. 5 - Prob. 82ECh. 5 - A piece of solid carbon dioxide, with a mass of...Ch. 5 - Prob. 84ECh. 5 - Consider the flasks in the following diagram. What...Ch. 5 - Consider the flask apparatus in Exercise 85, which...Ch. 5 - Prob. 87ECh. 5 - At 0C a 1.0-L flask contains 5.0 102 mole of N2,...Ch. 5 - Prob. 89ECh. 5 - A tank contains a mixture of 52.5 g oxygen gas and...Ch. 5 - Prob. 91ECh. 5 - Helium is collected over water at 25C and 1.00 atm...Ch. 5 - At elevated temperatures, sodium chlorate...Ch. 5 - Xenon and fluorine will react to form binary...Ch. 5 - Methanol (CH3OH) can be produced by the following...Ch. 5 - In the Mthode Champenoise, grape juice is...Ch. 5 - Hydrogen azide, HN3, decomposes on heating by the...Ch. 5 - Prob. 98ECh. 5 - Prob. 99ECh. 5 - The oxides of Group 2A metals (symbolized by M...Ch. 5 - Prob. 101ECh. 5 - Prob. 102ECh. 5 - Prob. 103ECh. 5 - Prob. 104ECh. 5 - Prob. 105ECh. 5 - Prob. 106ECh. 5 - Prob. 107ECh. 5 - Prob. 108ECh. 5 - Prob. 109ECh. 5 - Prob. 110ECh. 5 - Prob. 111ECh. 5 - Prob. 112ECh. 5 - Prob. 113ECh. 5 - Prob. 114ECh. 5 - Prob. 115ECh. 5 - Prob. 116ECh. 5 - Use the data in Table 84 to calculate the partial...Ch. 5 - Prob. 118ECh. 5 - Prob. 119ECh. 5 - Prob. 120ECh. 5 - Prob. 121ECh. 5 - Prob. 122ECh. 5 - Prob. 123AECh. 5 - At STP, 1.0 L Br2 reacts completely with 3.0 L F2,...Ch. 5 - Prob. 125AECh. 5 - Prob. 126AECh. 5 - Prob. 127AECh. 5 - Cyclopropane, a gas that when mixed with oxygen is...Ch. 5 - The nitrogen content of organic compounds can be...Ch. 5 - Prob. 130AECh. 5 - A 15.0L tank is filled with H2 to a pressure of...Ch. 5 - A spherical glass container of unknown volume...Ch. 5 - Prob. 133AECh. 5 - A 20.0L stainless steel container at 25C was...Ch. 5 - Metallic molybdenum can be produced from the...Ch. 5 - Prob. 136AECh. 5 - Prob. 137AECh. 5 - One of the chemical controversies of the...Ch. 5 - An organic compound contains C, H, N, and O....Ch. 5 - Prob. 140AECh. 5 - Prob. 141CWPCh. 5 - Prob. 142CWPCh. 5 - A certain flexible weather balloon contains helium...Ch. 5 - A large flask with a volume of 936 mL is evacuated...Ch. 5 - A 20.0L nickel container was charged with 0.859...Ch. 5 - Consider the unbalanced chemical equation below:...Ch. 5 - Prob. 147CWPCh. 5 - Which of the following statements is(are) true? a....Ch. 5 - A chemist weighed out 5.14 g of a mixture...Ch. 5 - A mixture of chromium and zinc weighing 0.362 g...Ch. 5 - Prob. 151CPCh. 5 - You have an equimolar mixture of the gases SO2 and...Ch. 5 - Methane (CH4) gas flows into a combustion chamber...Ch. 5 - Prob. 154CPCh. 5 - Prob. 155CPCh. 5 - Prob. 156CPCh. 5 - You have a helium balloon at 1.00 atm and 25C. You...Ch. 5 - We state that the ideal gas law tends to hold best...Ch. 5 - You are given an unknown gaseous binary compound...Ch. 5 - Prob. 160CPCh. 5 - In the presence of nitric acid, UO2+ undergoes a...Ch. 5 - Silane, SiH4, is the silicon analogue of methane,...Ch. 5 - Prob. 163IPCh. 5 - Prob. 164IPCh. 5 - Prob. 165MP
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