Organic Chemistry, Third Edition Binder Ready Version
3rd Edition
ISBN: 9781119110453
Author: Klein
Publisher: WILEY
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Question
Chapter 5, Problem 46PP
Interpretation Introduction
Interpretation: The true or false should be identified for the given statements.
Concept Introduction:
The racemic mixture is optically inactive, that there is no net rotation of plane polarized light.
The two enantiomers rotate plane-polarized light in opposite directions, the rotation cancel because they are present in equal amounts.
The meso compounds are optically inactive due to this differing absolute configuration on the opposing stereo centers. Further meso compounds is achiral so cannot have an enantiomers.
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יווי
10
20
30
40
50
60
70
3.5
3
2.5
2
1.5
1
[ppm]
3.5
3
2.5
2
1.5
1
6 [ppm]
1
1.5
-2.5
3.5
2H2S(g)+3O2(g)→2SO2(g)+2H2O(g)
A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion.
Question
Which of the following predicts the theoretical yield of SO2(g) from the reaction?
Responses
1.2 g
Answer A: 1.2 grams
A
41 g
Answer B: 41 grams
B
77 g
Answer C: 77 grams
C
154 g
Answer D: 154 grams
D
Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Chapter 5 Solutions
Organic Chemistry, Third Edition Binder Ready Version
Ch. 5.1 -
In the following compound, identify each unit...Ch. 5.1 - Prob. 2CCCh. 5.1 - Prob. 3CCCh. 5.2 - Prob. 1LTSCh. 5.2 - Prob. 4PTSCh. 5.2 - Prob. 5ATSCh. 5.2 - Prob. 6ATSCh. 5.2 - Prob. 2LTSCh. 5.2 - Prob. 7PTSCh. 5.2 - Prob. 8ATS
Ch. 5.3 - Prob. 3LTSCh. 5.3 - Prob. 9PTSCh. 5.3 - Prob. 10ATSCh. 5.4 - Prob. 4LTSCh. 5.4 - Prob. 11PTSCh. 5.4 - Prob. 12PTSCh. 5.4 - Prob. 13PTSCh. 5.4 - Prob. 14ATSCh. 5.4 - Prob. 5LTSCh. 5.4 - Prob. 15PTSCh. 5.4 - Prob. 16PTSCh. 5.4 - Prob. 17PTSCh. 5.4 - Prob. 18ATSCh. 5.5 - Prob. 6LTSCh. 5.5 - Prob. 19PTSCh. 5.5 - Prob. 20ATSCh. 5.6 - Prob. 21CCCh. 5.6 - Prob. 22CCCh. 5.6 - Prob. 23CCCh. 5.6 - Prob. 7LTSCh. 5.6 - Prob. 24PTSCh. 5.6 - Prob. 25ATSCh. 5.7 - Prob. 8LTSCh. 5.7 - Prob. 26PTSCh. 5.7 -
Protease inhibitors are a class of anti-viral...Ch. 5.9 - Prob. 28CCCh. 5.11 - Prob. 9LTSCh. 5.11 - Prob. 29PTSCh. 5.11 - Prob. 30ATSCh. 5 - Prob. 31PPCh. 5 - Prob. 32PPCh. 5 - Prob. 33PPCh. 5 - Prob. 34PPCh. 5 - Prob. 35PPCh. 5 - Prob. 36PPCh. 5 - Prob. 37PPCh. 5 - Prob. 38PPCh. 5 - Prob. 39PPCh. 5 - Prob. 40PPCh. 5 - Prob. 41PPCh. 5 - Prob. 42PPCh. 5 - Prob. 43PPCh. 5 - Prob. 44PPCh. 5 - Prob. 45PPCh. 5 - Prob. 46PPCh. 5 - Prob. 47PPCh. 5 - Prob. 48PPCh. 5 - Prob. 49PPCh. 5 - Prob. 50PPCh. 5 - Prob. 51PPCh. 5 - Prob. 52PPCh. 5 - For each of the following pairs of compounds,...Ch. 5 - Prob. 54PPCh. 5 - Prob. 55PPCh. 5 - Prob. 56PPCh. 5 - Prob. 57IPCh. 5 - Prob. 58IPCh. 5 - Prob. 59IPCh. 5 - Prob. 60IPCh. 5 - There are only two stereoisomers of...Ch. 5 - Prob. 62IPCh. 5 - Prob. 63IPCh. 5 - Prob. 64IPCh. 5 - Prob. 65IPCh. 5 - Prob. 66IPCh. 5 - Prob. 67IPCh. 5 - Prob. 68IPCh. 5 - Prob. 69IPCh. 5 - Prob. 70IPCh. 5 - Prob. 71IPCh. 5 - Prob. 72IPCh. 5 - Prob. 73IPCh. 5 - Prob. 74IPCh. 5 - Prob. 75IPCh. 5 - Prob. 76IPCh. 5 - Prob. 77CPCh. 5 - Prob. 78CPCh. 5 - Prob. 79CPCh. 5 - Prob. 80CP
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