CHEMISTRY IN FOCUS W/ OWL (LL)>IP<
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ISBN: 9781337306317
Author: Tro
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Chapter 5, Problem 30E
Draw a Lewis structure and use VSEPR theory to determine the geometry of each molecule. If the molecule has more than one central atom, indicate the geometry about each of these and draw the three-dimensional structure.
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 5 Solutions
CHEMISTRY IN FOCUS W/ OWL (LL)>IP<
Ch. 5 - Drawing Lewis Structures for Ionic Compounds Draw...Ch. 5 - Using Lewis Structures to Determine the Correct...Ch. 5 - Prob. 5.3YTCh. 5 - Prob. 5.4YTCh. 5 - Drawing Lewis Structures for Covalent Compounds...Ch. 5 - Prob. 5.6YTCh. 5 - Prob. 5.7YTCh. 5 - Prob. 5.8YTCh. 5 - Prob. 5.9YTCh. 5 - Determining if a Molecule Is Polar Is SCl2 a polar...
Ch. 5 - Based on the Lewis structures for hydrogen and...Ch. 5 - Prob. 2SCCh. 5 - Prob. 3SCCh. 5 - Prob. 4SCCh. 5 - Prob. 5SCCh. 5 - Prob. 6SCCh. 5 - Prob. 7SCCh. 5 - Why is salt, NaCl, relatively harmless even though...Ch. 5 - If sodium is dropped into water, a loud fizzing...Ch. 5 - Explain ionic bonding according to Lewis theory.Ch. 5 - Prob. 4ECh. 5 - Prob. 5ECh. 5 - Prob. 6ECh. 5 - Draw electron dot structures for the following...Ch. 5 - Explain VSEPR theory. According to this theory,...Ch. 5 - Prob. 9ECh. 5 - Prob. 10ECh. 5 - In what ways is water unique? What about the water...Ch. 5 - What is the difference between a polar and a...Ch. 5 - Why do polar molecules have a greater tendency to...Ch. 5 - Prob. 14ECh. 5 - Lewis Structures for Atoms Draw Lewis structures...Ch. 5 - Draw Lewis structures for each of the following...Ch. 5 - Ionic Lewis Structures Draw a Lewis structure for...Ch. 5 - Draw a Lewis structure for each of the following...Ch. 5 - Draw a Lewis structure for each of the following...Ch. 5 - Draw a Lewis structure for each of the following...Ch. 5 - Covalent Lewis Structures Draw a Lewis structure...Ch. 5 - Draw a Lewis structure for each molecular...Ch. 5 - General Lewis Structures Determine whether each...Ch. 5 - Determine whether each compound is ionic or...Ch. 5 - What is wrong with each Lewis structure? Fix the...Ch. 5 - What is wrong with each Lewis structure? Fix the...Ch. 5 - Predicting the Shapes of Molecules Use VSEPR...Ch. 5 - Use VSEPR theory to determine the geometry of the...Ch. 5 - Draw a Lewis structure and use VSEPR theory to...Ch. 5 - Draw a Lewis structure and use VSEPR theory to...Ch. 5 - CF2Cl2 is a chlorofluorocarbon implicated in ozone...Ch. 5 - Chlorofluorocarbons have been banned because they...Ch. 5 - Determining Molecular Polarity Determine whether...Ch. 5 - Determine whether each molecule is polar:...Ch. 5 - Determine whether each molecule is polar:...Ch. 5 - Determine whether each molecule is polar:...Ch. 5 - Explain why water would be a gas at room...Ch. 5 - Prob. 38ECh. 5 - Prob. 39ECh. 5 - One of the observations that led G. N. Lewis to...Ch. 5 - G. N. Lewis developed a model for chemical bonding...Ch. 5 - The opening quote of this chapter states that Man...Ch. 5 - Draw a Lewis structure of the H2 molecule. If you...Ch. 5 - Prob. 44ECh. 5 - The Lewis structures for CH4,N2,andCO2, along with...Ch. 5 - CH3COCH3 (acetone) is a common laboratory solvent...
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
- true or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forwardthe decomposition of N2O5 is the first order with a half-life of 1.98 minutes. If the inital concentration of N2O5 is 0.200 M, what is the concentration after 6 minutes?a) 0.612 Mb) 0.035 Mc) 0.024 Md) 0.100 Marrow_forward
- 20.00 mL of 0.150 M HCI is titrated with 0.075 M NaOH. What volume of NaOH is needed?a) 50 mLb) 20 mLc) 40 mLd) 26.66 mLarrow_forward20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCI. What is the molarity of the HCI?a) 0.150 Mb) 0.079 Mc) 0.025 Md) 0.050 Marrow_forwardin the following reaction, the OH- acts as which of these?NO2- (aq) + H2O (l) ⇌ OH- (aq) + HNO2 (aq)a) not a weak acidb) basec) acidarrow_forward
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