CHEMISTRY IN FOCUS W/ OWL (LL)>IP<
6th Edition
ISBN: 9781337306317
Author: Tro
Publisher: CENGAGE L
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Chapter 5, Problem 1E
Why is salt,
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 5 Solutions
CHEMISTRY IN FOCUS W/ OWL (LL)>IP<
Ch. 5 - Drawing Lewis Structures for Ionic Compounds Draw...Ch. 5 - Using Lewis Structures to Determine the Correct...Ch. 5 - Prob. 5.3YTCh. 5 - Prob. 5.4YTCh. 5 - Drawing Lewis Structures for Covalent Compounds...Ch. 5 - Prob. 5.6YTCh. 5 - Prob. 5.7YTCh. 5 - Prob. 5.8YTCh. 5 - Prob. 5.9YTCh. 5 - Determining if a Molecule Is Polar Is SCl2 a polar...
Ch. 5 - Based on the Lewis structures for hydrogen and...Ch. 5 - Prob. 2SCCh. 5 - Prob. 3SCCh. 5 - Prob. 4SCCh. 5 - Prob. 5SCCh. 5 - Prob. 6SCCh. 5 - Prob. 7SCCh. 5 - Why is salt, NaCl, relatively harmless even though...Ch. 5 - If sodium is dropped into water, a loud fizzing...Ch. 5 - Explain ionic bonding according to Lewis theory.Ch. 5 - Prob. 4ECh. 5 - Prob. 5ECh. 5 - Prob. 6ECh. 5 - Draw electron dot structures for the following...Ch. 5 - Explain VSEPR theory. According to this theory,...Ch. 5 - Prob. 9ECh. 5 - Prob. 10ECh. 5 - In what ways is water unique? What about the water...Ch. 5 - What is the difference between a polar and a...Ch. 5 - Why do polar molecules have a greater tendency to...Ch. 5 - Prob. 14ECh. 5 - Lewis Structures for Atoms Draw Lewis structures...Ch. 5 - Draw Lewis structures for each of the following...Ch. 5 - Ionic Lewis Structures Draw a Lewis structure for...Ch. 5 - Draw a Lewis structure for each of the following...Ch. 5 - Draw a Lewis structure for each of the following...Ch. 5 - Draw a Lewis structure for each of the following...Ch. 5 - Covalent Lewis Structures Draw a Lewis structure...Ch. 5 - Draw a Lewis structure for each molecular...Ch. 5 - General Lewis Structures Determine whether each...Ch. 5 - Determine whether each compound is ionic or...Ch. 5 - What is wrong with each Lewis structure? Fix the...Ch. 5 - What is wrong with each Lewis structure? Fix the...Ch. 5 - Predicting the Shapes of Molecules Use VSEPR...Ch. 5 - Use VSEPR theory to determine the geometry of the...Ch. 5 - Draw a Lewis structure and use VSEPR theory to...Ch. 5 - Draw a Lewis structure and use VSEPR theory to...Ch. 5 - CF2Cl2 is a chlorofluorocarbon implicated in ozone...Ch. 5 - Chlorofluorocarbons have been banned because they...Ch. 5 - Determining Molecular Polarity Determine whether...Ch. 5 - Determine whether each molecule is polar:...Ch. 5 - Determine whether each molecule is polar:...Ch. 5 - Determine whether each molecule is polar:...Ch. 5 - Explain why water would be a gas at room...Ch. 5 - Prob. 38ECh. 5 - Prob. 39ECh. 5 - One of the observations that led G. N. Lewis to...Ch. 5 - G. N. Lewis developed a model for chemical bonding...Ch. 5 - The opening quote of this chapter states that Man...Ch. 5 - Draw a Lewis structure of the H2 molecule. If you...Ch. 5 - Prob. 44ECh. 5 - The Lewis structures for CH4,N2,andCO2, along with...Ch. 5 - CH3COCH3 (acetone) is a common laboratory solvent...
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- n Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forward
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
- 13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forwardPart III. Arrange the following carbons (in blue) in order of increasing chemical shift. HO B NH 2 A CIarrow_forward
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