EBK CHEMISTRY: PRINCIPLES AND REACTIONS
8th Edition
ISBN: 9780100547964
Author: Hurley
Publisher: YUZU
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Textbook Question
Chapter 5, Problem 29QAP
A 1.58-g sample of C2H3X3(g) has a volume of 297 mL at 769 mm Hg and 35°C. Identify the element X.
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Chapter 5 Solutions
EBK CHEMISTRY: PRINCIPLES AND REACTIONS
Ch. 5 - Prob. 1QAPCh. 5 - A 6.00-ft cylinder has a radius of 26 in. It...Ch. 5 - Prob. 3QAPCh. 5 - Prob. 4QAPCh. 5 - A cylinder with a movable piston records a volume...Ch. 5 - A tank is filled with gas to a pressure of 875 mm...Ch. 5 - A sample of CO2 gas at 22C and 1.00 atm has a...Ch. 5 - A sample of nitrogen gas has a pressure of 1.22...Ch. 5 - Prob. 9QAPCh. 5 - A tire is inflated to a gauge pressure of 28.0 psi...
Ch. 5 - Prob. 11QAPCh. 5 - A sealed tank at room temperature, 25C, has 22.0 g...Ch. 5 - A balloon filled with helium hasa volume of...Ch. 5 - Prob. 14QAPCh. 5 - Prob. 15QAPCh. 5 - Prob. 16QAPCh. 5 - A piece of dry ice (CO2(s)) has a mass of 22.50 g....Ch. 5 - A four-liter tank is filled with propane gas,...Ch. 5 - Prob. 19QAPCh. 5 - Prob. 20QAPCh. 5 - Calculate the densities (in g/L) of the following...Ch. 5 - Calculate the densities (in grams per liter) of...Ch. 5 - Helium-filled balloons rise in the air because the...Ch. 5 - Space probes to Mars have shown that its...Ch. 5 - Cyclopropane mixed in the proper ratio with oxygen...Ch. 5 - Phosgene is a highly toxic gas made up of carbon,...Ch. 5 - The gas in the discharge cell of a laser contains...Ch. 5 - Exhaled air contains 74.5% N2, 15.7% O2, 3.6% CO2,...Ch. 5 - A 1.58-g sample of C2H3X3(g) has a volume of 297...Ch. 5 - A 0.750-g sample of the gas PX3 is in a sealed...Ch. 5 - Nitrogen oxide is a pollutant commonly found in...Ch. 5 - Nitrogen trifluoride gas reacts with steam to...Ch. 5 - Dichlorine oxide is used as bactericide to purify...Ch. 5 - Titanium(III) chloride is used in the manufacture...Ch. 5 - Nitric acid can be prepared by bubbling dinitrogen...Ch. 5 - Potassium peroxide is used to absorb the CO2...Ch. 5 - Hydrogen cyanide (HCN) is a poisonous gas. It can...Ch. 5 - When hydrogen peroxide decomposes, oxygen is...Ch. 5 - Ammonium nitrate can be used as an effective...Ch. 5 - Acetone peroxide, C9H18O6(s), is a powerful but...Ch. 5 - Prob. 41QAPCh. 5 - A certain laser uses a gas mixture consisting of...Ch. 5 - A sample of a smoke stack emission was collected...Ch. 5 - Prob. 44QAPCh. 5 - Prob. 45QAPCh. 5 - Prob. 46QAPCh. 5 - Prob. 47QAPCh. 5 - Follow the instructions of Problem 47 for the...Ch. 5 - When acetylene, C2H2, is burned in oxygen, carbon...Ch. 5 - When ammonium nitrate decomposes at 722C,...Ch. 5 - Prob. 51QAPCh. 5 - Nitrogen gas can be obtained by decomposing...Ch. 5 - Prob. 53QAPCh. 5 - Prob. 54QAPCh. 5 - Prob. 55QAPCh. 5 - Prob. 56QAPCh. 5 - A gas effuses 1.55 times faster than propane...Ch. 5 - A gas effuses through an opening one-fifth as fast...Ch. 5 - Prob. 59QAPCh. 5 - Prob. 60QAPCh. 5 - At what temperature will a molecule of uranium...Ch. 5 - Calculate the average speed of a (a) chlorine...Ch. 5 - Prob. 63QAPCh. 5 - Prob. 64QAPCh. 5 - Prob. 65QAPCh. 5 - Prob. 66QAPCh. 5 - Prob. 67QAPCh. 5 - Prob. 68QAPCh. 5 - Prob. 69QAPCh. 5 - Given that 1.00 mol of neon and 1.00 mol of...Ch. 5 - An intermediate reaction used in the production of...Ch. 5 - Prob. 72QAPCh. 5 - Prob. 73QAPCh. 5 - Glycine is an amino acid made up of carbon,...Ch. 5 - Prob. 75QAPCh. 5 - The Lamborghini Aventador engine has a 12-cylinder...Ch. 5 - Prob. 77QAPCh. 5 - Prob. 78QAPCh. 5 - Prob. 79QAPCh. 5 - Prob. 80QAPCh. 5 - Prob. 81QAPCh. 5 - Prob. 82QAPCh. 5 - Prob. 83QAPCh. 5 - The graph below shows the distribution of...Ch. 5 - Consider the following sketch. Each square in bulb...Ch. 5 - The following figure shows three 1.00-L bulbs...Ch. 5 - Prob. 87QAPCh. 5 - Prob. 88QAPCh. 5 - Prob. 89QAPCh. 5 - Prob. 90QAPCh. 5 - Prob. 91QAPCh. 5 - A 0.2500-g sample of an Al-Zn alloy reacts with...Ch. 5 - Prob. 93QAPCh. 5 - A mixture in which the mole ratio of hydrogen to...
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