Hydrogen azide, HN 3 , decomposes on heating by the following unbalanced equation: HN 3 O ( g ) → N 2 ( g ) + H 2 ( g ) If 3.0 atm of pure HN 3 (g) is decomposed initially, what is the final total pressure in the reaction container? What are the partial pressures of nitrogen and hydrogen gas? Assume the volume and temperature of the reaction container are constant.
Hydrogen azide, HN 3 , decomposes on heating by the following unbalanced equation: HN 3 O ( g ) → N 2 ( g ) + H 2 ( g ) If 3.0 atm of pure HN 3 (g) is decomposed initially, what is the final total pressure in the reaction container? What are the partial pressures of nitrogen and hydrogen gas? Assume the volume and temperature of the reaction container are constant.
Solution Summary: The author explains that the balanced equation of a reaction is written according to law of conservation of mass.
Hydrogen azide, HN3, decomposes on heating by the following unbalanced equation:
HN
3
O
(
g
)
→
N
2
(
g
)
+
H
2
(
g
)
If 3.0 atm of pure HN3(g) is decomposed initially, what is the final total pressure in the reaction container? What are the partial pressures of nitrogen and hydrogen gas? Assume the volume and temperature of the reaction container are constant.
Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 5 Solutions
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