Fundamentals of Chemical Engineering Thermodynamics (MindTap Course List)
Fundamentals of Chemical Engineering Thermodynamics (MindTap Course List)
1st Edition
ISBN: 9781111580704
Author: Kevin D. Dahm, Donald P. Visco
Publisher: Cengage Learning
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Chapter 4.8, Problem 26P
Interpretation Introduction

Interpretation:

The rate at which the entropy of the universe is increased by the boiler and condenser

Concept Introduction:

Write the steady state energy balance equation for valve.

ddt{M(U^+v22+gh)}=(j=1j=Jm˙j,in(H^j+vj22+ghj)k=1k=Km˙k,out(H^k+vk22+ghk)+W˙S+W˙EC+Q˙)

Here, time is t, total mass of the system is M, specific internal energy of the system is U^, velocity of the system is v, height of the system is h, acceleration due to gravity is g, mass flow rate for inlet and outlet streams is m˙j,in and m˙k,out, specific enthalpies of streams inlet and outlet is H^j and H^k, heights at which streams enters and leave the system is hj and hk, rate at which work is added to the system through expansion or contraction of the system is W˙EC, rate at which shaft work is added to the system is W˙S, and the rate at which heat is added to the system is Q˙.

Write the general expression for an entropy balance equation.

d(MS^)dt=j=1j=Jm˙j,inS^jk=1k=Km˙k,outS^k+n=1n=NQ˙nTn+S˙gen

Here, time is t, mass of the system is M, specific entropy of the system is S^, mass flow rates of individual streams entering and leaving the system is m˙j,in, m˙k,out, specific entropies of streams entering and leaving the system is S^j,S^k, actual rate at which heat is added to or removed from the system at one particular location is Q˙n, the temperature of the system at the boundary where the heat transfer labelled n occurs is Tn, and the rate at which entropy is generated within the boundaries of the system is S˙gen.

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