Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Textbook Question
Chapter 4.4, Problem 4.5P
The following reaction has a value of ∆G° = −2.1kJ/mol(−0.50kcaI/mol).
CH3Br + H2S ⇄ CH3 SH + HBr
- a. Calculate Keq at room temperature (25 °C) for this reaction as written.
- b. Starting with a 1 M solution of CH3Br and H2S, calculate the final concentrations of all four species at equilibrium.
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Organic Reactions Assignment
/26
Write the type of reaction that is occurring on the line provided then complete the reaction. Only include the
major products and any byproducts (e.g. H₂O) but no minor products. Please use either full structural
diagrams or the combination method shown in the lesson. Skeletal/line diagrams will not be accepted.
H3C
1.
2.
CH3
A
Acid
OH
Type of Reaction:
NH
Type of Reaction:
+ H₂O
Catalyst
+ HBr
3.
Type of Reaction:
H3C
4.
Type Reaction:
5. H3C
CH2 + H2O
OH
+
[0]
CH3
Type of Reaction:
6. OH
CH3
HO
CH3 +
Type of Reaction:
7.
Type of Reaction:
+ [H]
humbnai
Concentration Terms[1].pdf ox + New
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Inter Concreting Concentration forms.
Hydrogen peroxide is
a powerful oxidizing agent
wed in concentrated solution in rocket fuels and
in dilute solution as a
hair bleach. An aqueous
sulation of H2O2 is 30% by mass and has
density of #liligime calculat the
Ⓒmolality
⑥mole fraction of
molarity.
20
9.
B. A sample of Commercial Concentrated hydrochloric
ET
If a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.
Chapter 4 Solutions
Organic Chemistry (9th Edition)
Ch. 4.3A - Draw Lewis structures for the following free...Ch. 4.3B - a. Write the propagation steps leading to the...Ch. 4.3C - Prob. 4.3PCh. 4.3C - Prob. 4.4PCh. 4.4 - The following reaction has a value of G =...Ch. 4.4 - Under base-catalyzed conditions two molecules of...Ch. 4.5B - When ethene is mixed with hydrogen in the presence...Ch. 4.5B - For each reaction, estimate whether S for the...Ch. 4.7 - a. Propose a mechanism for the free radical...Ch. 4.7 - a. Using bond-dissociation enthalpies from...
Ch. 4.8 - The reaction of tert-butyl chloride with methanol...Ch. 4.8 - Under certain conditions, the bromination of...Ch. 4.8 - When a small piece of plat num is added to a...Ch. 4.10 - Prob. 4.14PCh. 4.10 - Prob. 4.15PCh. 4.12 - The bromination of methane proceeds through the...Ch. 4.12 - a. Using me BDEs in Table4-2 (page 167 ), compute...Ch. 4.13A - What would be the product ratio in the...Ch. 4.13A - Classify each hydrogen atom in the following...Ch. 4.13B - Use the bond-dissociation enthalpies in Tabte4-2...Ch. 4.13B - Prob. 4.21PCh. 4.13B - Prob. 4.22PCh. 4.14 - a. Compute the heats of reaction for abstraction...Ch. 4.14 - 2,3-Dimethylbutane reacts with bromine in the...Ch. 4.14 - Prob. 4.25PCh. 4.15 - Prob. 4.26PCh. 4.15 - Prob. 4.27PCh. 4.16A - Prob. 4.28PCh. 4.16A - Prob. 4.29PCh. 4.16B - Prob. 4.30PCh. 4.16C - Prob. 4.31PCh. 4.16C - Acetonitrile (CH3C N) is deprotonated by very...Ch. 4.16D - Prob. 4.33PCh. 4 - The following reaction is a common synthesis used...Ch. 4 - Consider the following reaction-energy diagram. a....Ch. 4 - Draw a reaction-energy diagram for a one-step...Ch. 4 - Draw a reaction-energy diagram for a two-step...Ch. 4 - Prob. 4.38SPCh. 4 - Treatment of tert-butyl alcohol with concentrated...Ch. 4 - Label each hydrogen atom in the following...Ch. 4 - Prob. 4.41SPCh. 4 - Prob. 4.42SPCh. 4 - Prob. 4.43SPCh. 4 - Prob. 4.44SPCh. 4 - Prob. 4.45SPCh. 4 - Prob. 4.46SPCh. 4 - For each compound, predict the major product of...Ch. 4 - When exactly 1 mole of methane is mixed with...Ch. 4 - Prob. 4.49SPCh. 4 - Prob. 4.50SPCh. 4 - Prob. 4.51SPCh. 4 - When dichloromethane is treated with strong NaOH,...Ch. 4 - Prob. 4.53SPCh. 4 - When a small amount of iodine is added to a...Ch. 4 - Prob. 4.55SPCh. 4 - When healthy, Earths stratosphere contains a low...Ch. 4 - Prob. 4.57SPCh. 4 - lodination of alkanes using iodine (I2) is usually...
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