Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 4, Problem 4.37SP
Draw a reaction-energy diagram for a two-step endothermic reaction with a rate-limiting second step.
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Sketch a qualitative reaction energy diagram for a chemical reaction with and without a catalyst. Assume the uncatalyzed reaction is endothermic.
Note: Because the sketches are only qualitative, the energies in them don't have to be exact. They only have to have the right relationship to each other. For example, if one energy is less than another, that fact should be clear in your sketch.
Sketch a crude time-temperature graph for an endothermic reaction.
Sketch a qualitative reaction energy diagram for a chemical reaction with and without a catalyst. Assume the uncatalyzed reaction is endothermic.
Note: Because the sketches are only qualitative, the energies in them don't have to be exact. They only have to have the right relationship to each other. For
example, if one energy is less than another, that fact should be clear in your sketch.
Uncatalyzed reaction
Catalyzed reaction
energy
energy
reactants
products
reactants
Ea
products
reaction coordinate
reaction coordinate
Chapter 4 Solutions
Organic Chemistry (9th Edition)
Ch. 4.3A - Draw Lewis structures for the following free...Ch. 4.3B - a. Write the propagation steps leading to the...Ch. 4.3C - Prob. 4.3PCh. 4.3C - Prob. 4.4PCh. 4.4 - The following reaction has a value of G =...Ch. 4.4 - Under base-catalyzed conditions two molecules of...Ch. 4.5B - When ethene is mixed with hydrogen in the presence...Ch. 4.5B - For each reaction, estimate whether S for the...Ch. 4.7 - a. Propose a mechanism for the free radical...Ch. 4.7 - a. Using bond-dissociation enthalpies from...
Ch. 4.8 - The reaction of tert-butyl chloride with methanol...Ch. 4.8 - Under certain conditions, the bromination of...Ch. 4.8 - When a small piece of plat num is added to a...Ch. 4.10 - Prob. 4.14PCh. 4.10 - Prob. 4.15PCh. 4.12 - The bromination of methane proceeds through the...Ch. 4.12 - a. Using me BDEs in Table4-2 (page 167 ), compute...Ch. 4.13A - What would be the product ratio in the...Ch. 4.13A - Classify each hydrogen atom in the following...Ch. 4.13B - Use the bond-dissociation enthalpies in Tabte4-2...Ch. 4.13B - Prob. 4.21PCh. 4.13B - Prob. 4.22PCh. 4.14 - a. Compute the heats of reaction for abstraction...Ch. 4.14 - 2,3-Dimethylbutane reacts with bromine in the...Ch. 4.14 - Prob. 4.25PCh. 4.15 - Prob. 4.26PCh. 4.15 - Prob. 4.27PCh. 4.16A - Prob. 4.28PCh. 4.16A - Prob. 4.29PCh. 4.16B - Prob. 4.30PCh. 4.16C - Prob. 4.31PCh. 4.16C - Acetonitrile (CH3C N) is deprotonated by very...Ch. 4.16D - Prob. 4.33PCh. 4 - The following reaction is a common synthesis used...Ch. 4 - Consider the following reaction-energy diagram. a....Ch. 4 - Draw a reaction-energy diagram for a one-step...Ch. 4 - Draw a reaction-energy diagram for a two-step...Ch. 4 - Prob. 4.38SPCh. 4 - Treatment of tert-butyl alcohol with concentrated...Ch. 4 - Label each hydrogen atom in the following...Ch. 4 - Prob. 4.41SPCh. 4 - Prob. 4.42SPCh. 4 - Prob. 4.43SPCh. 4 - Prob. 4.44SPCh. 4 - Prob. 4.45SPCh. 4 - Prob. 4.46SPCh. 4 - For each compound, predict the major product of...Ch. 4 - When exactly 1 mole of methane is mixed with...Ch. 4 - Prob. 4.49SPCh. 4 - Prob. 4.50SPCh. 4 - Prob. 4.51SPCh. 4 - When dichloromethane is treated with strong NaOH,...Ch. 4 - Prob. 4.53SPCh. 4 - When a small amount of iodine is added to a...Ch. 4 - Prob. 4.55SPCh. 4 - When healthy, Earths stratosphere contains a low...Ch. 4 - Prob. 4.57SPCh. 4 - lodination of alkanes using iodine (I2) is usually...
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- Draw an energy diagram graph for an endothermic reaction where no catalyst is present. Then draw an energy diagram graph for the same reaction when a catalyst is present. Indicate the similarities and differences between the two diagrams.arrow_forwardIn each of the following three reaction coordinate diagrams, state: (a) Whether the reaction is exothermic or endothermic. (b) Whether the reaction is the slowest, the fastest, or intermediate in rate. (c) If all three reactions have the same entropy change between the reactant and product, which reaction has the largest favorable G0.arrow_forwardSketch a qualitative reaction energy diagram for a chemical reaction with and without a catalyst. Assume the uncatalyzed reaction is endothermic. Note: Because the sketches are only qualitative, the energies in them don't have to be exact. They only have to have the right relationship to each other. For example, if one energy is less than another, that fact should be clear in your sketch. Uncatalyzed reaction Catalyzed reaction energy energy do reactants products reactants Ea products reaction coordinate reaction coordinate Explanation Check O 2021 McGraw-Hill Education. All Rights Reserved. Terms of Use I Privacy Accessibility 638 4 MacBook Air 42 4) DAI DD 111 888 F10 F9 F7 F6 F5 esc F3 F4 F2 %23 $ % & 6. 7 8 3 4 R T U W tabarrow_forward
- Draw a reaction-energy diagram for a one-step exothermic reaction. Label the parts that represent the reactants, products, transition state, activation energy, and heat of reactionarrow_forwardSketch a qualitative reaction energy diagram for a chemical reaction with and without a catalyst. Assume the uncatalyzed reaction is exothermic. Note: Because the sketches are only qualitative, the energies in them don't have to be exact. They only have to have the right relationship to each other. For example, if one energy is less than another, that fact should be clear in your sketch. Uncatalyzed reaction Catalyzed reaction energy energy reactants product eactant products reaction coordinate content Explanation Check P Type here to search Alt Al alexa ENABLEDarrow_forwardFactors Affecting Reaction Ratesarrow_forward
- Drawing thé reaction energy dlagrum Sketch a qualitative reaction energy diagram for a chemical reaction with and without a catalyst. Assume the uncatalyzed reaction is endothermic. Note: Because the sketches are only qualitative, the energies in them don't have to be exact. They only have to have the right relationship to each other. For example, if one energy is less than another, that fact should be clear in your sketch. Uncatalyzed reaction energy Catalyzed reaction energy reactants Ea products reactants products reaction coordinate reaction coordinate Explanation Check O2021 McGraw-Hill Education. All Rights Reserved. Terms of Use | Privacy Accessibility MacBook Air 4) DII 88 F10 F11 F9 F8 esc F5 F6 F7 F1 F2 F3 F4 &arrow_forwardtopic: chemical kineteics is it true that a reaction that occurs quickly must be an irreversible reaction? why or why not?arrow_forwardDraw a reaction coordinate diagram for a two-step reaction in which the first step is endergonic, the second step is exergonic, and the overall reaction is endergonic. Label the reactants, products, intermediates, and transition states.arrow_forward
- Consider this reaction diagrams where R is reactants and P is products. What would the reaction diagram look like if a catalyst was added?arrow_forwardIn studying a reaction that goes to completion (this is not a reversible reaction) what happens to the rate with the addition of a catalyst? Will the rate increase, decrease, or stay the same?arrow_forwardSelect all of the correct statements about reaction rates from the choices below. 1. The lower the rate of a reaction the longer it takes to reach completion.2. The rate of a slow step has more effect on the overall reaction rate than the rate of a fast step.3. Reaction rates decrease with increasing temperature.4. As a reaction progresses its rate goes down.5. Solid catalysts increase reaction rates as their surface areas increase.6. The rate of a reaction is independent of temperature.7. Reaction rates can show little change as masses of solid reactants increase.arrow_forward
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