Bundle: Physics for Scientists and Engineers with Modern Physics, Loose-leaf Version, 9th + WebAssign Printed Access Card, Multi-Term
9th Edition
ISBN: 9781305932302
Author: Raymond A. Serway, John W. Jewett
Publisher: Cengage Learning
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Chapter 43, Problem 17P
The nuclei of the O2 molecule are separated by a distance 1.20 × 10−10 m. The mass of each oxygen atom in the molecule is 2.66 × 10−26 kg. (a) Determine the rotational energies of an oxygen molecule in electron volts for the levels corresponding to J = 0, 1, and 2. (b) The effective force constant k between the atoms in the oxygen molecule is 1 177 N/m. Determine the vibrational energies (in electron volts) corresponding to v = 0, 1, and 2.
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One description of the potential energy of a diatomic molecule is given by the Lennard–Jones potential, U = (A)/(r12) - (B)/(r6)where A and B are constants and r is the separation distance between the atoms. For the H2 molecule, take A = 0.124 x 10-120 eV ⋅ m12 and B = 1.488 x 10-60 eV ⋅ m6. Find (a) the separation distance r0 at which the energy of the molecule is a minimum and (b) the energy E required to break up theH2 molecule.
One model for the potential energy of a two-atom molecule, where the atoms are separated by a distance r, is
U(r) = Uo[(¹) ¹2 – ( )²]
where ro = 0.8 nm and U₁ = 6.1 eV.
Note: 1 eV = 1.6 × 10-19 J.
Some helpful units:
[Force] = eV/nm
[Energy] = eV
[distance] = nm
Equilibrium Distance
What is the distance between the atoms when the molecule is in stable equilibrium?
Click here for a hint
T'eq
Hint:
Hint:
Hint:
Hint:
Hint:
Hint:
Force
If the distance between the atoms increases from equilibrium by r₁ = 0.35 nm, then what is the force from one atom on the other associated with this potential energy? (Enter your answer as postive if they repel each other, and negative if they attract.)
Fr(req+r₁)
Hint:
Hint:
0.89105934nm
Kinetic Energy
Hint:
The atoms are oscillating back and forth. The maximum separation of the atoms is r₂ = 2 nm. What is the kinetic energy of the atoms when they are separated by the equilibrium distance?
Click here for a hint
K(req)
Hint:
Hint:
= -1.288eV/nm
3.99eV
Calculate the radius of a nickel atom in cm, given that Ni has an FCC crystal structure, a density of 7.982 g/cm³, and an atomic weight of 58.69 g/mol.
Chapter 43 Solutions
Bundle: Physics for Scientists and Engineers with Modern Physics, Loose-leaf Version, 9th + WebAssign Printed Access Card, Multi-Term
Ch. 43.1 - For each of the following atoms or molecules,...Ch. 43.2 - Prob. 43.2QQCh. 43.2 - Prob. 43.3QQCh. 43 - Prob. 1OQCh. 43 - Prob. 2OQCh. 43 - Prob. 3OQCh. 43 - Prob. 4OQCh. 43 - Prob. 5OQCh. 43 - Prob. 6OQCh. 43 - Prob. 7OQ
Ch. 43 - Prob. 1CQCh. 43 - Prob. 2CQCh. 43 - Prob. 3CQCh. 43 - Prob. 4CQCh. 43 - Prob. 5CQCh. 43 - Prob. 6CQCh. 43 - Prob. 7CQCh. 43 - Prob. 8CQCh. 43 - Discuss models for the different types of bonds...Ch. 43 - Prob. 10CQCh. 43 - Prob. 1PCh. 43 - Prob. 2PCh. 43 - Prob. 3PCh. 43 - Prob. 4PCh. 43 - Prob. 5PCh. 43 - Prob. 6PCh. 43 - Prob. 7PCh. 43 - Prob. 8PCh. 43 - Prob. 9PCh. 43 - Prob. 10PCh. 43 - Prob. 12PCh. 43 - Prob. 13PCh. 43 - Prob. 14PCh. 43 - Prob. 15PCh. 43 - Prob. 16PCh. 43 - The nuclei of the O2 molecule are separated by a...Ch. 43 - Prob. 18PCh. 43 - Prob. 19PCh. 43 - Prob. 20PCh. 43 - Prob. 21PCh. 43 - Prob. 22PCh. 43 - Prob. 23PCh. 43 - Prob. 24PCh. 43 - Prob. 25PCh. 43 - Prob. 27PCh. 43 - Prob. 28PCh. 43 - Prob. 29PCh. 43 - Prob. 30PCh. 43 - Prob. 31PCh. 43 - Prob. 32PCh. 43 - Prob. 33PCh. 43 - Prob. 34PCh. 43 - Prob. 35PCh. 43 - Prob. 36PCh. 43 - Prob. 37PCh. 43 - Prob. 38PCh. 43 - Prob. 39PCh. 43 - Prob. 40PCh. 43 - Prob. 41PCh. 43 - Prob. 42PCh. 43 - Prob. 43PCh. 43 - Prob. 44PCh. 43 - Prob. 45PCh. 43 - Prob. 46PCh. 43 - Prob. 47PCh. 43 - Prob. 49PCh. 43 - Prob. 50PCh. 43 - Prob. 51PCh. 43 - A direct and relatively simple demonstration of...Ch. 43 - Prob. 53PCh. 43 - Prob. 54APCh. 43 - Prob. 55APCh. 43 - Prob. 56APCh. 43 - Prob. 57APCh. 43 - Prob. 58APCh. 43 - Prob. 59APCh. 43 - Prob. 61APCh. 43 - Prob. 62APCh. 43 - Prob. 63CPCh. 43 - As an alternative to Equation 43.1, another useful...
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