The systematic name of given compounds has to be provided. Concept Introduction: Nomenclature of organic compounds: The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are, The longer number of Carbon chain of a compound is identified this is called parent of the compound. In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound. The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain. The names of all substituents are arranged by alphabets to starts with lowest numbering. In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Question

#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

Answer 1

Question

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

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Answer 3

Question

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

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Answer 4

Question

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

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Answer 5

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 6

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 7

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 14

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Answer 25

Ch. 4.2 - Prob. 1LTS Ch. 4.2 - Prob. 1PTS Ch. 4.2 - Prob. 2PTS Ch. 4.2 - Prob. 3ATS Ch. 4.2 - Prob. 2LTS Ch. 4.2 - Prob. 4PTS Ch. 4.2 - Prob. 5ATS Ch. 4.2 - Prob. 3LTS Ch. 4.2 - Prob. 6PTS Ch. 4.2 - Prob. 7ATS

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Chapter 4 Solutions