The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined. Concept Introduction: Conformational isomers: The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers. The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial. The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane. The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position. The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position . The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

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Answer 1

Question

Chapter 4.12, Problem 33PTS

(a)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(b)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(c)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(d)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(e)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter 4.12, Problem 33PTS

(a)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(b)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(c)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(d)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(e)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

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Answer 3

Question

Chapter 4.12, Problem 33PTS

(a)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(b)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(c)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(d)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(e)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

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Answer 4

Question

Chapter 4.12, Problem 33PTS

(a)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(b)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(c)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(d)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(e)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

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Answer 5

Chapter 4.12, Problem 33PTS

(a)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(b)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(c)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(d)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

(e)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

Answer 6

Chapter 4.12, Problem 33PTS

(a)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

Answer 7

Chapter 4.12, Problem 33PTS

(a)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformation of given compounds are drawn and the lowest energy conformation should be determined.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.

The chair conformation of Cyclohexane have two positions of substituents which are axial and equatorial.

The normal wedge representations are used to draw the positions of Cyclohexane conformations. The dark wedge bond represents the group is pointing above the plane and the light wedge bond represents the group is pointing below the plane.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.

Answer 16

Expert Solution & Answer

Answer 17

Expert Solution & Answer

Answer 18

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Answer 19

Ch. 4.2 - Prob. 1LTS Ch. 4.2 - Prob. 1PTS Ch. 4.2 - Prob. 2ATS Ch. 4.2 - Prob. 3ATS Ch. 4.2 - Prob. 4ATS Ch. 4.2 - Prob. 2LTS Ch. 4.2 - Prob. 5PTS Ch. 4.2 - Prob. 6ATS Ch. 4.2 - Prob. 3LTS Ch. 4.2 - Prob. 7PTS

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