CAREY: ORGANIC CHEMISTRY
10th Edition
ISBN: 9781260364002
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Chapter 4.10, Problem 17P
Interpretation Introduction
Interpretation:
The crystalline solid stereoisomer of
Concept introduction:
Enantiomers are stereoisomers but non-superimposable mirror images.
Enantiomers have similar physical properties like density, melting point and boiling point.
The configuration at the corresponding chiral centers is exactly opposite in case of enantiomers.
Diastereomers are stereoisomers and are not mirror images of each other.
Diastereomers have very different physical and chemical properties.
Diastereomers have at least two chiral centers and they are not mirror images of each other; they must have an opposite configuration for at least one chirality centers.
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Give the major product of the following reaction.
excess
1. OH, H₂O
1.OH
H
CH3CH2CH21
H
2. A.-H₂O
Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and
Advanced Template toolbars. The single bond is active by default.
2. Use Hess's law to calculate the AH
(in kJ) for:
rxn
CIF(g) + F2(g) →
CIF 3 (1)
using the following information:
2CIF(g) + O2(g) →
Cl₂O(g) + OF 2(g)
AH = 167.5 kJ
ΔΗ
2F2 (g) + O2(g) → 2 OF 2(g)
2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g)
о
=
= -43.5 kJ
AH = 394.1kJ
ci
Draw the major product(s) of the following reactions: (3 pts)
CH3
HNO3/H2SO4
HNO3/ H2SO4
OCH3
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Chapter 4 Solutions
CAREY: ORGANIC CHEMISTRY
Ch. 4.2 - Examine the following for chirality centers:Ch. 4.2 - Prob. 2PCh. 4.3 - Prob. 3PCh. 4.3 - Prob. 4PCh. 4.4 - Prob. 5PCh. 4.4 - Prob. 6PCh. 4.5 - Does the molecular model shown represent...Ch. 4.6 - Assign absolute configurations as R or S to each...Ch. 4.6 - Draw three-dimensional representations ofCh. 4.7 - Prob. 10P
Ch. 4.7 - Using the Fischer projection of (R)-2-butanol...Ch. 4.8 - Prob. 12PCh. 4.9 - Prob. 13PCh. 4.9 - Prob. 14PCh. 4.10 - Prob. 15PCh. 4.10 - Draw Fischer projections of the four...Ch. 4.10 - Prob. 17PCh. 4.11 - A meso stereoisomer is possible for one of the...Ch. 4.11 - One of the stereoisomers of...Ch. 4.12 - Prob. 20PCh. 4.12 - Prob. 21PCh. 4.13 - Prob. 22PCh. 4.13 - Prob. 23PCh. 4.13 - Prob. 24PCh. 4.14 - Prob. 25PCh. 4 - Prob. 26PCh. 4 - Including stereoisomers, write structural formulas...Ch. 4 - Prob. 28PCh. 4 - Prob. 29PCh. 4 - Prob. 30PCh. 4 - Prob. 31PCh. 4 - Prob. 32PCh. 4 - Prob. 33PCh. 4 - Prob. 34PCh. 4 - Prob. 35PCh. 4 - Prob. 36PCh. 4 - Prob. 37PCh. 4 - Prob. 38PCh. 4 - Prob. 39PCh. 4 - (-)-Menthol is the most stable stereoisomer of...Ch. 4 - Prob. 41PCh. 4 - Prob. 42PCh. 4 - (a) An aqueous solution containing 10 g of...Ch. 4 - Prob. 44DSPCh. 4 - Prob. 45DSPCh. 4 - Consider two chemical changes: one occurring at a...Ch. 4 - Consider two chemical changes: one occurring at a...Ch. 4 - Prob. 48DSPCh. 4 - Consider two chemical changes: one occurring at a...Ch. 4 - Consider two chemical changes: one occurring at a...
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