The spherical harmonics
Answer to Problem 4.7P
The spherical harmonics
Explanation of Solution
Write the general expression for the spherical harmonics
Here,
Write the expression for the associated Legendre function.
Here,
Write the expression for the Legendre function.
Use equation (III) in (II) to solve for
The
Then the equation (IV) becomes,
The expansion of
Use equation (VI) in (V) and it becomes,
Use equation (VII) in (I) to solve for the spherical harmonics
Use equation (VIII) to find
Consider
Differentiate equation (X) with respect to
Take the second derivative of
The sum of the equations (XII) and (XI) can be written as
The equation (XIII) satisfies with the equation given in (4.18).
Consider
Take the partial derivative of equation (XIV) with respect to
Use equation (XV) in (XIII) and it can be written as
Take the second partial derivative of
Use equation (XVII) and (XVI) in (XIII) and compare,
In equation (XVIII), where
Conclusion:
Therefore, The spherical harmonics
Want to see more full solutions like this?
Chapter 4 Solutions
Introduction To Quantum Mechanics
- Problem 3.36. Consider an Einstein solid for which both N and q are much greater than 1. Think of each oscillator as a separate "particle." (a) Show that the chemical potential is N+ - kT ln N (b) Discuss this result in the limits N > q and N « q, concentrating on the question of how much S increases when another particle carrying no energy is added to the system. Does the formula make intuitive sense?arrow_forward2.arrow_forwardPlease answer completelyarrow_forward
- Problem 9.24 If you take the model in Ex. 4.1 at face value, what natural frequency do you get? Put in the actual numbers. Where, in the electromagnetic spectrum, does this lie, assuming the radius of the atom is 0.5 Å? Find the coefficients of refraction and dispersion, and compare them with the measured values for hydrogen at 0°C and atmospheric pressure: A = 1.36 × 10-4, B = 7.7 x 10-15 m².arrow_forwardIn terms of the totally antisymmetric E-symbol (Levi-Civita tensor) with €123 = +1, the vector product can be written as (A x B) i = tijk Aj Bk, where i, j, k = 1, 2, 3 and summation over repeated indices (here j and k) is implied. i) ii) iii) iv) For general vectors A and B, using (2) prove the following relations: a) A x B=-B x A b) (A x B) A = (A x B) - B = 0. The Levi-Civita symbol is related to the Kronecker delta. Prove the following very useful formula €ijk€ilm = 8j18km - Sjm³ki. (2) Prove the formula (3) €imn€jmn = 2dij. Assuming that (3) is true (and using antisymmetry of the E-symbol), prove the relation A x (B x C) = (AC) B- (AB) Carrow_forwardConsider the function v(1,2) =( [1s(1) 3s(2) + 3s(1) 1s(2)] [x(1) B(2) + B(1) a(2)] Which of the following statements is incorrect concerning p(1,2) ? a. W(1,2) is normalized. Ob. The function W(1,2) is symmetric with respect to the exchange of the space and the spin coordinates of the two electrons. OC. y(1,2) is an eigenfunction of the reference (or zero-order) Hamiltonian (in which the electron-electron repulsion term is ignored) of Li with eigenvalue = -5 hartree. d. The function y(1,2) is an acceptable wave function to describe the properties of one of the excited states of Lit. Oe. The function 4(1,2) is an eigenfunction of the operator S,(1,2) = S;(1) + S,(2) with eigenvalue zero.arrow_forward
- Let's consider a harmonic oscillator. The total energy of this oscillator is given by E=(p²/2m) +(½)kx?. A) For constant energy E, graph the energies in the range E to E + dE, the allowed region in the classical phase space (p-x plane) of the oscillator. B) For k = 6.0 N / m, m = 3.0 kg and the maximum amplitude of the oscillator xmax =2.3 m For the region with energies equal to or less than E, the oscillator number of states that can be entered D(E).arrow_forwardQUESTION 3: Abstract angular momentum operators: In this problem you may assume t commutation relations between the general angular momentum operators Ĵ, Ĵy, Ĵz. Use whenev possible the orthonormality of normalised angular momentum eigenstate |j, m) and that α = Îx±iĴy, Ĵ²|j,m) = ħ²j(j + 1)|j,m) and Ĵz|j,m) (a) Express ĴĴ_ in terms of Ĵ² and Ĵ₂. = ħmlj, m). (b) Using the result from (a) find the expectation value (j,m|εÎ_|j,m). (This is the nor squared of the state Î_|j,m).)arrow_forwardV7arrow_forward
- Problem 4.2 According to quantum mechanics, the electron cloud for a hydrogen atom in the ground state has a charge density. –2r/a p(r) = where q is the charge of the electron and a is the Bohr radius. Find the atomic polarizability of such an atom. [Hint: First calculate the electric field of the electron cloud, Ee(r); then expand the exponential, assuming r « a. For a more sophisticated approach, see W. A. Bowers, Am. J. Phys. 54, 347 (1986).]arrow_forwardProblem 3: Chemical potential of an Einstein solid. Consider an Einstein solid for which both N and q are much greater than 1. Think of each ocillator as a separate “particle". a) Show that the chemical potential is H = -kT In (**e) b) Discuss this result in the limits N » q and N « q, concentrating on the question of how much S increases when another particle carrying no energy is added to the system. Does the formula make intuitive sense?arrow_forwardConsider a composite state of spin j1 = s = 1/2 and angular momentum j2 = l = 2 of an electron. Find all the eigenstates of |j1, j2; j,m〉 as the linear combination of product states of spin and angular momentum. Give the values of Clebsch-Gordon coefficients you get from here.arrow_forward
- Classical Dynamics of Particles and SystemsPhysicsISBN:9780534408961Author:Stephen T. Thornton, Jerry B. MarionPublisher:Cengage Learning