INTOR TO CHEMISTRY LLF
5th Edition
ISBN: 9781264501731
Author: BAUER
Publisher: MCG
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Textbook Question
Chapter 4, Problem 72QP
Which of the following compounds of carbon and hydrogen have identical empirical formulas:
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5.
Use the MS data to answer the questions on the next page.
14.0
1.4
15.0
8.1
100-
MS-IW-5644
26.0
2.8
27.0
6.7
28.0
1.8
29.0
80
4.4
38.0
1.0
39.0
1.5
41.0
1.2
42.0
11.2
43.0
100.0
44.0
4.3
79.0
1.9
80.0
2.6
Relative Intensity
40
81.0
1.9
82.0
2.5
93.0
8.7
20-
95.0
8.2
121.0
2.0
123.0
2.0
136.0
11.8
0
138.0
11.5
20
40
8.
60
a.
Br
- 0
80
100
120
140
160
180
200
220
m/z
Identify the m/z of the base peak and molecular ion.
2
b.
Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0,
95.0, 136.0, and 138.0 m/z.
C.
Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to
fragment 43.0 m/z. Be sure to include all electrons and formal charges.
6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium
ion (CsH6N) and show your work.
None
Stereochemistry: Three possible answers- diastereomers, enantiomers
OH
CH₂OH
I
-c=0
21108 1101
41745 HOR
CH₂OH
IL
Но
CH₂OH
TIL
a. Compounds I and III have this relationship with each other: enantiomers
b. Compounds II and IV have this relationship with each other:
c. Compounds I and II have this relationship with each other:
d. *Draw one structure that is a stereoisomer of II, but neither a
diastereomer nor an enantiomer. (more than one correct answer)
Chapter 4 Solutions
INTOR TO CHEMISTRY LLF
Ch. 4 - Prob. 1QCCh. 4 - Prob. 2QCCh. 4 - Prob. 3QCCh. 4 - Prob. 4QCCh. 4 - Prob. 1PPCh. 4 - Prob. 2PPCh. 4 - Prob. 3PPCh. 4 - Prob. 4PPCh. 4 - Prob. 5PPCh. 4 - Prob. 6PP
Ch. 4 - Prob. 7PPCh. 4 - Prob. 8PPCh. 4 - Prob. 9PPCh. 4 - Prob. 10PPCh. 4 - Prob. 11PPCh. 4 - Prob. 12PPCh. 4 - Prob. 13PPCh. 4 - Prob. 14PPCh. 4 - Prob. 15PPCh. 4 - Prob. 16PPCh. 4 - Prob. 17PPCh. 4 - Prob. 18PPCh. 4 - Prob. 19PPCh. 4 - Prob. 20PPCh. 4 - Prob. 21PPCh. 4 - Prob. 22PPCh. 4 - Prob. 23PPCh. 4 - Prob. 1QPCh. 4 - Prob. 2QPCh. 4 - Prob. 3QPCh. 4 - Prob. 4QPCh. 4 - Prob. 5QPCh. 4 - Prob. 6QPCh. 4 - Lithium carbonate, Li2CO3 , contains 18.8 lithium...Ch. 4 - Prob. 8QPCh. 4 - Prob. 9QPCh. 4 - Prob. 10QPCh. 4 - Prob. 11QPCh. 4 - Prob. 12QPCh. 4 - Prob. 13QPCh. 4 - Prob. 14QPCh. 4 - Prob. 15QPCh. 4 - Prob. 16QPCh. 4 - Prob. 17QPCh. 4 - Prob. 18QPCh. 4 - Prob. 19QPCh. 4 - Prob. 20QPCh. 4 - Prob. 21QPCh. 4 - Prob. 22QPCh. 4 - Prob. 23QPCh. 4 - Prob. 24QPCh. 4 - Prob. 25QPCh. 4 - Prob. 26QPCh. 4 - Prob. 27QPCh. 4 - Calculate the molar mass of each of the following...Ch. 4 - Prob. 29QPCh. 4 - Prob. 30QPCh. 4 - Prob. 31QPCh. 4 - Prob. 32QPCh. 4 - Prob. 33QPCh. 4 - Prob. 34QPCh. 4 - Prob. 35QPCh. 4 - Prob. 36QPCh. 4 - Prob. 37QPCh. 4 - Prob. 38QPCh. 4 - Prob. 39QPCh. 4 - Prob. 40QPCh. 4 - Prob. 41QPCh. 4 - Prob. 42QPCh. 4 - Prob. 43QPCh. 4 - Calculate the mass of 0.750 mol of the following...Ch. 4 - Prob. 45QPCh. 4 - Prob. 46QPCh. 4 - A sample of ammonia, NH3 , weights 30.0 g....Ch. 4 - Prob. 48QPCh. 4 - Which of these substance has the most atoms per...Ch. 4 - Which of these substances has the atoms per mole?...Ch. 4 - A raindrop weighs 0.050 g. How many molecules of...Ch. 4 - A gain of sand weighs 7.7104g . How many formula...Ch. 4 - How many formula units are in 250.0 g of the...Ch. 4 - How many formula units are in 375.0 g of the...Ch. 4 - How many atoms (or ions) of each element are in...Ch. 4 - How many atoms (or ions) of each element are in...Ch. 4 - What is the mass of 6.41022 molecules of SO2?Ch. 4 - What is the mass of 1.81021 molecules of H2SO4?Ch. 4 - Which compound, NH3,NH4Cl,NO2,orN203, contains the...Ch. 4 - Which compound, NaCl,PC13,CaC12,orHCIO2, contains...Ch. 4 - You have two colorless gases, each made of sulfur...Ch. 4 - Describe some uses for the percent composition of...Ch. 4 - What is the difference between an empirical...Ch. 4 - Why do we normally use an empirical formula...Ch. 4 - Which of the following molecules have an empirical...Ch. 4 - Which of the following substances have an...Ch. 4 - Prob. 67QPCh. 4 - What is the empirical formula of each of the...Ch. 4 - Prob. 69QPCh. 4 - Prob. 70QPCh. 4 - Which of the following compounds of nitrogen and...Ch. 4 - Which of the following compounds of carbon and...Ch. 4 - What are the empirical formulas of the compounds...Ch. 4 - What are the empirical formulas of the compounds...Ch. 4 - Eugenol, a chemical substance with the flavor of...Ch. 4 - One of the compounds in cement has the following...Ch. 4 - The explosive trinitrotoluene (TNT) has the...Ch. 4 - Strychnine (rat poison) has the composition...Ch. 4 - An unknown organic compound was determined to have...Ch. 4 - Prob. 80QPCh. 4 - Prob. 81QPCh. 4 - Prob. 82QPCh. 4 - Prob. 83QPCh. 4 - Prob. 84QPCh. 4 - Prob. 85QPCh. 4 - Prob. 86QPCh. 4 - What is the percent composition of each of the...Ch. 4 - Prob. 88QPCh. 4 - Prob. 89QPCh. 4 - Prob. 90QPCh. 4 - Prob. 91QPCh. 4 - Prob. 92QPCh. 4 - Prob. 93QPCh. 4 - Prob. 94QPCh. 4 - Prob. 95QPCh. 4 - Prob. 96QPCh. 4 - Prob. 97QPCh. 4 - Prob. 98QPCh. 4 - Prob. 99QPCh. 4 - Prob. 100QPCh. 4 - Prob. 101QPCh. 4 - Prob. 102QPCh. 4 - Prob. 103QPCh. 4 - Prob. 104QPCh. 4 - Prob. 105QPCh. 4 - Prob. 106QPCh. 4 - Prob. 107QPCh. 4 - Prob. 108QPCh. 4 - Prob. 109QPCh. 4 - Prob. 110QPCh. 4 - Prob. 111QPCh. 4 - Prob. 112QPCh. 4 - Prob. 113QPCh. 4 - Prob. 114QPCh. 4 - Prob. 115QPCh. 4 - Prob. 116QPCh. 4 - Prob. 117QPCh. 4 - How many molecules are present in 15.43 g of butyl...Ch. 4 - Prob. 119QPCh. 4 - Prob. 120QPCh. 4 - Prob. 121QPCh. 4 - Prob. 122QPCh. 4 - Prob. 123QPCh. 4 - Prob. 124QPCh. 4 - Prob. 125QPCh. 4 - Prob. 126QPCh. 4 - Prob. 127QPCh. 4 - Prob. 128QPCh. 4 - Prob. 129QPCh. 4 - Prob. 130QPCh. 4 - Prob. 131QPCh. 4 - Prob. 132QPCh. 4 - Prob. 133QPCh. 4 - Prob. 134QPCh. 4 - Prob. 135QPCh. 4 - Prob. 136QPCh. 4 - Prob. 137QPCh. 4 - Prob. 138QPCh. 4 - Prob. 139QPCh. 4 - Prob. 140QPCh. 4 - Prob. 141QPCh. 4 - Prob. 142QPCh. 4 - Prob. 143QPCh. 4 - Prob. 144QPCh. 4 - Prob. 145QPCh. 4 - Prob. 146QPCh. 4 - Prob. 147QPCh. 4 - Prob. 148QPCh. 4 - Prob. 149QPCh. 4 - Prob. 150QPCh. 4 - Prob. 151QPCh. 4 - Prob. 152QP
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