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Chemistry: A Molecular Approach, Books a la Carte Plus Mastering Chemistry with Pearson eText -- Access Card Package (4th Edition)
4th Edition
ISBN: 9780134162454
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 4, Problem 64E
Interpretation Introduction
To determine: The volume of a diluted solution when 25 mL of 10.0 M
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Students have asked these similar questions
You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 4 Solutions
Chemistry: A Molecular Approach, Books a la Carte Plus Mastering Chemistry with Pearson eText -- Access Card Package (4th Edition)
Ch. 4 - Prob. 1SAQCh. 4 - Q2. Sodium and chlorine react to form sodium...Ch. 4 - Prob. 3SAQCh. 4 - Prob. 4SAQCh. 4 - Prob. 5SAQCh. 4 - Prob. 6SAQCh. 4 - Prob. 7SAQCh. 4 - Prob. 8SAQCh. 4 - Prob. 9SAQCh. 4 - Q10. What is the net ionic equation for the...
Ch. 4 - Q11. What is the net ionic equation for the...Ch. 4 - Q12. What is the net ionic equation for the...Ch. 4 - Prob. 13SAQCh. 4 - Prob. 14SAQCh. 4 - Prob. 15SAQCh. 4 - 1. What is reaction stoichiometry? What is the...Ch. 4 - Prob. 2ECh. 4 - Prob. 3ECh. 4 - Prob. 4ECh. 4 - 5. What is molarity? How is it useful?
Ch. 4 - 6. Explain how a strong electrolyte, a weak...Ch. 4 - 7. Explain the difference between a strong acid...Ch. 4 - Prob. 8ECh. 4 - Prob. 9ECh. 4 - Prob. 10ECh. 4 - Prob. 11ECh. 4 - Prob. 12ECh. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - 15. What is an acid–base reaction? Give an...Ch. 4 - 16. Explain the principles behind an acid–base...Ch. 4 - 17. What is a gas-evolution reaction? Give an...Ch. 4 - 18. What reactant types give rise to gas-evolution...Ch. 4 - Prob. 19ECh. 4 - Prob. 20ECh. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - 23. In a redox reaction, which reactant is the...Ch. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - 27. Calculate how many moles of NO2 form when each...Ch. 4 - 28. Calculate how many moles of NH3 form when each...Ch. 4 - Prob. 29ECh. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - 33. For each of the reactions, calculate the mass...Ch. 4 - 34. For each of the reactions, calculate the mass...Ch. 4 - 35. For each of the acid–base reactions, calculate...Ch. 4 - Prob. 36ECh. 4 - 37. Find the limiting reactant for each initial...Ch. 4 - 38. Find the limiting reactant for each initial...Ch. 4 - 39. Consider the reaction:
4 HCl(g) + O2(g) → 2...Ch. 4 - Prob. 40ECh. 4 - Prob. 41ECh. 4 - Prob. 42ECh. 4 - 43. Zinc sulfide reacts with oxygen according to...Ch. 4 - 44. Iron(II) sulfide reacts with hydrochloric acid...Ch. 4 - Prob. 45ECh. 4 - Prob. 46ECh. 4 - 47. Iron(III) oxide reacts with carbon monoxide...Ch. 4 - Prob. 48ECh. 4 - 49. Lead ions can be precipitated from solution...Ch. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - 53. Calculate the molarity of each solution.
a....Ch. 4 - Prob. 54ECh. 4 - 55. What is the molarity of NO3– in each...Ch. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - 58. What volume of 0.200 M ethanol solution...Ch. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - 61. If 123 mL of a 1.1 M glucose solution is...Ch. 4 - 62. If 3.5 L of a 4.8 M SrCl2 solution is diluted...Ch. 4 - 63. To what volume should you dilute 50.0 mL of a...Ch. 4 - 64. To what volume should you dilute 25 mL of a...Ch. 4 - Prob. 65ECh. 4 - 66. Consider the reaction:
Li2S(aq) + Co(NO3)2(aq)...Ch. 4 - 67. What is the minimum amount of 6.0 M H2SO4...Ch. 4 - Prob. 68ECh. 4 - 69. A 25.0-mL sample of a 1.20 M potassium...Ch. 4 - Prob. 70ECh. 4 - Prob. 71ECh. 4 - Prob. 72ECh. 4 - Prob. 73ECh. 4 - Prob. 74ECh. 4 - Prob. 75ECh. 4 - 76. Complete and balance each equation. If no...Ch. 4 - Write a molecular equation for the precipitation...Ch. 4 - 78. Write a molecular equation for the...Ch. 4 - Prob. 79ECh. 4 - 80. Write balanced complete ionic and net ionic...Ch. 4 - Prob. 81ECh. 4 - Prob. 82ECh. 4 - 83. Write balanced molecular and net ionic...Ch. 4 - Prob. 84ECh. 4 - Prob. 85ECh. 4 - Prob. 86ECh. 4 - Prob. 87ECh. 4 - 88. Write balanced complete ionic and net ionic...Ch. 4 - Prob. 89ECh. 4 - 90. A 30.00-mL sample of an unknown H3PO4 solution...Ch. 4 - Prob. 91ECh. 4 - Prob. 92ECh. 4 - Prob. 93ECh. 4 - Prob. 94ECh. 4 - Prob. 95ECh. 4 - Prob. 96ECh. 4 - Prob. 97ECh. 4 - Prob. 98ECh. 4 - Prob. 99ECh. 4 - Prob. 100ECh. 4 - Prob. 101ECh. 4 - Prob. 102ECh. 4 - 103. People sometimes use sodium bicarbonate as an...Ch. 4 - 104. Toilet bowl cleaners often contain...Ch. 4 - Prob. 105ECh. 4 - Prob. 106ECh. 4 - Prob. 107ECh. 4 - Prob. 108ECh. 4 - Prob. 109ECh. 4 - 110. A hydrochloric acid solution will neutralize...Ch. 4 - 111. Predict the products and write a balanced...Ch. 4 - 112. Predict the products and write a balanced...Ch. 4 - Prob. 113ECh. 4 - Prob. 114ECh. 4 - Prob. 115ECh. 4 - Prob. 116ECh. 4 - 117. The nitrogen in sodium nitrate and in...Ch. 4 - 118. Find the volume of 0.110 M hydrochloric acid...Ch. 4 - Prob. 119ECh. 4 - 120. We prepare a solution by mixing 0.10 L of...Ch. 4 - Prob. 121ECh. 4 - Prob. 122ECh. 4 - Prob. 123ECh. 4 - 124. An important reaction that takes place in a...Ch. 4 - 125. A liquid fuel mixture contains 30.35% hexane...Ch. 4 - 126. Titanium occurs in the magnetic mineral...Ch. 4 - Prob. 127ECh. 4 - Prob. 128ECh. 4 - Prob. 129ECh. 4 - Prob. 130ECh. 4 - 131. Recall from Section 4.6 that sodium carbonate...Ch. 4 - 132. Lead poisoning is a serious condition...Ch. 4 - Prob. 133ECh. 4 - Prob. 134ECh. 4 - Prob. 135ECh. 4 - Prob. 136ECh. 4 - Prob. 137ECh. 4 - Prob. 138ECh. 4 - Prob. 139ECh. 4 - Prob. 140ECh. 4 - Prob. 141QGWCh. 4 - Prob. 142QGWCh. 4 - Prob. 143QGWCh. 4 - 144. Define and give an example of each of the...Ch. 4 - Prob. 145QGWCh. 4 - Prob. 146DIA
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY