(a)
Interpretation:
The number of moles of pyridine (unused in reaction of cisplatin) should be determined.
Concept introduction:
Number of moles is equal to the ratio of given mass to the molar mass.
The mathematical expression is given by:
Number of moles =
Molarity is defined as the ratio of number of moles of solute to the volume of the solution in liters.
The mathematical expression is given by:
Molarity =
Density is defined as the ratio of mass to the volume.
Density =
(b)
Interpretation:
The number of moles of pyridine which react with one mole of cisplatin should be calculated.
Concept introduction:
The relation between the number of moles of the substances reacting in a reaction can be obtained from the balanced chemical equation for the reaction. From mass and molar mass of a substance, number of moles can be calculated as follows:
Here, m is mass and M is molar mass.

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Chapter 4 Solutions
OWLv2 for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 1 term (6 months)
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- Curved arrows are used to illustrate the flow of electrons. Using the provided starting anand product sytucutrs, draw the curved electron-pusing arrows for the following reaction or mechanistic steps. Be sure to account for all bond-breaking and bind-making stepsarrow_forwardDraw the major elimination and substitution products formed in this reavtion. Use a dash or wedge bond to indicatr the stereochemistry of substituents on assymetric centers, wheere applicable. Ignore any inorganic byproducts.arrow_forwardDraw the two possible products produced in this E2 elimination. Ignore any inorganic byproductsarrow_forward
- Draw the major products of this SN1 reaction. Ignore any inorganic byproducts.arrow_forwardDraw the major elimination and substitution products formed in this reaction. Use a dash or wedge bond to indicate the stereochemistry of substituents on asymmetric centers, wehre applicable. Ignore and inorganic byproducts.arrow_forwardCurved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Drawing Arrows THE Problem 33 of 35 N. C:0 Na + Submit Drag To Pan +arrow_forward
- Draw the product of the E2 reaction shown below. Include the correct stereochemistry. Ignore and inorganic byproducts.arrow_forwardDraw the major producrs of this SN1 reaction. Ignore any inorganic byproducts. Use a dash or wedge bond to indicate the sereochemistry of substituents on asymmetric centers where appllicable.arrow_forward5) Oxaloacetic Acid is an important intermediate in the biosynthesis of citric acid. Synthesize oxaloacetic acid using a mixed Claisen Condensation reaction with two different esters and a sodium ethoxide base. Give your answer as a scheme Hint 1: Your final acid product is producing using a decarboxylation reaction. Hint 2: Look up the structure of oxalic acid. HO all OH oxaloacetic acidarrow_forward
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