1 Matter, Energy, And Measurement 2 Atoms 3 Chemical Bonds 4 Chemical Reactions And Energy Calculations 5 Gases, Liquids, And Solids 6 Solutions And Colloids 7 Reaction Rates And Chemical Equilibrium 8 Acids And Bases 9 Nuclear Chemistry 10 Organic Chemistry 11 Alkanes 12 Alkenes, Alkynes, And Aromatic Compounds 13 Alcohols, Ethers, And Thiols 14 Chirality: The Handedness Of Molecules 15 Amines 16 Aldehydes And Ketones 17 Carboxylic Acids 18 Carboxylic Anhydrides, Esters, And Amides 19 Carbohydrates 20 Lipids 21 Proteins 22 Enzymes 23 Chemical Communications: Neurotransmitters And Hormones 24 Nucleotides, Nucleic Acids, And Heredity 25 Gene Expression And Protein Synthesis 26 Bioenergetics: How The Body Converts Food To Energy 27 Specific Catabolic Pathways: Carbohydrate, Lipid, And Protein Metabolism 28 Biosynthetic Pathways 29 Nutrition 30 Immunochemistry expand_more
4.1 The Chemical Reaction 4.2 Balancing Chemical Equations 4.3 Predicting Whether Ions In Aqueous Solution Will React With Each Other 4.4 Oxidation And Reduction Reactions 4.5 Formula Weights And Moleculat Weights 4.6 The Mole And Calculation Mass Relationships 4.7 Calculating Mass Relationships In Chemical Reactions 4.8 Describing Heat And The Ways In Which It Is Transferred 4.9 Heat Of Reaction Chapter Questions expand_more
Problem 1P: 4-17 Balance each equation. Problem 2P: 4-18 Balance each equation. Problem 3P Problem 4P: 4-20 Calcium oxide is prepared by heating limestone (calcium carbonate, CaCO3) to a high... Problem 5P: 4-21 The brilliant white light in some firework displays is produced by burning magnesium in air.... Problem 6P Problem 7P: 4-23 When solid carbon burns in a limited supply of oxygen gas, the gas carbon monoxide, CO, forms.... Problem 8P Problem 9P: 4-25 In the chemical test for arsenic, the gas arsme, AsH3, is prepared. When arsine is decomposed... Problem 10P Problem 11P Problem 12P: 4-28 Answer true or false. (a) A net ionic equation shows only those ions that undergo chemical... Problem 13P: 4-29 Balance these net ionic equations. (a) Ag+(aq) + Br-(aqAgBr(s) (b) Cd2(aq) + S2-(aq) CdS(s) (c)... Problem 14P: 4-30 In the equation (a) Identify the spectator ions. (b) Write the balanced net ionic equation. Problem 15P: 4-31 Predict whether a precipitate will form when aqueous solutions of the following compounds are... Problem 16P: 4-32 When a solution of ammonium chloride is added to a solution of lead(I1) nitrate, Pb(NO3)2, a... Problem 17P: 4-33 When a solution of hydrochloric acid, HCl, is added to a solution of sodium sulfite, Na.2S03,... Problem 18P Problem 19P Problem 20P: 4-36 Using the solubility generalizations given in Section 4-3, predict which of these ionic... Problem 21P: 4-37 Answer true or false. (a) When a substance is oxidized, it loses electrons. (b) When a... Problem 22P Problem 23P Problem 24P Problem 25P Problem 26P: 4-42 Calculate the formula weight of: (a) KCl (b) Na3PO4 (c) Fe(OH)2 (d) NaAl(SO3)2 (e) AL2(SO4)3... Problem 27P: 4-43 Calculate the molecular weight of: (a) Sucrose, C12H22O11 (b) Glycine, C2H5NO2 (C) DDT,... Problem 28P: 4-44 Answer true or false. (a) The mole is a counting unit, just as a dozen is acounting unit. (b)... Problem 29P: 4-45 Calculate the number of moles in: (a) 32 g of methane, CH4 (b) 345.6 g of nitric oxide, NO (c)... Problem 30P: 4-46 Calculate the number of grams in: (a) 1.77 mol of nitrogen dioxide, NO2 (b) 0.84 mol of... Problem 31P: 4-47 Calculate the number of moles of: (a) O atoms in 18.1 mol of forma1dehyde, CH2O (b) Br atoms in... Problem 32P: 4-48 Calculate the number of moles of: (a) S2- ions in 6.56 mol of Na2S (b) Mg2+ ions in 8.320 mol... Problem 33P: 4-49 Calculate the number of: (a) nitrogen atoms in 25.0 g of TNT, C7H5N3O6 (b) carbon atoms in 40.0... Problem 34P: 4-50 How many molecules are in each of the following? (a) 2.9 mol of TNT, C7H5N3O6 (b) one drop... Problem 35P: 4-51 What is the mass in grams of each number of mol ecules of formaldehyde, CH2O? (a) 100.... Problem 36P: 4-52 The molecular weight of hemoglobin is about 68,000 amu. What is the mass in grams of a single... Problem 37P: 4-53 A typical deposit of cholesterol, C27H46O, in an artery might have a mass of 3.9 mg. How many... Problem 38P: 4-54 Answer true or false. (a) Stoichiometry is the study of mass relationships in chemical... Problem 39P: 4-55 For the reaction: (a) How many moles of N2 are required to react completely with 1 mole of O2?... Problem 40P: 4-56 Magnesium reacts with sulfuric acid according to the following equation. How many moles of lI2... Problem 41P: 4-57 Chloroform, CHCl3, is prepared industrially by the reaction of methane with chlorine. How many... Problem 42P: 4-58 At one time, acetaldehyde was prepared industrially by the reaction of ethylene with air in the... Problem 43P: 4-59 Chlorine dioxide, ClO2, is used for bleaching paper. It is also the gas used to kill the... Problem 44P: 4-60 Ethanol, C2H6O, is added to gasoline to produce “gasohol,” a fuel for automobile engines. How... Problem 45P: 4-61 In photosynthesis, green plants convert CO2 and H2O to glucose, C6H12O6. How many grams of... Problem 46P: 4-62 Iron ore is converted to iron by heating it with coal (carbon), and oxygen according to the... Problem 47P Problem 48P: 4-64 Aspirin is made by the reaction of salicylic acid with acetic anhydride. How many grams of... Problem 49P: 4-65 Suppose the preparation of aspirin from salicylic acid and acetic anhydride (Problem 4-64)... Problem 50P: 4-66 Benzene reacts with bromine to produce bromoben zene according to the following equation: If... Problem 51P: 4-67 Ethyl chloride is prepared by the reaction of chlorine with ethane according to the following... Problem 52P: 4-68 Diethyl ether is made from ethanol according to the following reaction: In an experiment, 517 g... Problem 53P Problem 54P: How many calories are required to heat the following (specific heats are given in Table 4.2)? (a)... Problem 55P Problem 56P Problem 57P Problem 58P Problem 59P: 4-71 Which of these reactions are exothermic, and which are endothermic? Problem 60P Problem 61P Problem 62P Problem 63P Problem 64P Problem 65P: 4-77 To convert 1 mol of iron(III) oxide to its elements requires 196.5 kcal: How many grams of iron... Problem 66P: 4-78 (Chemical Connections 4A) How does fluoride ion protect the tooth enamel against decay? Problem 67P Problem 68P Problem 69P: 4-81 (Chemical Connections 4C) Balance the lithium iodine battery redox reaction described in this... Problem 70P: 4-82 When gaseous dinitrogen pentoxide, N2O5, is bubbled into water, nitric acid, HNO3, forms. Write... Problem 71P Problem 72P Problem 73P Problem 74P: 4-86 When an aqueous solution of Na3PO4 is added to an aqueous solution of Cd(NO3)2 a precipitate... Problem 75P Problem 76P: 4-88 Chlorophyll, the compound responsible for the green color of leaves and grasses, contains one... Problem 77P: 4-89 If 7.0 kg of is added to 11.0 kg of to form which reactant is in excess? Problem 78P: 4-90 Lead(lI) nitrate and aluminum chloride react according to the following equation: In an... Problem 79P: 4-91 Assume that the average red blood cell has a mass of 2 × 10-8 g and that 20% of its mass is... Problem 80P: 4-92 Reaction of pentane, C5H12, with oxygen, O2, gives carbon dioxide and water. (a) Write a... Problem 81P: 4-93 Ammonia is prepared industrially by the reaction of nitrogen and hydrogen according to the... Problem 82P: 4-94 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is a potent poison with the chemical formula... Problem 83P Problem 84P Problem 85P Problem 86P Problem 87P Problem 88P Problem 89P Problem 90P Problem 91P Problem 92P: 4-102 Aspartame, an artificial sweetener used as a sugar substitute in some foods and beverages, has... Problem 93P: 4-103 Caffeine, a central nervous system stimulant, has the molecular formula C8H10N402. (a) How... 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