Atkins' Physical Chemistry
11th Edition
ISBN: 9780198769866
Author: ATKINS, P. W. (peter William), De Paula, Julio, Keeler, JAMES
Publisher: Oxford University Press
expand_more
expand_more
format_list_bulleted
Question
Chapter 4, Problem 4B.5BE
Interpretation Introduction
Interpretation: The entropy and enthalpy of fusion of the solid has to be calculated.
Concept introduction: The entropy of fusion of the solid is calculated by the Clapeyron’s equation for the process that involves the phase transition process. The Clapeyron’s equation expresses the tangent of the phase boundary that applies to any phase equilibrium.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
O
HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
OA
B
OC
ch
B
C
Save For Later
Submit Ass
© 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center |
How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 4 Solutions
Atkins' Physical Chemistry
Ch. 4 - Prob. 4B.1STCh. 4 - Prob. 4B.2STCh. 4 - Prob. 4A.1DQCh. 4 - Prob. 4A.2DQCh. 4 - Prob. 4A.3DQCh. 4 - Prob. 4A.1AECh. 4 - Prob. 4A.1BECh. 4 - Prob. 4A.2AECh. 4 - Prob. 4A.2BECh. 4 - Prob. 4A.3AE
Ch. 4 - Prob. 4A.3BECh. 4 - Prob. 4A.4AECh. 4 - Prob. 4A.4BECh. 4 - Prob. 4A.5AECh. 4 - Prob. 4A.5BECh. 4 - Prob. 4A.1PCh. 4 - Prob. 4A.2PCh. 4 - Prob. 4A.3PCh. 4 - Prob. 4A.4PCh. 4 - Prob. 4B.1DQCh. 4 - Prob. 4B.2DQCh. 4 - Prob. 4B.3DQCh. 4 - Prob. 4B.1AECh. 4 - Prob. 4B.1BECh. 4 - Prob. 4B.2AECh. 4 - Prob. 4B.2BECh. 4 - Prob. 4B.3AECh. 4 - Prob. 4B.3BECh. 4 - Prob. 4B.4AECh. 4 - Prob. 4B.4BECh. 4 - Prob. 4B.5AECh. 4 - Prob. 4B.5BECh. 4 - Prob. 4B.6AECh. 4 - Prob. 4B.6BECh. 4 - Prob. 4B.7AECh. 4 - Prob. 4B.7BECh. 4 - Prob. 4B.8AECh. 4 - Prob. 4B.8BECh. 4 - Prob. 4B.9AECh. 4 - Prob. 4B.9BECh. 4 - Prob. 4B.10AECh. 4 - Prob. 4B.10BECh. 4 - Prob. 4B.11AECh. 4 - Prob. 4B.11BECh. 4 - Prob. 4B.12AECh. 4 - Prob. 4B.12BECh. 4 - Prob. 4B.13AECh. 4 - Prob. 4B.13BECh. 4 - Prob. 4B.14AECh. 4 - Prob. 4B.14BECh. 4 - Prob. 4B.1PCh. 4 - Prob. 4B.2PCh. 4 - Prob. 4B.3PCh. 4 - Prob. 4B.4PCh. 4 - Prob. 4B.5PCh. 4 - Prob. 4B.6PCh. 4 - Prob. 4B.7PCh. 4 - Prob. 4B.8PCh. 4 - Prob. 4B.9PCh. 4 - Prob. 4B.10PCh. 4 - Prob. 4B.11PCh. 4 - Prob. 4B.12PCh. 4 - Prob. 4B.13PCh. 4 - Prob. 4B.14PCh. 4 - Prob. 4B.15PCh. 4 - Prob. 4B.16PCh. 4 - Prob. 4.1IACh. 4 - Prob. 4.3IACh. 4 - Prob. 4.4IA
Knowledge Booster
Similar questions
- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
- true or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forwardthe decomposition of N2O5 is the first order with a half-life of 1.98 minutes. If the inital concentration of N2O5 is 0.200 M, what is the concentration after 6 minutes?a) 0.612 Mb) 0.035 Mc) 0.024 Md) 0.100 Marrow_forward
- 20.00 mL of 0.150 M HCI is titrated with 0.075 M NaOH. What volume of NaOH is needed?a) 50 mLb) 20 mLc) 40 mLd) 26.66 mLarrow_forward20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCI. What is the molarity of the HCI?a) 0.150 Mb) 0.079 Mc) 0.025 Md) 0.050 Marrow_forwardin the following reaction, the OH- acts as which of these?NO2- (aq) + H2O (l) ⇌ OH- (aq) + HNO2 (aq)a) not a weak acidb) basec) acidarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY