Atkins' Physical Chemistry
Atkins' Physical Chemistry
11th Edition
ISBN: 9780198769866
Author: ATKINS, P. W. (peter William), De Paula, Julio, Keeler, JAMES
Publisher: Oxford University Press
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Chapter 4, Problem 4B.1P
Interpretation Introduction

Interpretation:

Work done by the water vapour and fraction of enthalpy of vaporization spent on expanding the vapour has to be predicted.

Concept Introduction:

Energy needed to transform the liquid state of a substance to its gaseous state is known as the enthalpy of vaporization of the system.  The formula for enthalpy of vaporization is shown below.

    ΔHvaporization=ΔUvaporization+pΔV

Where,

  • ΔHvaporization is the enthalpy of vaporization.
  • ΔUvaporization is the increase in the internal energy.
  • pΔV is thework done against pressure.

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3. a. Use the periodic table to add up the molecular weight of thionyl chloride (SOCl2) and show your work. b. The actual value obtained for the molecular ion on a high resolution mass spectrometer is 117.9041. Explain the discrepancy. c. Show the calculations that correctly result in the exact mass of 117.9041 for SOC₁₂. Use Table 11.2 or Appendix E in your calculations.
6. Draw the molecular orbital diagram shown to determine which of the following is paramagnetic. B₂2+ B22+, B2, C22, B22- and N22+ Molecular Orbital Diagram B2 C22- B22- N22+ Which molecule is paramagnetic?
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