Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
7th Edition
ISBN: 9780133900811
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 4, Problem 4.8P
Interpretation Introduction
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8. Draw all the resonance forms for each of the fling molecules or ions, and indicate the major
contributor in each case, or if they are equivalent (45)
(2)
-PH2
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J
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Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
Chapter 4 Solutions
Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2ACh. 4 - Prob. 4.3PCh. 4 - Prob. 4.4PCh. 4 - Prob. 4.5ACh. 4 - Prob. 4.6PCh. 4 - APPLY 4.7 Sulfuric acid is normally purchased at a...Ch. 4 - Prob. 4.8PCh. 4 - Conceptual APPLY 4.9 Three different substances,...Ch. 4 - Prob. 4.10P
Ch. 4 - Prob. 4.11ACh. 4 - Prob. 4.12PCh. 4 - APPLY 4.13 How might you use a precipitation...Ch. 4 - Conceptual PRACTICE 4.14 An aqueous solution...Ch. 4 - Conceptual APPLY 4.15 A solution containing the...Ch. 4 - Prob. 4.16PCh. 4 - APPLY 4.17 Give likely chemical formulas...Ch. 4 - PRACTICE 4.18 Write a balanced ionic equation and...Ch. 4 - Prob. 4.19ACh. 4 - Prob. 4.20PCh. 4 - Prob. 4.21ACh. 4 - Prob. 4.22PCh. 4 - Prob. 4.23ACh. 4 - PRACTICE 4.24 Assign an oxidation number to each...Ch. 4 - APPLY 4.25 Chlorine can have several different...Ch. 4 - Prob. 4.26PCh. 4 - APPLY 4.27 Police often use a Breathalyzer test to...Ch. 4 - PRACTICE 4.28 Predict whether the following...Ch. 4 - Prob. 4.29ACh. 4 - Prob. 4.30PCh. 4 - Prob. 4.31ACh. 4 - Prob. 4.32PCh. 4 - Prob. 4.33PCh. 4 - Prob. 4.34PCh. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38CPCh. 4 - Prob. 4.39CPCh. 4 - Prob. 4.40CPCh. 4 - Assume that an aqueous solution Of a cation,...Ch. 4 - The following pictures represent aqueous solutions...Ch. 4 - Prob. 4.43CPCh. 4 - The concentration of an aqueous solution of NaOCl...Ch. 4 - Assume that the electrical conductivity of a...Ch. 4 - Based on the positions in the periodic table,...Ch. 4 - The following two redox reactions occur between...Ch. 4 - Prob. 4.48SPCh. 4 - How many grams of solute would you use to prepare...Ch. 4 - How many milliliters of a 0.45 M BaCl2 solution...Ch. 4 - How many milliliters of a 0.350 M KOH solution...Ch. 4 - The sterile saline solution used to rinse contact...Ch. 4 - Prob. 4.53SPCh. 4 - Copper reacts with dilute nitric acid according to...Ch. 4 - Prob. 4.55SPCh. 4 - Prob. 4.56SPCh. 4 - Prob. 4.57SPCh. 4 - Prob. 4.58SPCh. 4 - Prob. 4.59SPCh. 4 - Prob. 4.60SPCh. 4 - Prob. 4.61SPCh. 4 - Prob. 4.62SPCh. 4 - Prob. 4.63SPCh. 4 - Prob. 4.64SPCh. 4 - Is it possible for a molecular substance to be a...Ch. 4 - Prob. 4.66SPCh. 4 - Prob. 4.67SPCh. 4 - Prob. 4.68SPCh. 4 - Prob. 4.69SPCh. 4 - Prob. 4.70SPCh. 4 - Prob. 4.71SPCh. 4 - Prob. 4.72SPCh. 4 - Prob. 4.73SPCh. 4 - Prob. 4.74SPCh. 4 - Prob. 4.75SPCh. 4 - Prob. 4.76SPCh. 4 - Prob. 4.77SPCh. 4 - Prob. 4.78SPCh. 4 - Prob. 4.79SPCh. 4 - Prob. 4.80SPCh. 4 - Prob. 4.81SPCh. 4 - Prob. 4.82SPCh. 4 - Prob. 4.83SPCh. 4 - Prob. 4.84SPCh. 4 - Prob. 4.85SPCh. 4 - Assume that you are given a solution of an unknown...Ch. 4 - Prob. 4.87SPCh. 4 - Prob. 4.88SPCh. 4 - Prob. 4.89SPCh. 4 - Prob. 4.90SPCh. 4 - Prob. 4.91SPCh. 4 - Prob. 4.92SPCh. 4 - Prob. 4.93SPCh. 4 - Prob. 4.94SPCh. 4 - Prob. 4.95SPCh. 4 - Prob. 4.96SPCh. 4 - Prob. 4.97SPCh. 4 - Prob. 4.98SPCh. 4 - Prob. 4.99SPCh. 4 - Prob. 4.100SPCh. 4 - Where in the periodic table are the most easily...Ch. 4 - In each of the following instances, tell whether...Ch. 4 - Tell for each of the following substances whether...Ch. 4 - Prob. 4.104SPCh. 4 - Prob. 4.105SPCh. 4 - Prob. 4.106SPCh. 4 - Prob. 4.107SPCh. 4 - Nitrogen can have several different oxidation...Ch. 4 - Phosphorus can have several different oxidation...Ch. 4 - Which element is oxidized and which is reduced in...Ch. 4 - 4.111 Which element is oxidized and which is...Ch. 4 - Use the activity series of metals (Table 4.5) to...Ch. 4 - Prob. 4.113SPCh. 4 - Prob. 4.114SPCh. 4 - Prob. 4.115SPCh. 4 - Iodine, I2, reacts with aqueous thiosulfate ion in...Ch. 4 - Iodine, I2, reacts with aqueous thiosulfate ion in...Ch. 4 - Dichromate ion, Cr2O72 , reacts with aqueous...Ch. 4 - Prob. 4.119SPCh. 4 - Prob. 4.120SPCh. 4 - Standardized solutions Of KBrO3are frequently used...Ch. 4 - Prob. 4.122SPCh. 4 - Prob. 4.123SPCh. 4 - Prob. 4.124SPCh. 4 - Calcium levels in blood can be determined by...Ch. 4 - Prob. 4.126CPCh. 4 - Prob. 4.127CPCh. 4 - Prob. 4.128CPCh. 4 - Prob. 4.129CPCh. 4 - Prob. 4.130CPCh. 4 - Prob. 4.131CPCh. 4 - Prob. 4.132CPCh. 4 - Prob. 4.133CPCh. 4 - Prob. 4.134CPCh. 4 - Prob. 4.135CPCh. 4 - Prob. 4.136CPCh. 4 - Prob. 4.137CPCh. 4 - Prob. 4.138CPCh. 4 - Prob. 4.139CPCh. 4 - Prob. 4.140CPCh. 4 - Prob. 4.141CPCh. 4 - Prob. 4.142CPCh. 4 - Prob. 4.143CPCh. 4 - Prob. 4.144CPCh. 4 - Prob. 4.145CPCh. 4 - Prob. 4.146CPCh. 4 - Prob. 4.147CPCh. 4 - Prob. 4.148CPCh. 4 - Prob. 4.149CPCh. 4 - Prob. 4.150CPCh. 4 - Prob. 4.150MPCh. 4 - Prob. 4.151CPCh. 4 - Prob. 4.151MPCh. 4 - Prob. 4.152CPCh. 4 - Prob. 4.152MPCh. 4 - Prob. 4.153CPCh. 4 - Prob. 4.153MPCh. 4 - Prob. 4.154CPCh. 4 - Prob. 4.154MPCh. 4 - Prob. 4.155CPCh. 4 - Prob. 4.155MPCh. 4 - Prob. 4.156CPCh. 4 - Prob. 4.156MPCh. 4 - Prob. 4.157CPCh. 4 - Prob. 4.157MPCh. 4 - Prob. 4.158CPCh. 4 - Prob. 4.158MPCh. 4 - Prob. 4.159CPCh. 4 - Prob. 4.159MPCh. 4 - Prob. 4.160CPCh. 4 - Prob. 4.160MPCh. 4 - Prob. 4.161MPCh. 4 - Prob. 4.162MP
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