PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
2nd Edition
ISBN: 9781266811852
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 4, Problem 4.80AP
Why does steam form when hot lava falls into the ocean?
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There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS).
Ca, ppm
V, ppm
SCa, arb. units
SV, arb. units
20.0
10.0
14375.11
14261.02
40.0
10.0
36182.15
17997.10
60.0
10.0
39275.74
12988.01
80.0
10.0
57530.75
14268.54
100.0…
A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C.
H₂O(g) + C₁₂O(g) = 2 HOCl(g)
K = 0.0900 at 25°C
с
Calculate the equilibrium concentrations of each gas at 25 °C.
[H₂O]=
[C₁₂O]=
[HOCI]=
M
Σ
M
What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?
Chapter 4 Solutions
PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
Ch. 4.1 - Prob. 4.1PCh. 4.1 - Prob. 4.2PCh. 4.1 - Prob. 4.3PCh. 4.1 - Prob. 4.4PCh. 4.2 - Prob. 4.5PCh. 4.2 - Prob. 4.6PCh. 4.3 - Prob. 4.7PCh. 4.3 - Prob. 4.8PCh. 4.3 - Prob. 4.9PCh. 4.3 - Prob. 4.10P
Ch. 4.3 - Which of the compounds in each pair has stronger...Ch. 4.4 - Prob. 4.12PCh. 4.4 - Prob. 4.13PCh. 4.5 - A student has two containers one with 10 g of...Ch. 4.5 - Prob. 4.15PCh. 4.5 - How much energy is required to heat 28.0 g of iron...Ch. 4.5 - Prob. 4.17PCh. 4.5 - Prob. 4.18PCh. 4.5 - Prob. 4.19PCh. 4.6 - Prob. 4.20PCh. 4.6 - Prob. 4.21PCh. 4.6 - Label each process as endothermic or exothermic...Ch. 4.6 - Prob. 4.23PCh. 4.7 - Answer the following questions about the graph. a....Ch. 4.7 - Prob. 4.25PCh. 4.7 - If the cooling curve in Figure 4.5 represented a...Ch. 4.7 - How much energy (in calories) is released when...Ch. 4.7 - Prob. 4.28PCh. 4 - What phase change is shown in the accompanying...Ch. 4 - What phase change is shown in the accompanying...Ch. 4 - Consider the cooling curve drawn below. a. Which...Ch. 4 - Which line segments on the cooling curve in...Ch. 4 - Prob. 4.33UKCCh. 4 - Prob. 4.34UKCCh. 4 - Prob. 4.35UKCCh. 4 - Prob. 4.36UKCCh. 4 - Prob. 4.37UKCCh. 4 - Prob. 4.38UKCCh. 4 - Prob. 4.39APCh. 4 - Prob. 4.40APCh. 4 - Prob. 4.41APCh. 4 - Prob. 4.49APCh. 4 - Prob. 4.50APCh. 4 - Prob. 4.54APCh. 4 - Prob. 4.55APCh. 4 - Prob. 4.56APCh. 4 - Prob. 4.57APCh. 4 - Prob. 4.58APCh. 4 - Prob. 4.59APCh. 4 - Prob. 4.60APCh. 4 - Prob. 4.61APCh. 4 - Prob. 4.62APCh. 4 - Prob. 4.63APCh. 4 - Prob. 4.64APCh. 4 - Prob. 4.65APCh. 4 - Prob. 4.66APCh. 4 - Prob. 4.67APCh. 4 - Prob. 4.68APCh. 4 - Prob. 4.69APCh. 4 - Prob. 4.70APCh. 4 - Prob. 4.71APCh. 4 - Prob. 4.72APCh. 4 - Prob. 4.73APCh. 4 - Prob. 4.74APCh. 4 - Prob. 4.75APCh. 4 - Prob. 4.76APCh. 4 - Prob. 4.77APCh. 4 - Prob. 4.78APCh. 4 - Prob. 4.79APCh. 4 - Why does steam form when hot lava falls into the...Ch. 4 - Prob. 4.81APCh. 4 - Prob. 4.82AP
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