
Chemistry (7th Edition)
7th Edition
ISBN: 9780321943170
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Textbook Question
Chapter 4, Problem 4.65SP
Is it possible for a molecular substance to be a strong electrolyte? Explain.
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Using a cell of known pathlength b = 1.25115 x 10-3 cm, a water absorption spectrum was measured. The band at 1645 cm-1, assigned to the O-H bending, showed an absorbance, A, of 1.40.
a) Assuming that water density is 1.00 g/mL, calculate the water molar concentration c (hint: M= mole/L)
b) Calculate the molar absorptivity, a, of the 1645 cm-1 band
c) The transmitted light, I, can be written as I= Ioexp(-xb), where x is the absorption coefficient (sometimes designated as alpha), Io is the input light, and b is the cell pathlength. Prove that x= (ln10)*x*c. (Please provide a full derivation of the equation for x from the equation for I).
d) Calculate x for the 1645 cm-1 band
I need help with the follloaing
For a CARS experiment on a Raman band 918 cm-1, if omega1= 1280 nm, calculate the omega2 in wavelength (nm) and the CARS output in wavelength (nm).
Chapter 4 Solutions
Chemistry (7th Edition)
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2ACh. 4 - Prob. 4.3PCh. 4 - Prob. 4.4PCh. 4 - Prob. 4.5ACh. 4 - Prob. 4.6PCh. 4 - APPLY 4.7 Sulfuric acid is normally purchased at a...Ch. 4 - Prob. 4.8PCh. 4 - Conceptual APPLY 4.9 Three different substances,...Ch. 4 - Prob. 4.10P
Ch. 4 - Prob. 4.11ACh. 4 - Prob. 4.12PCh. 4 - APPLY 4.13 How might you use a precipitation...Ch. 4 - Conceptual PRACTICE 4.14 An aqueous solution...Ch. 4 - Conceptual APPLY 4.15 A solution containing the...Ch. 4 - Prob. 4.16PCh. 4 - APPLY 4.17 Give likely chemical formulas...Ch. 4 - PRACTICE 4.18 Write a balanced ionic equation and...Ch. 4 - Prob. 4.19ACh. 4 - Prob. 4.20PCh. 4 - Prob. 4.21ACh. 4 - Prob. 4.22PCh. 4 - Prob. 4.23ACh. 4 - PRACTICE 4.24 Assign an oxidation number to each...Ch. 4 - APPLY 4.25 Chlorine can have several different...Ch. 4 - Prob. 4.26PCh. 4 - APPLY 4.27 Police often use a Breathalyzer test to...Ch. 4 - PRACTICE 4.28 Predict whether the following...Ch. 4 - Prob. 4.29ACh. 4 - Prob. 4.30PCh. 4 - Prob. 4.31ACh. 4 - Prob. 4.32PCh. 4 - Prob. 4.33PCh. 4 - Prob. 4.34PCh. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38CPCh. 4 - Prob. 4.39CPCh. 4 - Prob. 4.40CPCh. 4 - Assume that an aqueous solution Of a cation,...Ch. 4 - The following pictures represent aqueous solutions...Ch. 4 - Prob. 4.43CPCh. 4 - The concentration of an aqueous solution of NaOCl...Ch. 4 - Assume that the electrical conductivity of a...Ch. 4 - Based on the positions in the periodic table,...Ch. 4 - The following two redox reactions occur between...Ch. 4 - Prob. 4.48SPCh. 4 - How many grams of solute would you use to prepare...Ch. 4 - How many milliliters of a 0.45 M BaCl2 solution...Ch. 4 - How many milliliters of a 0.350 M KOH solution...Ch. 4 - The sterile saline solution used to rinse contact...Ch. 4 - Prob. 4.53SPCh. 4 - Copper reacts with dilute nitric acid according to...Ch. 4 - Prob. 4.55SPCh. 4 - Prob. 4.56SPCh. 4 - Prob. 4.57SPCh. 4 - Prob. 4.58SPCh. 4 - Prob. 4.59SPCh. 4 - Prob. 4.60SPCh. 4 - Prob. 4.61SPCh. 4 - Prob. 4.62SPCh. 4 - Prob. 4.63SPCh. 4 - Prob. 4.64SPCh. 4 - Is it possible for a molecular substance to be a...Ch. 4 - Prob. 4.66SPCh. 4 - Prob. 4.67SPCh. 4 - Prob. 4.68SPCh. 4 - Prob. 4.69SPCh. 4 - Prob. 4.70SPCh. 4 - Prob. 4.71SPCh. 4 - Prob. 4.72SPCh. 4 - Prob. 4.73SPCh. 4 - Prob. 4.74SPCh. 4 - Prob. 4.75SPCh. 4 - Prob. 4.76SPCh. 4 - Prob. 4.77SPCh. 4 - Prob. 4.78SPCh. 4 - Prob. 4.79SPCh. 4 - Prob. 4.80SPCh. 4 - Prob. 4.81SPCh. 4 - Prob. 4.82SPCh. 4 - Prob. 4.83SPCh. 4 - Prob. 4.84SPCh. 4 - Prob. 4.85SPCh. 4 - Assume that you are given a solution of an unknown...Ch. 4 - Prob. 4.87SPCh. 4 - Prob. 4.88SPCh. 4 - Prob. 4.89SPCh. 4 - Prob. 4.90SPCh. 4 - Prob. 4.91SPCh. 4 - Prob. 4.92SPCh. 4 - Prob. 4.93SPCh. 4 - Prob. 4.94SPCh. 4 - Prob. 4.95SPCh. 4 - Prob. 4.96SPCh. 4 - Prob. 4.97SPCh. 4 - Prob. 4.98SPCh. 4 - Prob. 4.99SPCh. 4 - Prob. 4.100SPCh. 4 - Where in the periodic table are the most easily...Ch. 4 - In each of the following instances, tell whether...Ch. 4 - Tell for each of the following substances whether...Ch. 4 - Prob. 4.104SPCh. 4 - Prob. 4.105SPCh. 4 - Prob. 4.106SPCh. 4 - Prob. 4.107SPCh. 4 - Nitrogen can have several different oxidation...Ch. 4 - Phosphorus can have several different oxidation...Ch. 4 - Which element is oxidized and which is reduced in...Ch. 4 - 4.111 Which element is oxidized and which is...Ch. 4 - Use the activity series of metals (Table 4.5) to...Ch. 4 - Prob. 4.113SPCh. 4 - Prob. 4.114SPCh. 4 - Prob. 4.115SPCh. 4 - Iodine, I2, reacts with aqueous thiosulfate ion in...Ch. 4 - Iodine, I2, reacts with aqueous thiosulfate ion in...Ch. 4 - Dichromate ion, Cr2O72 , reacts with aqueous...Ch. 4 - Prob. 4.119SPCh. 4 - Prob. 4.120SPCh. 4 - Standardized solutions Of KBrO3are frequently used...Ch. 4 - Prob. 4.122SPCh. 4 - Prob. 4.123SPCh. 4 - Prob. 4.124SPCh. 4 - Calcium levels in blood can be determined by...Ch. 4 - Prob. 4.126CPCh. 4 - Prob. 4.127CPCh. 4 - Prob. 4.128CPCh. 4 - Prob. 4.129CPCh. 4 - Prob. 4.130CPCh. 4 - Prob. 4.131CPCh. 4 - Prob. 4.132CPCh. 4 - Prob. 4.133CPCh. 4 - Prob. 4.134CPCh. 4 - Prob. 4.135CPCh. 4 - Prob. 4.136CPCh. 4 - Prob. 4.137CPCh. 4 - Prob. 4.138CPCh. 4 - Prob. 4.139CPCh. 4 - Prob. 4.140CPCh. 4 - Prob. 4.141CPCh. 4 - Prob. 4.142CPCh. 4 - Prob. 4.143CPCh. 4 - Prob. 4.144CPCh. 4 - Prob. 4.145CPCh. 4 - Prob. 4.146CPCh. 4 - Prob. 4.147CPCh. 4 - Prob. 4.148CPCh. 4 - Prob. 4.149CPCh. 4 - Prob. 4.150CPCh. 4 - Prob. 4.150MPCh. 4 - Prob. 4.151CPCh. 4 - Prob. 4.151MPCh. 4 - Prob. 4.152CPCh. 4 - Prob. 4.152MPCh. 4 - Prob. 4.153CPCh. 4 - Prob. 4.153MPCh. 4 - Prob. 4.154CPCh. 4 - Prob. 4.154MPCh. 4 - Prob. 4.155CPCh. 4 - Prob. 4.155MPCh. 4 - Prob. 4.156CPCh. 4 - Prob. 4.156MPCh. 4 - Prob. 4.157CPCh. 4 - Prob. 4.157MPCh. 4 - Prob. 4.158CPCh. 4 - Prob. 4.158MPCh. 4 - Prob. 4.159CPCh. 4 - Prob. 4.159MPCh. 4 - Prob. 4.160CPCh. 4 - Prob. 4.160MPCh. 4 - Prob. 4.161MPCh. 4 - Prob. 4.162MP
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- Using a cell of known pathlength b = 1.25115 x 10-3 cm, a water absorption spectrum was measured. The band at 1645 cm-1, assigned to the O-H bending, showed an absorbance, A, of 1.40. a) Assuming that water density is 1.00 g/mL, calculate the water molar concentration c (hint: M= mole/L) b) Calculate the molar absorptivity, a, of the 1645 cm-1 band c) The transmitted light, I, can be written as I= Ioexp(-xb), where x is the absorption coefficient (sometimes designated as alpha), Io is the input light, and b is the cell pathlength. Prove that x= (ln10)*x*c d) Calculate x for the 1645 cm-1 bandarrow_forwardConvert 1.38 eV into wavelength (nm) and wavenumber (cm-1) (c = 2.998 x 108 m/s; h = 6.626 x 10-34 J*s).arrow_forwardCan you help me understand the CBC method on metal bridging by looking at this problem?arrow_forward
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