The factor responsible for the completion of the following acid-base reaction is to be determined. MgSO 3 ( s ) + 2 HCl ( a q ) → MgCl 2 ( a q ) + SO 2 ( g ) + H 2 O ( l ) Concept Introduction: Strong acids and strong bases are the substance that dissociates completely into its ions when dissolved in the solution. They dissociate completely in water to release H + ions and OH − ions. Weak acids and weak bases are the substance that does not dissociate completely into its ions when dissolved in the solution. They dissociate partially in water to release H + ions and OH − ions. The driving force of the acid-base reaction is the formation of a gaseous product or precipitate in the reaction. The formation of a water molecule also acts as a factor to drive the reaction to completion.
The factor responsible for the completion of the following acid-base reaction is to be determined. MgSO 3 ( s ) + 2 HCl ( a q ) → MgCl 2 ( a q ) + SO 2 ( g ) + H 2 O ( l ) Concept Introduction: Strong acids and strong bases are the substance that dissociates completely into its ions when dissolved in the solution. They dissociate completely in water to release H + ions and OH − ions. Weak acids and weak bases are the substance that does not dissociate completely into its ions when dissolved in the solution. They dissociate partially in water to release H + ions and OH − ions. The driving force of the acid-base reaction is the formation of a gaseous product or precipitate in the reaction. The formation of a water molecule also acts as a factor to drive the reaction to completion.
The factor responsible for the completion of the following acid-base reaction is to be determined.
MgSO3(s)+2HCl(aq)→MgCl2(aq)+SO2(g)+H2O(l)
Concept Introduction:
Strong acids and strong bases are the substance that dissociates completely into its ions when dissolved in the solution. They dissociate completely in water to release H+ ions and OH− ions.
Weak acids and weak bases are the substance that does not dissociate completely into its ions when dissolved in the solution. They dissociate partially in water to release H+ ions and OH− ions.
The driving force of the acid-base reaction is the formation of a gaseous product or precipitate in the reaction. The formation of a water molecule also acts as a factor to drive the reaction to completion.
(b)
Interpretation Introduction
Interpretation:
The factor responsible for the completion of the following acid-base reaction is to be determined.
3Ba(OH)2(s)+2H3PO4(aq)→Ba3(PO4)2(aq)+6H2O(l)
Concept Introduction:
Strong acids and strong bases are the substance that dissociates completely into its ions when dissolved in the solution. They dissociate completely in water to release H+ ions and OH− ions.
Weak acids and weak bases are the substance that does not dissociate completely into its ions when dissolved in the solution. They dissociate partially in water to release H+ ions and OH− ions.
The driving force of the acid-base reaction is the formation of a gaseous product or precipitate in the reaction. The formation of a water molecule also acts as a factor to drive the reaction to completion.
21.38 Arrange the molecules in each set in order of increasing acidity (from least acidic to
most acidic).
OH
OH
SH
NH2
8
NH3
OH
(b)
OH
OH
OH
(c)
& & &
CH3
NO2
21.39 Explain the trends in the acidity of phenol and the monofluoro derivatives of phenol.
OH
OH
OH
OH
PK 10.0
PK 8.81
PK 9.28
PK 9.81
identify which spectrum is for acetaminophen and which is for phenacetin
The Concept of Aromaticity
21.15 State the number of 2p orbital electrons in each molecule or ion.
(a)
(b)
(e)
(f)
(c)
(d)
(h)
(i)
DA
(k)
21.16 Which of the molecules and ions given in Problem 21.15 are aromatic according to the
Hückel criteria? Which, if planar, would be antiaromatic?
21.17 Which of the following structures are considered aromatic according to the Hückel
criteria?
---0-0
(a)
(b)
(c)
(d)
(e)
(h)
H
-H
.8.0-
21.18 Which of the molecules and ions from Problem 21.17 have electrons donated by a
heteroatom?