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EBK CHEMISTRY
8th Edition
ISBN: 9780135216972
Author: Robinson
Publisher: PEARSON CO
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Question
Chapter 4, Problem 4.53SP
Interpretation Introduction
(a)
Interpretation:
The given concentration of gold in g/mL needs to be converted into mol/L
Concept introduction:
The number of moles can be calculated from mass and molar mass as follows:
Here, m is mass and M is molar mass.
Interpretation Introduction
(b)
Interpretation:
The mass of gold dissolved in the ocean needs to be calculated if the volume of ocean is
Concept introduction:
The molarity or concentration of the solution can be calculated as follows:
Here, n is number of moles and V is volume of solution in L.
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Students have asked these similar questions
You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 4 Solutions
EBK CHEMISTRY
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2ACh. 4 - How many moles of solute are present in 125 mLof...Ch. 4 - Prob. 4.4ACh. 4 - Prob. 4.5PCh. 4 - APPLY 4.7 Sulfuric acid is normally purchased at a...Ch. 4 - Prob. 4.7PCh. 4 - Conceptual APPLY 4.9 Three different substances,...Ch. 4 - Write ne ionic equations for the following...Ch. 4 - Prob. 4.10A
Ch. 4 - Will a precipitation reaction occur when aqueous...Ch. 4 - APPLY 4.13 How might you use a precipitation...Ch. 4 - Conceptual PRACTICE 4.14 An aqueous solution...Ch. 4 - Conceptual APPLY 4.15 A solution containing the...Ch. 4 - Name the acids HI and HBrO2 .Ch. 4 - APPLY 4.17 Give likely chemical formulas...Ch. 4 - PRACTICE 4.18 Write a balanced ionic equation and...Ch. 4 - Milk of magnesia (active ingredient: magnesium...Ch. 4 - Prob. 4.19PCh. 4 - Prob. 4.20ACh. 4 - Prob. 4.21PCh. 4 - Assume that the buret contains H+ ions, the flask...Ch. 4 - PRACTICE 4.24 Assign an oxidation number to each...Ch. 4 - APPLY 4.25 Chlorine can have several different...Ch. 4 - Identify the oxidizing agent and reducing agent in...Ch. 4 - APPLY 4.27 Police often use a Breathalyzer test to...Ch. 4 - PRACTICE 4.28 Predict whether the following...Ch. 4 - Use the following reactions to arrange the...Ch. 4 - Prob. 4.29PCh. 4 - Prob. 4.30ACh. 4 - A viramin-fortified brand of a sports...Ch. 4 - The nutritional label on Power ade specifies that...Ch. 4 - Prob. 4.33PCh. 4 - One way to analyze a sports drink for the...Ch. 4 - To measure the concentration of chloride ions ina...Ch. 4 - The flavor of the first batch of Gatorade was...Ch. 4 - Prob. 4.37CPCh. 4 - Prob. 4.38CPCh. 4 - Assume that an aqueous solution Of a cation,...Ch. 4 - The following pictures represent aqueous solutions...Ch. 4 - Prob. 4.41CPCh. 4 - The concentration of an aqueous solution of NaOCl...Ch. 4 - Assume that the electrical conductivity of a...Ch. 4 - Based on the positions in the periodic table,...Ch. 4 - The following two redox reactions occur between...Ch. 4 - Prob. 4.46SPCh. 4 - How many grams of solute would you use to prepare...Ch. 4 - How many milliliters of a 0.45 M BaCl2 solution...Ch. 4 - How many milliliters of a 0.350 M KOH solution...Ch. 4 - The sterile saline solution used to rinse contact...Ch. 4 - Prob. 4.51SPCh. 4 - Copper reacts with dilute nitric acid according to...Ch. 4 - Prob. 4.53SPCh. 4 - How many grams of solute would you use to prepare...Ch. 4 - Prob. 4.55SPCh. 4 - How would you prepare 250 mL of a 0.100 M solution...Ch. 4 - Pennies minted after 1982 are mostly zinc (97.5%)...Ch. 4 - A bottle of 12.0 M hydrochloric acid has only 35.7...Ch. 4 - What is the volume of the solution that would...Ch. 4 - How would you prepare 250 mL of a 0.100 M solution...Ch. 4 - Prob. 4.61SPCh. 4 - The following aqueous solutions were tested with a...Ch. 4 - Prob. 4.63SPCh. 4 - Individual solutions of Ba(OH)2 and H2SO4 both...Ch. 4 - A solution of HCl in water conducts electricity,...Ch. 4 - Classify each of the following substances as a...Ch. 4 - Is it possible for a molecular substance to be a...Ch. 4 - What is the total molar concentration of ions in...Ch. 4 - What is the total molar concentration of ions in...Ch. 4 - Ringer’s solution, used in the treatment of burns...Ch. 4 - What is the molarity of each ion in a solution...Ch. 4 - Prob. 4.72SPCh. 4 - Prob. 4.73SPCh. 4 - Write net ionic equations for the reactions listed...Ch. 4 - Write net ionic equations for the reactions listed...Ch. 4 - Which of the following substances are likely to be...Ch. 4 - Which of the following substances are likely to be...Ch. 4 - Predict whether a precipitation reaction will...Ch. 4 - Predict whether a precipitation reaction will...Ch. 4 - hich of the following solutions will not form a...Ch. 4 - Which of the following solutions will not form a...Ch. 4 - How would you prepare the following substances by...Ch. 4 - How would you prepare the following substances by...Ch. 4 - What are the mass and the identity of the...Ch. 4 - What are the mass and the identity of the...Ch. 4 - Assume that you have an aqueous mixture of NaNO3...Ch. 4 - Assume that you have an aqueous mixture of BaCl2...Ch. 4 - Assume that you have an aqueous solution of an...Ch. 4 - Assume that you have an aqueous solution of an...Ch. 4 - How could you use a precipitation reaction to...Ch. 4 - How could you u a precipitation reaction to...Ch. 4 - The following three solutions are mixed: 100.0 mL...Ch. 4 - A 250.0 g sample of a white solid is known to be a...Ch. 4 - Assume that you are given a solution of an unknown...Ch. 4 - Why do we use a double arrow () to show the...Ch. 4 - Write balanced ionic equations for the following...Ch. 4 - Write balanced ionic equations for the following...Ch. 4 - Write balanced net ionic equations for the...Ch. 4 - Write balanced net ionic equations for the...Ch. 4 - A flask containing 450 mL of 0.500 M HBr was...Ch. 4 - The odor of skunks is caused by chemical compounds...Ch. 4 - Prob. 4.102SPCh. 4 - Prob. 4.103SPCh. 4 - How many milliliters of 1.00 M KOH must be added...Ch. 4 - How many milliliters of 2.00 M HCl must be added...Ch. 4 - If the following solutions are mixed, is the...Ch. 4 - If the following solutions are mixed, is the...Ch. 4 - Prob. 4.108SPCh. 4 - Assign oxidation numbers to each element in the...Ch. 4 - Assign oxidation numbers to each element in the...Ch. 4 - Assign oxidation numbers to each element in the...Ch. 4 - Nitrogen can have several different oxidation...Ch. 4 - Prob. 4.113SPCh. 4 - Prob. 4.114SPCh. 4 - Where in the periodic table are the most easily...Ch. 4 - In each of the following instances, tell whether...Ch. 4 - Tell for each of the following substances whether...Ch. 4 - Which element is oxidized and which is reduced in...Ch. 4 - Which element is oxidized and which is reduced in...Ch. 4 - Use the activity series of metals (Table 4.5) to...Ch. 4 - Neither strontium (Sr) nor antimony (Sb) is shown...Ch. 4 - (a) Use the following reactions to arrange the...Ch. 4 - Prob. 4.123SPCh. 4 - Iodine, I2 , reacts with aqueous thiosulfate ion...Ch. 4 - How many milliliters of 0.250MNa2S2O3 solution is...Ch. 4 - Dichromate ion, Cr2O72 reacts with aqueous...Ch. 4 - A volume of 18.72 mL of 0.1500MK2Cr2O7 solution...Ch. 4 - What is the molar concentration of As(III) in a...Ch. 4 - Standardized solutions of KBrO3 are frequently...Ch. 4 - The metal content of iron in ores can be...Ch. 4 - Prob. 4.131SPCh. 4 - Alcohol levels in blood can he determined by a...Ch. 4 - Calcium levels in blood can be determined by...Ch. 4 - Assume that you have 1.00 g of a mixture of...Ch. 4 - A compound with the formula XOCl2 , reacts with...Ch. 4 - Prob. 4.136MPCh. 4 - Some metals occur naturally in their elemental...Ch. 4 - A sample weighing 14.98 g and containing a small...Ch. 4 - The solubility of an ionic compound can be...Ch. 4 - Prob. 4.140MPCh. 4 - Prob. 4.141MPCh. 4 - Prob. 4.142MPCh. 4 - A sample of metal (M) reacted with both steam and...Ch. 4 - Prob. 4.144MPCh. 4 - Prob. 4.145MPCh. 4 - Iron content in ores can be determined by a redox...Ch. 4 - Prob. 4.147MPCh. 4 - Salicylic acid, used in the manufacture of...Ch. 4 - Compound X contains only the elements C, H, O, and...Ch. 4 - Prob. 4.150MPCh. 4 - Element M is prepared industrially by a two-step...Ch. 4 - Prob. 4.152MPCh. 4 - Four solutions are prepared and mixed in the...Ch. 4 - To 100.0 mL of a solution that contains 0.120MCr(...Ch. 4 - Sodium nitrite, NaNO2 , is frequently added to...Ch. 4 - Brass is an approximately 4:1 alloy of copper and...Ch. 4 - Prob. 4.157MPCh. 4 - Prob. 4.158MP
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Similar questions
- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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