Bundle: Chemistry In Focus: A Molecular View Of Our World, 6th + Owlv2 6-month Printed Access Card
6th Edition
ISBN: 9781305618374
Author: Nivaldo J. Tro
Publisher: Cengage Learning
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Chapter 4, Problem 4.4YT
Interpretation Introduction
Interpretation:
The name of the given compound is to be written.
Concept Introduction:
The naming of a molecular compound is similar to that of an ionic compound. The name of the more non metallic ion is written first, followed by the name of the relatively less non metallic ion.
In the prefix, the more metallic elements are followed by the less metallic elements and the suffix “ide” is used.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 4 Solutions
Bundle: Chemistry In Focus: A Molecular View Of Our World, 6th + Owlv2 6-month Printed Access Card
Ch. 4 - Interpreting Chemical Formulas Determine the...Ch. 4 - Prob. 4.2YTCh. 4 - Prob. 4.3YTCh. 4 - Prob. 4.4YTCh. 4 - Calculating Formula Mass Calculate the formula...Ch. 4 - Using the Molar Mass to Find the Number of...Ch. 4 - Prob. 4.7YTCh. 4 - Chemical Formulas as Conversion Factors (Mass to...Ch. 4 - Prob. 4.9YTCh. 4 - Prob. 4.10YT
Ch. 4 - Using Chemical Equation Coefficients as Conversion...Ch. 4 - Classify each compound as ionic or molecular. LiBr...Ch. 4 - Prob. 2SCCh. 4 - What is wrong with the following compound names?...Ch. 4 - Prob. 4SCCh. 4 - The coefficients in the chemical reaction 2A+3B...Ch. 4 - Prob. 6SCCh. 4 - In Chapter 3, we learned that all matter is...Ch. 4 - Name some common everyday compounds.Ch. 4 - Prob. 3ECh. 4 - Prob. 4ECh. 4 - Prob. 5ECh. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - What is the difference between a common name for a...Ch. 4 - Prob. 9ECh. 4 - Prob. 10ECh. 4 - Prob. 11ECh. 4 - Prob. 12ECh. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - Why must chemical equations be balanced?Ch. 4 - Explain the numerical relationships inherent in a...Ch. 4 - Chemical Formulas Determine the number of each...Ch. 4 - Determine the number of each type of atom in each...Ch. 4 - Classify each compound as ionic or molecular:...Ch. 4 - Classify each compound as ionic or molecular:...Ch. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - Give a chemical formula for each compound: a....Ch. 4 - Give a chemical formula for each compound: a....Ch. 4 - Prob. 29ECh. 4 - Calculate the formula mass for each compound:...Ch. 4 - The formula mass of an unknown compound containing...Ch. 4 - The formula mass of an unknown compound containing...Ch. 4 - Mole Conversions How many moles of CO2 are...Ch. 4 - What is the mass of 2.55 moles of water?Ch. 4 - The active ingredient in aspirin is...Ch. 4 - The active ingredient in Tylenol is acetaminophen...Ch. 4 - Calculate the number of water molecules (H2O) in...Ch. 4 - Acetone (C3H6O) is used as nail polish remover. If...Ch. 4 - Determine the number of sugar molecules in 7.5 g...Ch. 4 - One drop of water from a medicine dropper has a...Ch. 4 - How many chlorine atoms are in each of the...Ch. 4 - How many hydrogen atoms are in each of the...Ch. 4 - Prob. 43ECh. 4 - Find the number of moles of nitrogen in each of...Ch. 4 - The U.S. Food and Drug Administration recommends...Ch. 4 - The scientific consensus indicates that adults...Ch. 4 - Determine the mass of iron (in kilograms)...Ch. 4 - Determine the mass of carbon (in kilograms)...Ch. 4 - Balancing Chemical Equations Balance each chemical...Ch. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Water can be synthesized according to the...Ch. 4 - Billions of pounds of urea, CO(NH2)2, are produced...Ch. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 61ECh. 4 - For each space-filling molecular model, write a...Ch. 4 - For each chemical reaction, draw in the missing...
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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