The compound is needed to found which has more heat of combustion value between the given set of compounds. Concept introduction: Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule. Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring. Example: Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

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Answer 1

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Chapter 4, Problem 44PP

(a)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(b)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(c)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(d)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

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Answer 2

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Chapter 4, Problem 44PP

(a)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(b)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(c)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(d)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

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Answer 3

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Chapter 4, Problem 44PP

(a)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(b)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(c)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(d)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

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Answer 4

Question

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Chapter 4, Problem 44PP

(a)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(b)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(c)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(d)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

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Answer 5

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Answer 6

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Answer 7

Chapter 4, Problem 44PP

(a)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(b)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(c)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

(d)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

Answer 8

Chapter 4, Problem 44PP

(a)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

Answer 9

Chapter 4, Problem 44PP

(a)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

Answer 10

(b)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

Answer 11

(b)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

Answer 12

(c)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

Answer 13

(c)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

Answer 14

(d)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

Answer 15

(d)

Interpretation Introduction

Interpretation:

The compound is needed to found which has more heat of combustion value between the given set of compounds.

Concept introduction:

Heat of combustion: heat of combustion is the numeric value, which represents the energy required to burn a hydrocarbon completely in presence of oxygen. For more stable molecule heat of combustion value will be high when compare with least stable molecule.

Chair conformer: chair conformer is a stable conformer for cyclohexane compound. In this chair conformer two positions are important for substitutions one is equatorial and other one axial position. Axial positions are parallel to the axis of ring while equatorial positions are perpendicular to the axis of the ring.
Example:

Equatorial position is more stable than axial position; therefore a compound with equatorial substituents has high heat of combustion value than a compound with axial substituents.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 4.2 - Prob. 1LTS Ch. 4.2 - Prob. 1PTS Ch. 4.2 - Prob. 2PTS Ch. 4.2 - Prob. 3ATS Ch. 4.2 - Prob. 2LTS Ch. 4.2 - Prob. 4PTS Ch. 4.2 - Prob. 5ATS Ch. 4.2 - Prob. 3LTS Ch. 4.2 - Prob. 6PTS Ch. 4.2 - Prob. 7ATS

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Chapter 4 Solutions