Chemistry, Books a la Carte Edition and Modified Mastering Chemistry with Pearson eText & ValuePack Access Card (7th Edition)
7th Edition
ISBN: 9780134172514
Author: John E. McMurry
Publisher: PEARSON
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Question
Chapter 4, Problem 4.48SP
Interpretation Introduction
To determine:
- Moles of solute
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Students have asked these similar questions
AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
metal:
a) Tris(acetylacetonato)iron(III)
b) Hexabromoplatinate(2-)
c) Potassium diamminetetrabromocobaltate(III)
(6 points)
2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation
constant for [Fe(CN)6] 4 is ~1032, and that:
Fe3+ (aq) + e
= Fe²+ (aq)
E° = +0.77 V
[Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V
(4 points)
Chapter 4 Solutions
Chemistry, Books a la Carte Edition and Modified Mastering Chemistry with Pearson eText & ValuePack Access Card (7th Edition)
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2ACh. 4 - Prob. 4.3PCh. 4 - Prob. 4.4PCh. 4 - Prob. 4.5ACh. 4 - Prob. 4.6PCh. 4 - APPLY 4.7 Sulfuric acid is normally purchased at a...Ch. 4 - Prob. 4.8PCh. 4 - Conceptual APPLY 4.9 Three different substances,...Ch. 4 - Prob. 4.10P
Ch. 4 - Prob. 4.11ACh. 4 - Prob. 4.12PCh. 4 - APPLY 4.13 How might you use a precipitation...Ch. 4 - Conceptual PRACTICE 4.14 An aqueous solution...Ch. 4 - Conceptual APPLY 4.15 A solution containing the...Ch. 4 - Prob. 4.16PCh. 4 - APPLY 4.17 Give likely chemical formulas...Ch. 4 - PRACTICE 4.18 Write a balanced ionic equation and...Ch. 4 - Prob. 4.19ACh. 4 - Prob. 4.20PCh. 4 - Prob. 4.21ACh. 4 - Prob. 4.22PCh. 4 - Prob. 4.23ACh. 4 - PRACTICE 4.24 Assign an oxidation number to each...Ch. 4 - APPLY 4.25 Chlorine can have several different...Ch. 4 - Prob. 4.26PCh. 4 - APPLY 4.27 Police often use a Breathalyzer test to...Ch. 4 - PRACTICE 4.28 Predict whether the following...Ch. 4 - Prob. 4.29ACh. 4 - Prob. 4.30PCh. 4 - Prob. 4.31ACh. 4 - Prob. 4.32PCh. 4 - Prob. 4.33PCh. 4 - Prob. 4.34PCh. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38CPCh. 4 - Prob. 4.39CPCh. 4 - Prob. 4.40CPCh. 4 - Assume that an aqueous solution Of a cation,...Ch. 4 - The following pictures represent aqueous solutions...Ch. 4 - Prob. 4.43CPCh. 4 - The concentration of an aqueous solution of NaOCl...Ch. 4 - Assume that the electrical conductivity of a...Ch. 4 - Based on the positions in the periodic table,...Ch. 4 - The following two redox reactions occur between...Ch. 4 - Prob. 4.48SPCh. 4 - How many grams of solute would you use to prepare...Ch. 4 - How many milliliters of a 0.45 M BaCl2 solution...Ch. 4 - How many milliliters of a 0.350 M KOH solution...Ch. 4 - The sterile saline solution used to rinse contact...Ch. 4 - Prob. 4.53SPCh. 4 - Copper reacts with dilute nitric acid according to...Ch. 4 - Prob. 4.55SPCh. 4 - Prob. 4.56SPCh. 4 - Prob. 4.57SPCh. 4 - Prob. 4.58SPCh. 4 - Prob. 4.59SPCh. 4 - Prob. 4.60SPCh. 4 - Prob. 4.61SPCh. 4 - Prob. 4.62SPCh. 4 - Prob. 4.63SPCh. 4 - Prob. 4.64SPCh. 4 - Is it possible for a molecular substance to be a...Ch. 4 - Prob. 4.66SPCh. 4 - Prob. 4.67SPCh. 4 - Prob. 4.68SPCh. 4 - Prob. 4.69SPCh. 4 - Prob. 4.70SPCh. 4 - Prob. 4.71SPCh. 4 - Prob. 4.72SPCh. 4 - Prob. 4.73SPCh. 4 - Prob. 4.74SPCh. 4 - Prob. 4.75SPCh. 4 - Prob. 4.76SPCh. 4 - Prob. 4.77SPCh. 4 - Prob. 4.78SPCh. 4 - Prob. 4.79SPCh. 4 - Prob. 4.80SPCh. 4 - Prob. 4.81SPCh. 4 - Prob. 4.82SPCh. 4 - Prob. 4.83SPCh. 4 - Prob. 4.84SPCh. 4 - Prob. 4.85SPCh. 4 - Assume that you are given a solution of an unknown...Ch. 4 - Prob. 4.87SPCh. 4 - Prob. 4.88SPCh. 4 - Prob. 4.89SPCh. 4 - Prob. 4.90SPCh. 4 - Prob. 4.91SPCh. 4 - Prob. 4.92SPCh. 4 - Prob. 4.93SPCh. 4 - Prob. 4.94SPCh. 4 - Prob. 4.95SPCh. 4 - Prob. 4.96SPCh. 4 - Prob. 4.97SPCh. 4 - Prob. 4.98SPCh. 4 - Prob. 4.99SPCh. 4 - Prob. 4.100SPCh. 4 - Where in the periodic table are the most easily...Ch. 4 - In each of the following instances, tell whether...Ch. 4 - Tell for each of the following substances whether...Ch. 4 - Prob. 4.104SPCh. 4 - Prob. 4.105SPCh. 4 - Prob. 4.106SPCh. 4 - Prob. 4.107SPCh. 4 - Nitrogen can have several different oxidation...Ch. 4 - Phosphorus can have several different oxidation...Ch. 4 - Which element is oxidized and which is reduced in...Ch. 4 - 4.111 Which element is oxidized and which is...Ch. 4 - Use the activity series of metals (Table 4.5) to...Ch. 4 - Prob. 4.113SPCh. 4 - Prob. 4.114SPCh. 4 - Prob. 4.115SPCh. 4 - Iodine, I2, reacts with aqueous thiosulfate ion in...Ch. 4 - Iodine, I2, reacts with aqueous thiosulfate ion in...Ch. 4 - Dichromate ion, Cr2O72 , reacts with aqueous...Ch. 4 - Prob. 4.119SPCh. 4 - Prob. 4.120SPCh. 4 - Standardized solutions Of KBrO3are frequently used...Ch. 4 - Prob. 4.122SPCh. 4 - Prob. 4.123SPCh. 4 - Prob. 4.124SPCh. 4 - Calcium levels in blood can be determined by...Ch. 4 - Prob. 4.126CPCh. 4 - Prob. 4.127CPCh. 4 - Prob. 4.128CPCh. 4 - Prob. 4.129CPCh. 4 - Prob. 4.130CPCh. 4 - Prob. 4.131CPCh. 4 - Prob. 4.132CPCh. 4 - Prob. 4.133CPCh. 4 - Prob. 4.134CPCh. 4 - Prob. 4.135CPCh. 4 - Prob. 4.136CPCh. 4 - Prob. 4.137CPCh. 4 - Prob. 4.138CPCh. 4 - Prob. 4.139CPCh. 4 - Prob. 4.140CPCh. 4 - Prob. 4.141CPCh. 4 - Prob. 4.142CPCh. 4 - Prob. 4.143CPCh. 4 - Prob. 4.144CPCh. 4 - Prob. 4.145CPCh. 4 - Prob. 4.146CPCh. 4 - Prob. 4.147CPCh. 4 - Prob. 4.148CPCh. 4 - Prob. 4.149CPCh. 4 - Prob. 4.150CPCh. 4 - Prob. 4.150MPCh. 4 - Prob. 4.151CPCh. 4 - Prob. 4.151MPCh. 4 - Prob. 4.152CPCh. 4 - Prob. 4.152MPCh. 4 - Prob. 4.153CPCh. 4 - Prob. 4.153MPCh. 4 - Prob. 4.154CPCh. 4 - Prob. 4.154MPCh. 4 - Prob. 4.155CPCh. 4 - Prob. 4.155MPCh. 4 - Prob. 4.156CPCh. 4 - Prob. 4.156MPCh. 4 - Prob. 4.157CPCh. 4 - Prob. 4.157MPCh. 4 - Prob. 4.158CPCh. 4 - Prob. 4.158MPCh. 4 - Prob. 4.159CPCh. 4 - Prob. 4.159MPCh. 4 - Prob. 4.160CPCh. 4 - Prob. 4.160MPCh. 4 - Prob. 4.161MPCh. 4 - Prob. 4.162MP
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