GENERAL,ORGANIC+BIOCHEM (LOOSELEAF)
10th Edition
ISBN: 9781264035090
Author: Denniston
Publisher: MCG
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 4, Problem 4.41QP
(a)
Interpretation Introduction
Interpretation:
The mass (in gram) contained in
Concept Introduction:
Mass:
Mass of the compound is calculated by mole of the compound multiplied with molar mass of the compound.
(b)
Interpretation Introduction
Interpretation:
The mass (in gram) contained in
Concept Introduction:
Refer part (a)
(c)
Interpretation Introduction
Interpretation:
The mass (in gram) contained in
Concept Introduction:
Refer part (a)
(d)
Interpretation Introduction
Interpretation:
The mass (in gram) contained in
Concept Introduction:
Refer part (a)
Expert Solution & Answer
![Check Mark](/static/check-mark.png)
Want to see the full answer?
Check out a sample textbook solution![Blurred answer](/static/blurred-answer.jpg)
Students have asked these similar questions
Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Could you redraw these and also explain how to solve them for me pleas
Chapter 4 Solutions
GENERAL,ORGANIC+BIOCHEM (LOOSELEAF)
Ch. 4.1 - Calculate the mass, in g, of Avogadro’s number...Ch. 4.1 - Prob. 4.2PPCh. 4.1 - Prob. 4.3PPCh. 4.1 - What is the mass, in g, of 3.50 mol of the element...Ch. 4.1 - Calculate the number of mol of silver in a silver...Ch. 4.1 - Prob. 4.6PPCh. 4.1 - Prob. 4.1QCh. 4.1 - Prob. 4.2QCh. 4.2 - Prob. 4.7PPCh. 4.2 - Prob. 4.8PP
Ch. 4.2 - Prob. 4.3QCh. 4.2 - Prob. 4.4QCh. 4.3 - Prob. 4.5QCh. 4.3 - Prob. 4.6QCh. 4.4 - Prob. 4.9PPCh. 4.4 - Prob. 4.10PPCh. 4.5 - Prob. 4.11PPCh. 4.6 - Prob. 4.12PPCh. 4.6 - Prob. 4.7QCh. 4.6 - Prob. 4.8QCh. 4.9 - Prob. 4.13PPCh. 4.9 - When potassium cyanide (KCN) reacts with...Ch. 4.9 - Prob. 4.15PPCh. 4.9 - Prob. 4.16PPCh. 4.9 - Prob. 4.17PPCh. 4.9 - Barium carbonate decomposes upon heating to barium...Ch. 4.9 - Prob. 4.19PPCh. 4.9 - Prob. 4.9QCh. 4.9 - Prob. 4.10QCh. 4 - Prob. 4.11QPCh. 4 - What is the average mass (in amu) of:
Zr
Cs
Ca
Ch. 4 - What is the average molar mass of:
Si
Ag
As
Ch. 4 - What is the average molar mass of:
S
Na
Hg
Ch. 4 - What is the mass, in g, of Avogadro’s number of...Ch. 4 - What is the mass, in g, of Avogadro’s number of...Ch. 4 - How many carbon atoms are present in 1.0 × 10−4...Ch. 4 - How many mercury atoms are present in 1.0 × 10−10...Ch. 4 - How many mol of arsenic correspond to 1.0 × 102...Ch. 4 - How many mol of sodium correspond to 1.0 × 1015...Ch. 4 - How many g of neon are contained in 2.00 mol of...Ch. 4 - How many g of carbon are contained in 3.00 mol of...Ch. 4 - What is the mass, in g, of 1.00 mol of helium...Ch. 4 - What is the mass, in g, of 1.00 mol of nitrogen...Ch. 4 - Calculate the number of mol corresponding to:
20.0...Ch. 4 - Calculate the number of mol corresponding to:
0.10...Ch. 4 - What is the mass, in g, of 15.0 mol of silver?
Ch. 4 - What is the mass, in g, of 15.0 mol of carbon?
Ch. 4 - Calculate the number of silver atoms in 15.0 g of...Ch. 4 - Calculate the number of carbon atoms in 15.0 g of...Ch. 4 - Prob. 4.31QPCh. 4 - Distinguish between the terms formula mass and...Ch. 4 - Calculate formula mass and the molar mass of each...Ch. 4 - Calculate formula mass and the molar mass of each...Ch. 4 - Calculate formula mass and the molar mass of...Ch. 4 - Calculate formula mass and the molar mass of...Ch. 4 - Calculate formula mass and the molar mass of CuSO4...Ch. 4 - Calculate formula mass and the molar mass of CaCl2...Ch. 4 - Calculate the number of mol corresponding to:
15.0...Ch. 4 - Calculate the number of mol corresponding to:
15.0...Ch. 4 - Calculate the mass in g corresponding to:
1.000...Ch. 4 - Calculate the mass in g corresponding to:
0.400...Ch. 4 - How many g are required to have 0.100 mol of each...Ch. 4 - Prob. 4.44QPCh. 4 - How many mol are in 50.0 g of each of the...Ch. 4 - How many mol are in 50.0 g of each of the...Ch. 4 - What law is the ultimate basis for a balanced...Ch. 4 - List the general types of information that a...Ch. 4 - Prob. 4.49QPCh. 4 - Prob. 4.50QPCh. 4 - Prob. 4.51QPCh. 4 - What is the meaning of (s), (l), (g), and (aq)...Ch. 4 - Prob. 4.53QPCh. 4 - Prob. 4.54QPCh. 4 - What is the meaning of the subscript in a chemical...Ch. 4 - What is the meaning of the coefficient in a...Ch. 4 - When you are balancing an equation, why must the...Ch. 4 - Describe the process of checking to ensure that an...Ch. 4 - Prob. 4.59QPCh. 4 - Prob. 4.60QPCh. 4 - Prob. 4.61QPCh. 4 - Prob. 4.62QPCh. 4 - Prob. 4.63QPCh. 4 - Balance each of the following equations:
Ch. 4 - Write a balanced equation for each of the...Ch. 4 - Prob. 4.66QPCh. 4 - 4.67 Which of the following ionic compounds will...Ch. 4 - Prob. 4.68QPCh. 4 - Will a precipitate form if solutions of the...Ch. 4 - Prob. 4.70QPCh. 4 - Solutions containing (NH4)2CO3(aq) and CaCl2(aq)...Ch. 4 - Prob. 4.72QPCh. 4 - Describe the difference between the terms ionic...Ch. 4 - Prob. 4.74QPCh. 4 - Write the net ionic equation for the reaction of...Ch. 4 - Prob. 4.76QPCh. 4 - Does an acid gain or lose a hydrogen cation, H+,...Ch. 4 - Prob. 4.78QPCh. 4 - Identify the acid and base in the following...Ch. 4 - Prob. 4.80QPCh. 4 - Does the following equation represent oxidation or...Ch. 4 - Prob. 4.82QPCh. 4 - In the following reaction, identify the species...Ch. 4 - Prob. 4.84QPCh. 4 - Why is it essential to use balanced equations to...Ch. 4 - Describe the steps used in the calculation of g of...Ch. 4 - How many g of B2H6 will react with 3.00 mol of...Ch. 4 - How many g of Al will react with 3.00 mol of O2?
Ch. 4 - Calculate the number of moles of CrCl3 that could...Ch. 4 - A 3.5-g sample of water reacts with PCl3 according...Ch. 4 - Prob. 4.91QPCh. 4 - Prob. 4.92QPCh. 4 - Prob. 4.93QPCh. 4 - Triglycerides (Chapters 17 and 23) are used in...Ch. 4 - Joseph Priestley discovered oxygen in the...Ch. 4 - Dinitrogen monoxide (also known as nitrous oxide...Ch. 4 - The burning of acetylene (C2H2) in oxygen is the...Ch. 4 - Prob. 4.98QPCh. 4 - Various members of a class of compounds called...Ch. 4 - Prob. 4.100QPCh. 4 - A rocket can be powered by the reaction between...Ch. 4 - A 4.00-g sample of Fe3O4 reacts with O2 to produce...Ch. 4 - If the actual yield of decane in Question 4.99 is...Ch. 4 - If the actual yield of oxygen gas in Question...Ch. 4 - If the % yield of nitrogen gas in Question 4.101...Ch. 4 - If the % yield of Fe2O3 in Question 4.102 is...Ch. 4 - Prob. 1MCPCh. 4 - Prob. 2MCPCh. 4 - Prob. 3MCPCh. 4 - Prob. 4MCPCh. 4 - Prob. 5MCPCh. 4 - Prob. 7MCPCh. 4 - Prob. 8MCPCh. 4 - Prob. 9MCP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- In the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forwardNonearrow_forwardNonearrow_forward
- Nonearrow_forwardWhat spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.arrow_forwardQuestion 6 What is the major product of the following Diels-Alder reaction? ? Aldy by day of A. H о B. C. D. E. OB OD Oc OE OAarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY