(a) Interpretation: The Lewis structure of the molecule, whose Newman projection is given, is to be drawn. Concept introduction: In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

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Answer 1

Question

Chapter 4, Problem 4.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. CH3 Ph OEt هد Ph CH3 Hint: the species on the left is an ynolate, which behaves a lot like an enolate.

b. CH3 H3C CH3 CH3 H3C an unexpected product, containing a single 9- membered ring the expected product, containing two fused rings H3C-I (H3C)2CuLi an enolate

Answer 2

Question

Chapter 4, Problem 4.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

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Answer 3

Question

Chapter 4, Problem 4.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

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Answer 4

Question

Chapter 4, Problem 4.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

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Answer 5

Chapter 4, Problem 4.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Answer 6

Chapter 4, Problem 4.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Answer 7

Chapter 4, Problem 4.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of the molecule, whose Newman projection is given, is to be drawn.

Concept introduction:

In a Newman projection, the bond of interest connecting the atoms is not shown. But the atoms connected are shown explicitly. The front atom is shown as a point while the back atom is shown as a circle. The atoms attached to the front carbon converge at the point while the atoms attached to the back carbon are shown connected to the circle.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 4 - Prob. 4.1P Ch. 4 - Prob. 4.2P Ch. 4 - Prob. 4.3P Ch. 4 - Prob. 4.4P Ch. 4 - Prob. 4.5P Ch. 4 - Prob. 4.6P Ch. 4 - Prob. 4.7P Ch. 4 - Prob. 4.8P Ch. 4 - Prob. 4.9P Ch. 4 - Prob. 4.10P

Solution Summary: The author illustrates how the Lewis structure of the molecule, whose Newman projection is given, is drawn.

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Chapter 4 Solutions