Introductory Chemistry (6th Edition)
6th Edition
ISBN: 9780134302386
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 4, Problem 42E
Interpretation Introduction
Interpretation:
Atomic number for each of the given element is to be found with the help of the periodic table.
Concept Introduction:
The number of protons in the nucleus of an atom is known as atomic number of that element.
The symbol for atomic number of an atom is Z.
The elements in periodic table are listed in the increasing order of their
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Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
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mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 4 Solutions
Introductory Chemistry (6th Edition)
Ch. 4 - Q1. Which statement is not part of Dalton’s...Ch. 4 - Q2. Which statement best summarizes the nuclear...Ch. 4 - Q3. An ion composed of which of these particles...Ch. 4 - Which element is a maingroup metal with an even...Ch. 4 - Which element is a halo0gen? a. Ne b. O c. Ca d. ICh. 4 - Prob. 6SAQCh. 4 - Q7. Which element is a row 4 noble gas?
a. Ne
b....Ch. 4 - How many element does the predictable (most...Ch. 4 - Q9. How many neutrons does the Fe-56 isotope...Ch. 4 - Q10. Determine the number of protons, neutrons,...
Ch. 4 - Q11. What is the charge of the Cr ion that...Ch. 4 - An element has four naturally occurring isotopes;...Ch. 4 - What did Democritus contribute to our modern...Ch. 4 - 2. What are three man ideas in Dalton’s atomic...Ch. 4 - Describe Rutherfords gold foil experiment and the...Ch. 4 - What are the main ideas in the nuclear theory of...Ch. 4 - List the three subatomic particles and their...Ch. 4 - What is electrical charge?Ch. 4 - Is matter usually charge-neutral? How would be...Ch. 4 - 8. What does the atomic number of an element...Ch. 4 - What is a chemical symbol?Ch. 4 - Prob. 10ECh. 4 - What Dmitri Mendeleevs main contribution to our...Ch. 4 - What is the man idea in the periodic law?Ch. 4 - How is the periodic table organized?Ch. 4 - Prob. 14ECh. 4 - Prob. 15ECh. 4 - Prob. 16ECh. 4 - What is a family or group of elements?Ch. 4 - Locate each group of elements on the periodic...Ch. 4 - 19. What is an ion?
Ch. 4 - Prob. 20ECh. 4 - 21. Locate each group on the periodic table and...Ch. 4 - 22. What are isotopes?
Ch. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - What notations are commonly used to specify...Ch. 4 - What is the atomic mass of an element?Ch. 4 - 27. Which statement are inconsistent with Dalton’s...Ch. 4 - Which statements are consistent with Daltons...Ch. 4 - Which statements are inconsistent with Rutherfords...Ch. 4 - 30. Which statement are consistent with...Ch. 4 - Prob. 31ECh. 4 - 32. Rutherford’s experiment indicated that matter...Ch. 4 - 33. Which statement about electrons is true?
a....Ch. 4 - 34. Which statement about electrons is false?
a....Ch. 4 - 35. Which statement about protons is true?
a....Ch. 4 - 36. Which statement about protons is false?
a....Ch. 4 - 37. How many electrons would it take to equal the...Ch. 4 - A helium nucleus has two has two neutrons. How...Ch. 4 - What mass of electrons is required to neutralize...Ch. 4 - 40. What mass of protons is required to neutralize...Ch. 4 - Find the atomic number (Z) for each element. a. Fr...Ch. 4 - Prob. 42ECh. 4 - 43. How many protons are in the nucleus of an atom...Ch. 4 - How many protons are in the nucleus of an atom of...Ch. 4 - 45. List the symbol and atomic number of each...Ch. 4 - 46. List the symbol and atomic number of each...Ch. 4 - List the name and the atomic number of each...Ch. 4 - List the name and the atomic number of each...Ch. 4 - Fill in the blanks to complete the table. Element...Ch. 4 - Fill in the blanks to complete the table. Element...Ch. 4 - Classify each element as a metal, nonmetal, or...Ch. 4 - Classify each element as a metal, nonmetal, or...Ch. 4 - Which elements would you expect to lose electrons...Ch. 4 - 54. Which elements would you expect to gain...Ch. 4 - 55. Which elements are main group elements?
a....Ch. 4 - Which elements are not main-group elements? a. AI...Ch. 4 - 57. Which elements are alkaline earth metals?
a....Ch. 4 - Which elements are alkaline earth metal? a....Ch. 4 - 59. Which elements are alkali metals?
a. barium
b....Ch. 4 - Which elements are alkali metals? a. scandium b....Ch. 4 - Classify each element as a halogen, a noble gas,...Ch. 4 - Prob. 62ECh. 4 - 63. To what group number does each element...Ch. 4 - Prob. 64ECh. 4 - Which element do you expect to be most like...Ch. 4 - Which element do you expect to be most like...Ch. 4 - Which pair of elements do you expect to be most...Ch. 4 - Prob. 68ECh. 4 - 69. Which element is a main – group nonmetal?
a....Ch. 4 - Prob. 70ECh. 4 - Prob. 71ECh. 4 - Prob. 72ECh. 4 - Prob. 73ECh. 4 - Prob. 74ECh. 4 - Determine the change of each ion. a. oxygen ion...Ch. 4 - 76. Determine the charge of each ion.
a. tungsten...Ch. 4 - Determine the number of protons and electrons in...Ch. 4 - 78. Determine the number of protons and electrons...Ch. 4 - Prob. 79ECh. 4 - Determine whether each statement is true or false....Ch. 4 - Predict the ion formed by each element. a. Rb b. K...Ch. 4 - 82. Predict ion formed by each element.
a. F
b....Ch. 4 - Predict how many electrons each element will most...Ch. 4 - Predict how many electrons each element will most...Ch. 4 - 85. Fill in the blanks to compele the...Ch. 4 - Fill in the blacks to complete the table. Symbol...Ch. 4 - 87. Determine the atomic number and mass number...Ch. 4 - 88. How many neutrons are in an atom each atomic...Ch. 4 - 89. Write isotopic symbols in the form for each...Ch. 4 - Write isotopic symbol in the form X-A (for...Ch. 4 - Write the symbol for each isotope in the form XZA....Ch. 4 - Write the symbol for each isotope in the form XZA....Ch. 4 - 93. Determine the number of protons and neutrons...Ch. 4 - Determine the number of protons and neutrons in...Ch. 4 - Carbon 14, present within living organisms and...Ch. 4 - Plutonium-239 is used in nuclear bombs. Determine...Ch. 4 - Rubidium has two naturally occurring isotopes:...Ch. 4 - 98. Silicon has three naturally occurring...Ch. 4 - Bromine has two naturally occurring isotopes...Ch. 4 - Silver has two naturally occurring isotopes...Ch. 4 - 101. An element has two naturally occurring...Ch. 4 - Copper has two naturally occurring isotopes. Cu-63...Ch. 4 - Electrical charge is sometimes reported in...Ch. 4 - 104. How many excess protons are in a charged...Ch. 4 - 105. The hydrogen atom contains 1 proton 1...Ch. 4 - 106. Carbon-12 contains 6 protons and 6 neutrons....Ch. 4 - Prepare a table like Table 4.2 for the four...Ch. 4 - 108. Determine the number of protons and neutrons...Ch. 4 - Fill in the blanks to complete the table. Symbol Z...Ch. 4 - 110. Fill in the blanks to complete the...Ch. 4 - Europium has two naturally occurring isotopes:...Ch. 4 - Rhenium has two naturally occurring isotopes:...Ch. 4 - Chapter 1 describes the difference between...Ch. 4 - 114. Chapter1 describes the difference between...Ch. 4 - The atomic mass of fluorine is 19. 00 amu, and all...Ch. 4 - 116. The atomic mass of germanium is 72.61 amu. Is...Ch. 4 - Prob. 117ECh. 4 - Gallium has only two naturally occurring isotopes,...Ch. 4 - 119. The figure shown here is a representation of...Ch. 4 - 120. Neutron stars are believed to be composed of...Ch. 4 - 121. Complete the following...Ch. 4 - Prob. 122QGWCh. 4 - Prob. 123QGWCh. 4 - Prob. 124QGWCh. 4 - 125. The graph at the right shows the atomic...
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