ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 4, Problem 4.21P
Interpretation Introduction

Interpretation:

The product of the reaction of HBr with 2-methyl-1-pentene is to be predicted using the curved arrow mechanism of the reaction.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.
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